Fine Structure in High-L Rydberg States: A Path to Properties of Positive Ions

Advances in Atomic, Molecular and Optical Physics

Volumn 52, Issue , 2005, Pages 161-208

  Lundeen, Stephen R ^a  

^a Department of Environmental and Radiological Health Sciences   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 55049124438     PISSN: 1049250X     EISSN: None     Source Type: Book Series    
DOI: 10.1016/S1049-250X(05)52004-4     Document Type: Review

References (123)

1. Amini J.M., and Gould H. High precision measurement of the static dipole polarizability of cesium. Phys. Rev. Lett. 91 (2003) 153001
2. Angel J.R.P., Sandars P.G.H., and Woodgate G.K. Direct measurements of an atomic quadrupole moment. J. Chem. Phys. 47 (1967) 1552
3. 2 Rydberg states. Phys. Rev. A 42 (1990) 6950
4. 2: An experimental test of polarization model predictions. Phys. Rev. A 41 (1990) 3648
5. Aymar M., Greene C.H., and Luc-Koenig E. Multichannel Rydberg spectroscopy of complex atoms. Rev. Mod. Phys. 68 (1996) 1015
6. Babb J.F., and Chang E.S. The Rydberg electronic transitions of the hydrogen molecule. At. Data Nucl. Data Tables 50 (1992) 137
7. Babb J.F., and Dalgarno A. Spin coupling constants and hyperfine transition frequencies for the hydrogen molecular ion. Phys. Rev. A 46 (1992) R5317
8. Babb J.F., Habs D., Spruch L., and Wolf A. Retardation (Casimir) energy shifts for Rydberg helium-like low-Z ions. Z. Phys. D 23 (1992) 197
9. 2. Molecular Phys. 81 (1994) 1435
10. 1,3D and high-L states of He for n = 7 to 10 by electric-field-induced anticrossings. J. Phys. B. At. Mol. Phys. 11 (1978) 979
11. Bhatia A.K., and Drachman R.J. Relativistic, retardation, and radiative corrections in Rydberg states of lithium. Phys. Rev. A 55 (1997) 1842
12. Bhatia A.K., and Drachman R.J. Energy levels of triply ionized carbon (CIV): Polarization model. Phys. Rev. A 60 (1999) 2848
13. 2 Rydberg states: the (0,1) 10 G, H, I, and K states. Phys. Rev. Lett. 62 (1989) 3008
14. 2. Chem. Phys. Lett. 134 (1987) 283
15. Bockasten K. Mean values of powers of the radius for hydrogenic electron orbits. Phys. Rev. A 9 (1974) 1087
16. 4. Phys. Rev. A 14 (1976) 341
17. Breault J., and Noyes R. Solar emission lines near 12 microns. Astrophys. J. 269 (1983) L61
18. Casimir H.B.G., and Polder D. The influence of retardation on the London-van der Waals forces. Phys. Rev. 73 (1948) 360
19. Chang E.S. Nonpenetrating Rydberg states of silicon from solar data. J. Phys. B. At. Mol. Phys. 17 (1984) L11
20. Chang E.S., and Noyes R.W. Identification of the solar emission lines near 12 microns. Astrophys. J. 275 1 (1983) L11
21. Chang E.S., and Sakai H. Properties of ions from spectroscopic data. J. Phys. B. At. Mol. Phys. 15 (1982) L649
22. Chang E.S., Avrett E.H., Mauas P.J., Noyes R.W., and Loeser R. Formation of the infrared emission lines of MgI in the solar atmosphere. Astrophys. J. 379 (1991) L79
23. Chupka W.A. Factors affecting lifetimes and resolution of Rydberg states observed in zero-kinetic-energy spectroscopy. J. Chem. Phys. 96 (1992) 4520
24. Clark W., and Greene C.H. Adventures of a Rydberg electron in an anisotropic world. Rev. Mod. Phys. 71 (1999) 821
25. Clark W., Greene C.H., and Miecznik G. Anisotropic interaction potential between a Rydberg electron and an open-shell ion. Phys. Rev. A 53 (1996) 2248
26. Cok D.R., and Lundeen S.R. Magnetic and electric fine structure in helium Rydberg states. Phys. Rev. A 19 (1979) 1830 24, 3283
27. Cok D.R., and Lundeen S.R. Atomic beam measurements of helium F-G, F-H, and F-I intervals. Phys. Rev. A 23 (1981) 2488
28. Cooke W.E., Gallagher T.F., Hill R.M., and Edelstein S.A. Resonance measurements of d-f and d-g intervals in lithium Rydberg states. Phys. Rev. A 16 (1977) 1141
29. Dalgarno A., and Lewis J.T. The representation of long range forces by series expansion I: The divergence of the series, II: The complete perturbation calculation of long range forces. Proc. Phys. Soc. London Sect. A 69 (1956) 57
