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Angewandte Chemie - International Edition

Volumn 47, Issue 45, 2008, Pages 8615-8617

Hydrogenation of arenes by dual activation: Reduction of substrates ranging from benzene to C60 fullerene under ambient conditions

(5) Deshmukh, Ravindra R a Lee, Ji Woong a Shin, Ueon Sang a Lee, Jin Yong a Song, Choong Eui a

a Sungkyunkwan University (South Korea)

Author keywords

Fullerenes; Hydrogenation; Ionic liquids; Lewis acids; Palladium

Indexed keywords

ACIDS; AROMATIC COMPOUNDS; AROMATIC HYDROCARBONS; BENZENE; CHEMICAL REACTIONS; FULLERENES; HYDROGEN; HYDROGENATION; IONIZATION OF LIQUIDS; NANOSTRUCTURES; PALLADIUM; SUBSTRATES;

AMBIENT CONDITIONS; AROMATIC SUBSTRATES; AROMATICITY; CHEMICAL EQUATIONS; IONIC HYDROGENATIONS; LEWIS ACIDIC; LEWIS ACIDS; MOLECULAR HYDROGENS; ROOM TEMPERATURES;

IONIC LIQUIDS;

EID: 55249084927 PISSN: 14337851 EISSN: None Source Type: Journal
DOI: 10.1002/anie.200803850 Document Type: Article

Times cited : (75)

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- Some degradation of the fullerene to give lighter hydrocarbons was observed under these conditions
- Some degradation of the fullerene to give lighter hydrocarbons was observed under these conditions.

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14
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- The stable anthracenium salt can also be obtained by mixing anthracene with other quaternary ammonium analogues of 1, such as [NMe 4]Cl-AlCl3 x of AlCl3, 0.67, see the Supporting Information, Figure S1
- 3 = 0.67); see the Supporting Information, Figure S1).

15
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- An additional hydrogenation experiment was conducted with the anthracenium salt, bmim]-2-[AlCl4, under the same conditions used for entry 10 in Table 2. As anticipated, the same reduced products were obtained with those formed from entry 10 in Table 2
- 4], under the same conditions used for entry 10 in Table 2. As anticipated, the same reduced products were obtained with those formed from entry 10 in Table 2.

16
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- In the case of benzene, the enthalpy of the complex formation between benzene-AlCl3 and [bmim][AlCl4]is 9.3 kcal mol -1. For details, see the Supporting Information
- -1. For details, see the Supporting Information.

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