Nanostructured poly(urethane)s and poly(urethane-urea)s from reactive solutions of poly[styrene-b-butadiene-b-(methyl methacrylate)]-triblock copolymers

European Polymer Journal

Volumn 44, Issue 11, 2008, Pages 3439-3455

  Jaffrennou, Boris ^a   Portal, Julien ^a   Méchin, Françoise ^a   Pascault, Jean Pierre ^a  

^a UNIVERSITÉ DE LYON   (France)

Author keywords

Block copolymers; Nanostructuration; Poly(urethane urea)s; Polyaddition; Polyurethanes

Indexed keywords

BLENDING; BLOCK COPOLYMERS; BUTADIENE; METABOLISM; MICROPHASE SEPARATION; NANOSTRUCTURED MATERIALS; NANOSTRUCTURES; POLYURETHANES; STYRENE; UREA;

ISOPHORONE DIISOCYANATE; METHYL METHACRYLATES; NANO STRUCTURATION; POLYADDITION; POLYURETHANE UREA; RHEOLOGICAL BEHAVIORS; SEGMENTED POLYURETHANES; TWIN SCREW EXTRUDERS;

ESTERS;

EID: 55349111441     PISSN: 00143057     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.eurpolymj.2008.08.015     Document Type: Article

References (34)

1. In: Oertel G. (Ed). Polyurethane handbook, 2nd ed. (1994), Carl Hanser Verlag, Munich
2. Watanabe H. Slow dielectric relaxation of a styrene-isoprene-styrene triblock copolymer with dipole inversion in the middle block: a challenge to a loop/bridge problem. Macromolecules 28 (1995) 5006-5011
3. Zheng W., and Wang Z.G. Morphology of ABC triblock copolymers. Macromolecules 28 (1995) 7215-7223
4. Breiner U., Krappe U., Abetz V., and Stadler R. Cylindrical morphologies in asymmetric ABC triblock copolymers. Macromol Chem Phys 198 (1997) 1051-1083
5. Breiner U., Krappe U., Jakob T., Abetz V., and Stadler R. "Spheres on spheres" - A novel spherical multiphase morphology in polystyrene-block-polybutadiene-block-poly(methyl methacrylate) triblock copolymers. Polym Bull 40 (1998) 219-226
6. Abetz V., and Stadler R. ABC and BAC triblock copolymers - Morphological engineering by variation of the block sequence. Macromol Symp 113 (1997) 19-26
7. Abetz V., Jiang S., and Göpfert A. Novel pattern formation in blends of asymmetric ABC triblock terpolymers. e-Polymers (2004) n°040
8. Jung K., Abetz V., and Stadler R. Thermodynamically controlled morphological disorder in a microphase separated cylindrical block copolymer. Macromolecules 29 (1996) 1076-1078
9. Stadler R., Auschra C., Beckmann J., Krappe U., Voigt-Martin I., and Leibler L. Morphology and thermodynamics of symmetric poly(A-block-B-block-C) triblock copolymers. Macromolecules 28 (1995) 3080-3097
10. Lodge T.P., Xu X., Ryu C.Y., Hamley I.W., Fairclough J.P.A., Ryan A.J., et al. Structure and dynamics of concentrated solutions of asymmetric block copolymers in slightly selective solvents. Macromolecules 29 (1996) 5955-5964
11. Hamley I.W., Fairclough J.P.A., Ryan A.J., Ryu C.Y., Lodge T.P., Gleeson A.J., et al. Micellar ordering in concentrated solutions of di- and triblock copolymers in a slightly selective solvent. Macromolecules 31 (1998) 1188-1196
12. Lai C., Russell W.B., and Register R.A. Phase behavior of styrene-isoprene diblock copolymers in strongly selective solvents. Macromolecules 35 (2002) 841-849
13. Sato T., Watanabe H., and Osaki K. Rheological and dielectric behavior of a styrene-isoprene-styrene triblock copolymer in n-tetradecane. 1. Rubbery-plastic-viscous transition. Macromolecules 29 (1996) 6231-6239
14. Watanabe H., Sato T., Osaki K., Yao M.L., and Yamagishi A. Rheological and dielectric behavior of a styrene-isoprene-styrene triblock copolymer in selective solvents. 2. Contribution of loop-type middle blocks to elasticity and plasticity. Macromolecules 30 (1997) 5877-5892
15. Meng F., Zheng S., Zhang W., Li H., and Liang Q. Nanostructured thermosetting blends of epoxy resin and amphiphilic poly(ε-caprolactone)-block-polybutadiene-block-poly(ε-caprolac tone) triblock copolymer. Macromolecules 39 (2006) 711-719
