Kinetics of the anionic polymerization of 1,3-butadiene using an initiator composed of alkyl aluminium, n-butyllithium and barium alkoxide to produce high trans-1,4-polybutadiene

Macromolecular Reaction Engineering

Volumn 2, Issue 3, 2008, Pages 222-232

  Tapia, Juan J Benvenuta ^a   Lôpez, José A Tenorio ^b   Nájera, Rafael Herrera ^a  

^a UNIVERSIDAD NACIONAL AUTÓNOMA DE MÉXICO   (Mexico)

^b UNIVERSIDAD VERACRUZANA   (Mexico)

Author keywords

Anionic polymerization; High trans 1,4 polybutadiene; Kinetics; Microstructure; Sequence distribution

Indexed keywords

ACTIVE SITES; ALKOXIDE; ANIONIC LIVING POLYMERIZATIONS; HIGH TRANS-1,4-POLYBUTADIENE; KINETIC MODELS; POLYMERIZATION REACTIONS; SEQUENCE DISTRIBUTION; SEQUENCE DISTRIBUTIONS;

ABS RESINS; ALKYLATION; BARIUM; BUTADIENE; CHEMICAL REACTIONS; LIVING POLYMERIZATION; MICROSTRUCTURE; MONOMERS; POLYMERIZATION; POLYMERS;

ANIONIC POLYMERIZATION;

EID: 55349102013     PISSN: 1862832X     EISSN: 18628338     Source Type: Journal    
DOI: 10.1002/mren.200700048     Document Type: Article

References (37)

1. US 5 596 053 (1997), I. Kang, J. Poulton.
2. US 6 024 146 (2000), P. H. Sandstrom, R. B. Roennau.
3. US 6 184 168 (2000), T. Lynch.
4. M. Rivera, R. Herrera-Nájera, L. J. Ríos-Guerrero, J. Elast Plast. 2006, 38, 133.
5. B. D. Ludbrook, Int. J. Adhes. Adhes. 1984, 4, 148.
6. J. C. Brosse, D. Derouet, F. Epaillard, J. C. Soutif, G. Legeay, K. Dusek, Adv. Polym. Sci. 1986, 81, 167.
7. M. Vargas, A. Chávez-Castellanos, R. Herrera-Nájera, O. Manero-Brito, Rubber Chem. Technol. 2005, 78, 620.
8. M. Morton, "Anionic polymerization: Principles and practices", Academic Press, New York 1983.
9. H. L. Hsieh, R. P. Quirk, "Anionic polymerization: principles and practical applications", Marcel Dekker, New York 1996.
10. P. Ghioca, S. S. Buzdugan, N. Stribeck, Mater. Plast. 2001, 38, 67.
11. M. Rivera, M. J. Benvenuta, R. Herrera, L. Ríos, J. Elast. Plast. 2005, 37, 267.
12. US 5 834 573 (1998), K. Castner.
13. US 5 844 044 (1998), P. H. Sandstrom, W. L. Hsu.
14. A. He, W. Yao, B. Huang, Y. Huang, S. Jiao, J. Appl Polym. Sci. 2004, 92, 52941.
15. US 4 092 268 (1978), Y. Zaraus.
16. US 4 503 204 (1985), R.E. Bingham, C. Fallas, R. Durst, I. Hargis, S. Aggarwal.
17. I. G. Hargis, R. A. Livigni, S. L. Aggarwal, "Devolpments in Rubber Technology", A. Whelan, K. S. Lee, Eds., Elsevier Science, London 1987.
18. A. Halasa, D. B. Patterson, Macromolecules 1991, 24, 1583.
19. A. Halasa, D. B. Patterson, Macromolecules 1991, 24, 4489.
20. D. K. Jenkins, Polymer 1985, 26, 147.
21. J. Boor, "Ziegler-Natta Catalysts and polymerization", Academic Press, New York 1979.
22. F. J. Welch, J. Am. Chem. Soc. 1960, 82, 6000.
23. US 3 992 561 (1976), I. G. Hargis, R. A. Livigni, S. L. Aggarwal.
24. J. J. Benvenuta, R. Herrera, High trans-1,4-poly(butadiene) produced by anionic polymerization of 1,3-butadiene using an initiator composed of alkyl aluminium, n-butyllithium, and barium alkoxide: microstructure-thermal property relationship , Polym. Eng. Sci. under review.
25. [25a] J. N. Hay, J. F. McCabe, J. C. Robb, J. Chem. Soc. Faraday Trans. 1972, 68, 1;
26. [25b] H. L. Hsieh, W. H. Glaze, Rubber Chem. Technol. 1970, 43, 22.
27. S. Bywater, Y. Firat, P. E. Black, J. Polym. Sci. Polym. Chem. Ed. 1984, 22, 669.
28. F. A. Halasa, V. D. Mochel, G. Fraenkel, Am. Chem. Soc. Sym. 1981, 166, 367.
29. V. M. Monroy, G. Guevara, I. Leon, A. Corriga, R. Herrera, Rubber Chem. Technol 1993, 66, 588.
30. Chen Xianong, Chin. J. Polym. Sci. 1990, 8, 3.
31. A. D. Clague, van. J. A. M. Broekhoven, L. P. Blaauw, Macromolecules 1974, 7, 348.
32. F. Schilling, F. A. Bovey, S. Tseng, S. A. Woodward, Macromolecules 1983, 16, 808.
33. H. Sato, K. Takebayashi, Y. Tanaka, Macromolecules 1987, 20, 2418.
34. Y. Tanaka, H. Sato, M. Ogawa, K. Hatada, T. Yoshio, Polym. Lett. Ed. 1974, 12, 369.
35. G. E. Ham, Polym. Sci. 1964, A2, 2735.
36. P. Price, "Markov Chain and Monte Carlo Calculations", in: Polymer Science, G. Lowry, Ed., Marcel Dekker, 1970, Chap. 7.
37. T. L. Sutton, J. F. MacGregor, Can. J. Chem. Eng. 1977, 55, 602.