Characterization of calcium isotopes in natural and synthetic barite

Geochimica et Cosmochimica Acta

Volumn 72, Issue 23, 2008, Pages 5641-5658

  Griffith, Elizabeth M ^a,b   Schauble, Edwin A ^c   Bullen, Thomas D ^d   Paytan, Adina ^b  

^a STANFORD UNIVERSITY   (United States)

^b UNIVERSITY OF CALIFORNIA   (United States)

^c UNIVERSITY OF CALIFORNIA   (United States)

^d U S GEOLOGICAL SURVEY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BARITE; CALCIUM; CRYSTAL STRUCTURE; HOLOCENE; ISOTOPIC COMPOSITION; ISOTOPIC FRACTIONATION;

EID: 55149084593     PISSN: 00167037     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.gca.2008.08.010     Document Type: Article

References (74)

1. 44/40Ca) fractionation along hydrothermal pathways, Logatchev field (Mid-Atlantic Ridge, 14°45′N). Geochim. Cosmochim. Acta 72 (2008) 4107-4122
2. Averyt K.B., and Paytan A. Empirical partition coefficients for Sr and Ca in marine barite: implications for reconstructing seawater Sr and Ca concentrations. Geochem. Geophys. Geosyst. 4 5 (2003) 1043 10.1029/2002GC000426 ISSN: 1525-2027
3. Bakó I., Hutter J., and Palinkas G. Car-Parrinello molecular dynamics simulation of the hydrated calcium ion. J. Chem. Phys. 117 (2002) 9838-9843
4. Bigeleisen J., and Mayer M.G. Calculation of equilibrium constants for isotopic exchange reactions. J. Chem. Phys. 15 (1947) 261-267
5. Bishop J.K.B. The barite-opal-organic carbon association in oceanic particulate matter. Nature 311 (1988) 341-343
6. Broecker W. S. and Peng T. -H. (1982) Tracers in the Sea. Lamont-Doherty Geologic Observatory.
7. Bruneval F., Donadio D., and Parrinello M. Molecular dynamics study of the solvation of calcium carbonate in water. J. Phys. Chem. B 111 (2007) 12219-12227
8. 86Sr in a sandy silicate aquifer, northern Wisconsin. Geochim. Cosmochim. Acta 60 (1996) 1807-1821
9. Chow T.J., and Goldberg E.D. On the marine geochemistry of barium. Geochim. Cosmochim. Acta 20 (1960) 192-198
10. Church T. M. (1970) Marine barite. Ph.D. thesis, University of California, San Diego.
11. Conkright M. E., Levitus S., O'Brien T., Boyer T. P., Antonov J. I. and Stephens C. (1998) World Ocean Atlas 1998 CD-ROM Data Set Documentation. In Tech. Rep. 15, pp. 16. NODC Internal Report.
12. Cowley E.R., and Pant A.K. Lattice dynamics of calcite. Phys. Rev. B 8 (1973) 4795-4800
13. Criss R.E. Principles of stable isotope distribution (1999), Oxford University Press
14. 4. Spectrochim. Acta 35A (1977) 83-93
15. De La Rocha C.L., and DePaolo D.J. Isotopic evidence for variations in the marine calcium cycle over the Cenozoic. Science 289 (2000) 1176-1178
16. Dehairs F., Chesselet R., and Jedwab J. Discrete suspended particles of barite and the barium cycle in the open ocean. Earth Planet. Sci. Lett. 49 (1980) 528-550
17. Eagle M., Paytan A., Arrigo K.R., Dijken G.v., and Murray R.W. A comparison between excess barium and barite as indicators of carbon export. Paleoceanography 18 1 (2003) 1021:1-13
18. Elderfield H., and Schultz A. Mid-ocean ridge hydrothermal fluxes and the chemical composition of the ocean. Annu. Rev. Earth Planet. Sci. 24 (1996) 191-224
19. Fantle M.S., and DePaolo D.J. Variations in the marine Ca cycle over the past 20 million years. Earth Planet. Sci. Lett. 237 (2005) 102-117
20. 2+(aq)-calcite equilibrium fractionation factor and calcite recrystallization rates in Pleistocene sediments. Geochim. Cosmochim. Acta 71 (2007) 2524-2546
21. 44/40Ca of marine skeletal carbonates. Earth Planet. Sci. Lett. 253 1-2 (2007) 96-111
22. 2+ in aqueous solution. I: the perspective on local structure from EXAFS and XANES. J. Phys. Chem. A 107 (2003) 4688-4696
23. Ganeshram R.S., Francois R., Commeau J., and Brown-Leger S.L. An experimental investigation of barite formation in seawater. Geochim. Cosmochim. Acta 67 (2003) 2599-2605
24. Graf D.L. Crystallographic tables for the rhombohedral carbonates. Am. Mineral. 46 (1961) 1283-1316
