Kinetics study of the UV-initiated cationic polymerization of cycloaliphatic diepoxide resins

European Polymer Journal

Volumn 44, Issue 11, 2008, Pages 3640-3649

  Voytekunas, Vanda Yu ^a   Ng, F L ^a   Abadie, Marc J M ^b,c  

^a SINGAPORE INSTITUTE OF MANUFACTURING TECHNOLOGY   (Singapore)

^b NANYANG TECHNOLOGICAL UNIVERSITY   (Singapore)

^c UNIV MONTPELLIER   (France)

Author keywords

Differencial photocalorimetry; Epoxies; Kinetics; Photo polymerization; Reactivity

Indexed keywords

ABS RESINS; ACTIVATION ENERGY; CARBOXYLATION; CHEMICAL REACTIONS; CHEMICAL REACTIVITY; CHROMOPHORES; CURING; DIFFERENTIAL SCANNING CALORIMETRY; EPOXY RESINS; FUNCTIONAL GROUPS; LASER INTERFEROMETRY; MONOMERS; POLYMERIZATION; POLYMERS; RATE CONSTANTS; REACTION KINETICS; RESINS; STRUCTURE (COMPOSITION);

ADIPATE; ARRHENIUS EQUATIONS; AUTOCATALYTIC KINETICS MODELS; CARBOXYLATE GROUPS; CHEMICAL STRUCTURES; CURE KINETICS; CURING PROCESSES; DIEPOXY MONOMERS; DIFFERENCIAL PHOTOCALORIMETRY; EPOXIES; EPOXY SYSTEMS; EPOXYCYCLOHEXANE; INDUCTION TIMES; ISOTHERMAL TEMPERATURES; KINETICS ANALYSES; KINETICS STUDIES; PEAK MAXIMUMS; PHOTO INITIATORS; PHOTO-POLYMERIZATION; PHOTOCHEMICAL REACTIVITIES; RATE COEFFICIENTS; REACTIVITY; RESIN MONOMERS;

CATIONIC POLYMERIZATION;

EID: 55149088106     PISSN: 00143057     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.eurpolymj.2008.08.043     Document Type: Article

References (29)

1. Pappas S.P. Radiation curing - science and technology (1992), Plenum Press, New York
2. Roffey C.G. Photopolymerization of surface coatings (1981), Wiley, New York
3. In: Oldring P.K.T. (Ed). Chemistry and technology of UV and e-beam formulation for coatings, inks and paints (1991), SITA Technology, London 1-4
4. Dietliker K.K. Chemistry and technology of UV and e-beam formulations for coatings, inks and paints. In: Oldring P.K.T. (Ed) (1991), SITA Technology, London 3
5. Reiser A. Photoreactive polymers (1989), Wiley, New York
6. Fouassier J.-P. Photoinitiation, Photopolymerization and Photocuring - Fundamental and Applications (1995), Hanser, New York
7. Cho I.D., Kim H.K., Kim Y.S., and Hong J.W. Dual curing of cationic UV-curable clear and pigmented coating systems photosensitized by thioxanthone and anthracene. Polym Test 22 6 (2003) 633-645
8. Decker C., Viet T.N.T., Decker D., and Weber-Koehl E. UV-radiation curing of acrylate/epoxide systems. Polym 42 (2001) 5531-5541
9. Boey F.Y.C., Chia N.K., Rath S.K., and Abadie M.J.M. Low-energy electron beam-induced cationic polymerization with onium salts. J Appl Polym Sci 82 12 (2001) 3099-3108
10. Boey F.Y.C., Rath S.K., Ng A.K., and Abadie M.J.M. Cationic UV cure kinetics for multifunctional epoxies. J Appl Polym Sci 86 2 (2002) 518-525
11. Bilyeu B., Brostow W., and Menard K.P. Epoxy thermosets and their applications. III. Kinetic equations and models. J Mater Ed 23 (2001) 189
12. Ionescu-Vasii L.L., and Abadie M.J.M. Kinetic model of photoinduced polymerisation of phenyl glycidyl ether monomer. Polym Int 47 (1998) 221-225
13. Lebel A., Couve J., and Abadie M.J.M. Study of the photolysis of sulfonium salts - cationic photoinitiators, vol. 1, Série II (1998), C.R. Acad Sci., Paris p. 201-207
14. Vuluga S.M., Pantiru M., and Abadie M.J.M. Photoinitiated cationic polymerisation of 1,3-dioxepane. Eur Polym J 35 12 (1999) 2193-2195
15. Sestak J., and Berggren G. Study of the kinetics of the mechanism of solid-state reactions at increasing temperatures. Therm Acta 3 (1971) 1-11
16. Grassino S.B., Strumia M.C., Couve J., and Abadie M.J.M. Photoactive films obtained from methacrylo-urethanes tannic acid-based with potential usage as coating materials: analytic and kinetic studies. Prog Org Coat 37 1-2 (1999) 39-48
17. Crivello J.V., and Lam J.H.W. Complex triarylsulfonium salts photoinitiators. I. The identification, characterization and syntheses of a new class of triarysulfonium salt photoinitiators. J Polym Chem Ed 18 (1980) 2677-2695
18. Crivello J.V. The discovery and development of onium salts cationic photoinitiators. J Polym Sci. Part A: Polym Chem 37 (1999) 4241-4254
19. Boey F.Y.C., and Qiang W. Experimental modeling of the cure kinetics of an epoxy-hexaanhydro-4-methylphthalicanhydride (MHHPA) system. Polym 41 6 (2000) 2081-2094
20. Cho J.-D., and Hong J.-W. Photo-curing kinetics for the UV-initiated cationic polymerization of a cycloaliphatic diepoxide system photosensitized by thioxanthone. Eur Pol J 41 2 (2005) 367-374
21. Abadie M.J.M., Chia N.K., and Boey F.Y.C. Cure kinetics for the ultraviolet cationic polymerization of cycloliphatic and diglycidyl ether of bisphenol-A (DGEBA) epoxy systems with sulfonium salt using an auto catalytic model. J Appl Polym Sci 86 7 (2002) 1587-1591
22. Belgian Pat.828,669, GE (1975).
23. Belgian Pat.828,841, 3M (1975).
24. Belgian Pat.837,782, ICI (1976).
25. Belgian Pat.828,668, GE (1975).
26. Belgian Pat.828,670, GE (1975).
27. Belgian Pat.833,472, ICI (1976).
28. Crivello J.V., and Lam J.H.W. Diaryliodonium salts. A new class of photoinitiators for cationic polymerization. Macromol 10 6 (1977) 1307-1315
29. Abadie MJM. Confidential Report- Rhône Poulenc, 1995.