Influence of particle size on reaction selectivity in cyclohexene hydrogenation and dehydrogenation over silica-supported monodisperse pt particles

Catalysis Letters

Volumn 126, Issue 1-2, 2008, Pages 10-19

  Rioux, R M ^a,b   Hsu, B B ^a,c   Grass, M E ^a   Song, H ^a,d   Somorjai, G A ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b The Pennsylvania State University   (United States)

^c MASSACHUSETTS INSTITUTE OF TECHNOLOGY   (United States)

^d Korea Advanced Institute of Science and Technology (KAIST)   (South Korea)

Author keywords

Cyclohexene; Dehydrogenation; Hydrogenation; Particle size; Platinum; Selectivity

Indexed keywords

DEHYDROGENATION; GRAIN SIZE AND SHAPE; HYDROGEN; HYDROGENATION; OLEFINS; PARTICLE SIZE; PLASMAS; PLATINUM; RATE CONSTANTS; SILICA;

APPARENT ACTIVATION ENERGIES; ARRHENIUS; ARRHENIUS TEMPERATURES; CYCLOHEXENE; HIGH TEMPERATURES; INTERMEDIATE TEMPERATURE RANGES; LARGE PARTICLES; LOW TEMPERATURES; MONODISPERSE; NEGATIVE ACTIVATION ENERGIES; REACTION SELECTIVITIES; SELECTIVITY; SIZE DEPENDENTS; SMALL PARTICLES; STRUCTURE SENSITIVES; STRUCTURE SENSITIVITIES; TEMPERATURE REGIMES;

ACTIVATION ENERGY;

EID: 55149089481     PISSN: 1011372X     EISSN: 1572879X     Source Type: Journal    
DOI: 10.1007/s10562-008-9637-8     Document Type: Article

References (38)

1. M Che CO Bennett 1989 Adv Catal 36 55
2. M Boudart 1969 Adv Catal 20 153
3. RM Rioux H Song JD Hoefelmeyer P Yang GA Somorjai 2005 J Phys Chem B 109 2192
4. H Song RM Rioux JD Hoefelmeyer R Komor K Niesz M Grass P Yang GA Somorjai 2006 J Am Chem Soc 128 3027
5. E Segal RJ Madon M Boudart 1978 J Catal 52 45
6. TA Dorling RL Moss 1966 J Catal 5 111
7. SM Davis GA Somorjai 1980 J Catal 65 78
8. KR McCrea GA Somorjai 2000 J Mol Catal A Chem 163 43
9. PA Sermon G Georgiades MSW Vong MA Martin-Luengo PN Reyes 1987 Proc R Soc Lond A 410 353
10. DJ O'Rear DG Löffler M Boudart 1985 J Catal 94 225
11. JM Cogen K Ezaz-Nikpay RH Fleming SM Baumann WF Maier 1987 Angew Chem Int Ed Engl 26 1182
12. É Molnár G Tasi Z Kónya I Kiricsi 2005 Catal Lett 101 159
13. F Zaera 2002 J Phys Chem B 106 4043
14. C Mohr H Hofmeister P Claus 2003 J Catal 213 86
15. C Mohr H Hofmeister J Radnik P Claus 2003 J Am Chem Soc 125 1905
16. MA Vannice B Sen 1989 J Catal 115 65
17. GA Somorjai RM Rioux 2005 Catal Today 100 201
18. Kim JM, Han YJ, Chmelka BF, Stucky GD (2000) Chem Commun 2437
19. UK Singh MA Vannice 2000 J Catal 191 165
20. RM Rioux R Komor H Song JD Hoefelmeyer M Grass K Niesz P Yang GA Somorjai 2008 J Catal 254 1
21. WA Deitz 1967 J Gas Chromatogr 5 68
22. A Fási I Pálinkó T Katona M Bartók 1997 J Catal 167 215
23. Z Paál 1985 J Catal 91 181
24. KJ Yoon MA Vannice 1983 J Catal 82 457
25. JM Orozco G Webb 1983 Appl Catal 6 67
26. A Wootsch Z Paál 1999 J Catal 185 192
27. A Wootsch Z Paál 2002 J Catal 205 86
28. GC Bond JC Slaa 1994 Catal Lett 23 293
29. GC Bond JC Slaa 1995 J Mol Catal A Chem 98 81
30. M Yang RM Rioux GA Somorjai 2006 J Catal 237 255
31. KM Bratlie LD Flores GA Somorjai 2005 Surf Sci 599 93
32. B Sen MA Vannice 1991 J Catal 130 9
33. RW McCabe LD Schmidt 1976 Surf Sci 60 85
34. RW McCabe LD Schmidt 1977 Surf Sci 65 189
35. MSW Vong PA Sermon 1987 J Chem Soc Faraday Trans 83 1369
36. JM Parera NS Figoli EM Traffano JN Beltramini EE Martinelli 1983 Appl Catal 5 33
37. MSW Vong PA Sermon 1987 J Chem Soc Faraday Trans 83 1667
38. GJ Janz 1954 J Chem Phys 22 751