25. Griffith E.M., Paytan A., Kozdon R., Eisenhauer A., and Ravelo A.C. Influences on the fractionation of calcium isotopes in planktonic foraminifera. Earth Planet. Sci. Lett. 268 (2008) 124-136
26. Gussone N., Böhm F., Eisenhauer A., Dietzel M., Heuser A., Teichert B.M.A., Reitner J., Worheide G., and Dullo W.-C. Calcium isotope fractionation in calcite and aragonite. Geochim. Cosmochim. Acta 69 (2005) 4485-4494
27. Gustafsson, J. P. (2007) Visual MINTEQ Version 2.52. [Online] Available from: .
28. Hawthorne F.C., and Ferguson R.B. Anhydrous sulphates, II. Refinement of the crystal structure of anhydrite. Can. Mineral. 13 (1975) 289-292
29. Hellwege K.H., Lesch W., Plihal M., and Schaack G. Zwei-phononen-Absorptionsspektren end Dispersion der Schwingungszweige in Kristallen der Kalkspatstruktur (Translated title: "Two phonon absorption spectra and dispersion of phonon branches in crystals of calcite structure). Zeitschrift fur Physik 232 (1977) 61-86
30. Hennessy A.J.B., and Graham G.M. The effect of additives on the co-crystallisation of calcium with barium sulphate. J. Cryst. Growth 237-239 (2002) 2153-2159
31. Hensley T. M. 2006. Calcium isotopic variation in marine evaporites and carbonates: applications to Late Miocene Mediterranean brine chemistry and Late Cenozoic calcium cycling in the oceans. Ph.D., Univ. of California, San Deigo.
32. 44Ca) using a multicollector TIMS technique. Int. J. Mass Spectrom. 220 (2002) 385-397
33. 44/40Ca) variations of Neogene planktonic foraminifera. Paleoceanography 20 PA2013 (2005) 1-13 10.1029/2004PA001048
34. Hippler D., Schmitt A.-D., Gussone N., Heuser A., Stille P., Eisenhauer A., and Nägler T.F. Ca isotopic composition of various standards and seawater. Geostandard Newslett. 27 (2003) 13-19
35. 4 groups in celestine, anglesite and barite. Can. Mineral. 36 (1998) 1053-1060
36. Jones F., Oliviera A., Parkinson G.M., Rohl A.L., Stanley A., and Upson T. The effect of calcium ions on the precipitation of barium sulphate 1: calcium ions in the absence of organic additives. J. Cryst. Growth 262 (2004) 572-580
37. Kasemann S.A., Hawkesworth C.J., Prave A.R., Fallick A.E., and Pearson P.N. Boron and calcium isotope composition in Neoproterozoic carbonate rocks from Namibia: evidence for extreme environmental change. Earth Planet. Sci. Lett. 231 (2005) 73-86
38. Kowacz M., Putnis C.V., and Putnis A. The effect of cation:anion ratio in solution on the mechanism of barite growth at constant supersaturation: role of desolvation on the growth kinetics. Geochim. Cosmochim. Acta 71 (2007) 5168-5179
39. Legg M. R. 1980 Seismicity and tectonics of the inner continental borderland of southern California and northern Baja California, Mexico. M.S. thesis, Univ. of California, San Diego.
40. Lemarchand D., Wasserburg G.J., and Papanstassiou D.A. Rate-controlled calcium isotope fractionation in synthetic calcite. Geochim. Cosmochim. Acta 68 (2004) 4665-4678
41. Lonsdale P. A deep-sea hydrothermal site on a strike-slip fault. Nature 281 (1979) 531-534
42. Lonsdale P., and Becker K. Hydrothermal plumes, hot springs, and conductive heat flow in the Southern Trough of Guaymas Basin. Earth Planet. Sci. Lett. 73 2-4 (1985) 211-225
43. Martin E.E., Macdougall J.D., Herbert T.D., Paytan A., and Kastner M. Strontium and neodymium isotopic analyses of marine barite separates. Geochim. Cosmochim. Acta 59 (1995) 1353-1361
44. Méheut M., Lazzeri M., Balan E., and Mauri F. Equilibrium isotopic fractionation in the kaolinite, quartz, water system: prediction from first-principles density-functional theory. Geochim. Cosmochim. Acta 71 (2007) 3170-3181
45. Monkhorst H.J., and Pack J.D. Special points for Brillouin-zone integrations. Phys. Rev. B 13 (1976) 5188-5192
46. 4 solid solutions. Geochim. Cosmochim. Acta 70 (2006) 3290-3298
47. Monnin C., Jeandel C., Cattaldo T., and Dehairs F. The marine barite saturation state of the world's oceans. Mar. Chem. 65 (1999) 253-261