16. Meng F., Zheng S., Li H., Liang Q., and Liu T. Formation of ordered nanostructures in epoxy thermosets: a mechanism of reaction-induced microphase separation. Macromolecules 39 (2006) 5072-5080
17. Auschra C., and Stadler R. New ordered morphologies in ABC triblock copolymers. Macromolecules 26 (1993) 2171-2174
18. Beckmann J., Auschra C., and Stadler R. "Ball at the Wall" - A new lamellar multiphase morphology in polystyrene-block-polybutadiene-block-poly(methyl methacrylate) triblock copolymer. Macromol Rapid Commun 15 (1994) 67-72
19. Yamaguchi D., Cloitre M., Panine P., and Leibler L. Phase behavior and viscoelastic properties of thermoplastic elastomer gels based on ABC triblock copolymers. Macromolecules 38 (2005) 7798-7806
20. Ritzenthaler S., Court F., David L., Girard-Reydet E., Leibler L., and Pascault J.P. ABC triblock copolymers/epoxy-diamine blends. 1. Keys to achieve nanostructured thermosets. Macromolecules 35 (2002) 6245-6254
21. Jaffrennou B., Soulé E.R., Méchin F., Borrajo J., Pascault J.P., and Williams R.J.J. Miscibility of blends of poly(methyl methacrylate) and oligodiols based on a bisphenol A nucleus and ethylene oxide or propylene oxide branches. Polymer 45 (2004) 7185-7192
22. Navarro C., Marcarian X., and Vuillemin B. Ligated anionic polymerization: an innovative Elf-Atochem technology for the polymerization of (meth)acrylates. Macromol Symp 132 (1998) 263-272
23. Jerôme R., Teyssié P., Vuillemin B., Zundel T., and Zune C. Recent achievements in anionic polymerization of (meth)acrylates. J Polym Sci Part A: Polym Chem 37 (1999) 1-10
24. Ritzenthaler S., Court F., Girard-Reydet E., Leibler L., and Pascault J.P. ABC triblock copolymers/epoxy-diamine blends. 2. Parameters controlling the morphologies and properties. Macromolecules 36 (2003) 118-126
25. Verchère D., Sautereau H., Pascault J.P., Moschiar S.M., Riccardi C.C., and Williams R.J.J. Miscibility of epoxy monomers with carboxyl-terminated butadiene-acrylonitrile random copolymers. Polymer 30 (1989) 107-115
26. Girard-Reydet E., Sautereau H., Pascault J.P., Keates P., Navard P., Thollet G., et al. Reaction-induced phase separation mechanisms in modified thermosets. Polymer 39 (1998) 2269-2280
27. Fine T., Lortie F., David L., and Pascault J.P. Structures and rheological properties of reactive solutions of block copolymers. Part I. Diblock copolymers in a liquid epoxy monomer. Polymer 46 (2005) 6605-6613
28. Soenen H., Berghmanns H., Winter H.H., and Overbergh N. Ordering and structure formation in triblock copolymer solutions. Part I. Rheological observations. Polymer 38 (1997) 5653-5660
29. Soenen H., Liskova A., Reynders K., Berghmanns H., Winter H.H., and Overbergh N. Ordering and structure formation in triblock copolymer solutions. Part II. Small angle X-ray scattering and calorimetric observations. Polymer 38 (1997) 5661-5665
30. Kleppinger R., Mischenko N., Reynaers H.L., and Koch M.H.J. Long-range order in physical networks of gel-forming triblock copolymer solutions. J Polym Sci Part B: Polym Phys 37 (1999) 1833-1840
31. Nie H., Bansil R., Ludwig K., Steinhart M., Konak C., and Bang J. Time-resolved small angle X-ray scattering study of the kinetics of disorder-order transition in a triblock copolymer in a selective solvent for the middle block. Macromolecules 36 (2003) 8097-8106
32. Inomata K., Nakanishi D., Banno A., Nakanishi E., Abe Y., Kurihara R., et al. Association and physical gelation of ABA triblock copolymer in selective solvent. Polymer 44 (2003) 5303-5310
33. Ritzenthaler S., Girard-Reydet E., and Pascault J.P. Influence of epoxy hardener on miscibility of blends of poly(methyl methacrylate) and epoxy networks. Polymer 41 (2000) 6375-6386
34. Samson N., Méchin F., and Pascault J.P. New segmented polyurethane ureas based on 4,4′-dicyclohexylmethane diisocyanate and on various soft segments. J Appl Polym Sci 70 (1998) 2331-2342