48. Paytan A. (1996) Marine barite: a recorder of oceanic chemistry, productivity and circulation. Ph.D. thesis, Univ. of California, San Diego.
49. Paytan A., Kastner M., Martin E.E., Macdougall J.D., and Herbert T. Marine barite as a monitor of seawater strontium isotope composition. Nature 366 (1993) 445-449
50. Paytan A., Mearon S., Cobb K., and Kastner M. Origin of marine barite deposits: Sr and S isotope characterization. Geology 30 8 (2002) 747-750
51. Perdew J.P., Burke K., and Ernzerhof M. Generalized gradient approximation made simple. Phys. Rev. Lett. 77 (1996) 3865-3868
52. Pilson M.E.Q. An Introduction to the Chemistry of the Sea (1998), Prentice-Hall Inc.
53. Porto S.P.S. Depolarization of Raman scattering in calcite. Phys. Rev. 147 (1966) 608-611
54. Reyes A.O., Moore W.S., and Stakes D.S. Th-228/R-228 ages of a Barite-rich chimney from the endeavor segment of the Juan-De-Fuca ridge. Earth Planet. Sci. Lett. 131 1-2 (1995) 99-113
55. Rutt H.N., and Nicola J.H. Raman spectra of carbonates of calcite structure. J. Phys. C Solid State 7 (1974) 4522-4528
56. Schauble E. A. (2004) Applying stable isotope fractionation theory to new systems. In Geochemistry of non-traditional stable isotopes vol. 55 (eds. C. M. Johnson, B. Beard, and F. Albarede), pp. 65-111.
57. 18O bonds in carbonate minerals, estimated using first-principles lattice dynamics. Geochim. Cosmochim. Acta 70 (2006) 2510-2529
58. Schmitt A.D., Chabaux F., and Stille P. The calcium riverine and hydrothermal isotopic fluxes and the oceanic calcium mass balance. Earth Planet. Sci. Lett. 213 3-4 (2003) 503-518
59. 18O values of Miocene phosphates. Geochim. Cosmochim. Acta 67 (2003) 2607-2614
60. Shannon R.D. Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Acta Crystallogr. A32 (1976) 751-767
61. Sime N.G., De La Rocha C.L., Tipper E.T., Tripati A., Galy A., and Bickle M.J. Interpreting the Ca isotope record of marine biogenic carbonates. Geochim. Cosmochim. Acta 71 (2007) 3979-3989
62. Skulan J., DePaolo D.J., and Owens T.L. Biological control of calcium isotopic abundances in the global calcium cycle. Geochim. Cosmochim. Acta 61 (1997) 2505-2510
63. Skulan J., Bullen T.D., Anbar A.D., Puzas J.E., Schackelford L., LeBlanc A., and Smith S.M. Natural calcium isotopic composition of urine as a marker of bone mineral balance. Clin. Chem. 53 6 (2007) 1155-1158
64. 144Nd isotope variations in cretaceous-eocene Tethyan francolites and their bearing on phosphogenesis in the southern Tethys. Geology 32 5 (2004) 389-392
65. Steuber T., and Buhl D. Calcium-isotope fractionation in selected modern and ancient marine carbonates. Geochim. Cosmochim. Acta 70 (2006) 5507-5521
66. Stroobants N., Dehairs F., Goeyens L., Vanderheijden N., and Grieken R.V. Barite formation in the Southern Ocean water column. Mar. Chem. 35 (1991) 411-421
67. 40Ca fractionation during inorganic calcite formation: II. Ca isotopes. Geochim. Cosmochim. Acta 72 (2008) 3733-3745
68. 18O) in gas hydrate environments. Geology 33 3 (2005) 213-316
69. Tivey M.K., Humphries S.E., Thompson G., Hannington M.D., and Rona P.A. Deducing patterns of fluid flow and mixing within the TAG active hydrothermal mound using mineralogical and geochemical data. J. Geophys. Res. 100 (1995) 12527-12555
70. Torres M.E., McManus J., and Huh C.A. Fluid seepage along the San Clemente Fault scarp: basin-wide impact on barium cycling. Earth Planet. Sci. Lett. 203 (2002) 181-194
71. Urey H.C. The thermodynamic properties of isotopic substances. J. Chem. Soc. (London) (1947) 562-581
72. Wahid F.A., Thomson G.B., Graham G.M., and Jackson R.A. A computational study of the effect of doping covalent cations in barite. J. Mater. Chem. 12 (2002) 3799-3802
73. Wu Z., and Cohen R.E. More accurate generalized gradient approximation for solids. Phys. Rev. B 73 (2006) 235116
74. Zhu P., and Macdougall J.D. Calcium isotopes in the marine environment and the oceanic calcium cycle. Geochim. Cosmochim. Acta 62 (1998) 1691-1698