30. Deck F.J., Hessels E.A., and Lundeen S.R. Population of high-L sulfur Rydberg levels by ion-Rydberg-atom charge transfer. Phys. Rev. A 48 (1993) 4400
31. Deming D., Jennings D.E., McCabe G., Moran T., and Lowenstein R. Limb observations of the 12.32-micron MgI emission line during the 1994 annular eclipse. Solar Phys. 182 (1998) 283
32. 6. Phys. Rev. A 65 (2002) 053403
33. Deutsch C. Rydberg states of HeI using the polarization model. Phys. Rev. A 13 (1976) 2311
34. Drachman R.J. Rydberg states of helium: An optical potential analysis. Phys. Rev. A 26 (1982) 1228
35. Drachman R.J. Rydberg states of helium: Relativistic and second-order corrections. Phys. Rev. A 31 (1985) 1253
36. Drachman R.J. Rydberg states of helium: A new recoil term. Phys. Rev. A 37 (1988) 979
37. Drachman R.J. Rydberg states of helium: Some further small corrections. Phys. Rev. A 47 (1993) 694
38. Drachman R.J., and Bhatia A.K. Rydberg levels of lithium. Phys. Rev. A 51 (1995) 2926
39. Drake G.W.F. Variational eigenvalues for the Rydberg states of helium: Comparison with experiment and with asymptotic expansions. Phys. Rev. Lett. 65 (1990) 2769
40. Drake G.W.F. High-precision calculations for the Rydberg states of helium. In: Levin F.S., and Micha D.A. (Eds). Long-Range Casimir Forces: Theory and Recent Experiments on Atomic Systems (1993), Plenum Press, New York 107-217
41. Drake G.W.F. Precision calculations for helium. In: Drake G.W.F. (Ed). Atomic, Molecular, and Optical Physics Handbook (1996), AIP Press, Woodbury, NY 154-171
42. Drake G.W.F., and Swainson R.A. Quantum defects and the 1 / N dependence of Rydberg energies - 2nd-order polarization effects. Phys. Rev. A 44 (1991) 5448
43. Dyubko S.F., Efremov V.A., Gerasimov V.G., and MacAdam K.B. Microwave spectroscopy of Al I atoms in Rydberg states: D and G terms. J. Phys. B. At. Mol. Opt. Phys. 36 (2003) 4827
44. Edlen B. Atomic Spectra. Encyclopedia of Physics vol. XXVII (1964), Springer, Berlin
45. Eissa H., and Opik U. The polarization of a closed-shell core of an atomic system by an outer electron I. A correction to the adiabatic approximation. Proc. Phys. Soc. London 92 (1967) 556
46. Ekstrom C.R., Schmiedmayer J., Chapman M.S., Hammond T.D., and Pritchard D.E. Measurement of the electric polarizability of sodium with an atom interferometer. Phys. Rev. A 51 (1995) 3883
47. Eriksson K.B.S. Coupling of electrons with high orbital angular momentum, illustrated by 2 p n f and 2 p n g in NII. Phys. Rev. 102 (1956) 102
48. 4He. Phys. Rev. A 20 (1979) 1754
49. Fisher D.S., Lundeen S.R., Fehrenbach C.W., and DePaola B.D. Energy transfer in ion-Rydberg-atom charge exchange. Phys. Rev. A 63 (2001) 052712
50. Freeman R.R., and Kleppner D. Core polarization and quantum defects in high-angular momentum states of alkali atoms. Phys. Rev. A 14 (1976) 1614
51. 2. Phys. Rev. A 46 (1992) R5313
52. Gallagher T.F. Rydberg Atoms (1994), Cambridge Univ. Press, Cambridge
53. Gallagher T.F., Hill R.M., and Edelstein S.A. Resonance measurements of d-f-g-h splittings in highly excited sates of sodium. Phys. Rev. A 14 (1976) 744
54. Gallagher T.F., Kachru R., and Tran N.H. Radio frequency resonance measurements of the Ba 6sng-6snh-6sni-6snk intervals: An investigation of the non-adiabatic effects in core polarization. Phys. Rev. A 26 (1982) 2611
55. 0 state. Phys. Rev. A 54 (1996) 1973
56. Gray L.G., Sun X., and MacAdam K.B. Resonance measurements of d-f-g-h intervals in Rydberg states of sodium and a redetermination of the core polarizabilities. Phys. Rev. A 38 (1988) 4985
57. Greene C.H., and Jungen Ch. Molecular applications of quantum defect theory. Adv. At. Mol. Phys. 21 (1985) 51
58. 2. J. Chem. Phys. 77 12 (1982) 5876
59. Hessels E.A. Higher-order relativistic corrections to the polarization energies of helium Rydberg states. Phys. Rev. A 46 (1992) 5389
60. Hessels E.A., Sturrus W.G., Lundeen S.R., and Cok D.R. Measurement of the magnetic fine structure of the 10G and 10H states of helium. Phys. Rev. A 35 (1987) 4489
61. Hessels E.A., Arcuni P.W., Deck F.J., and Lundeen S.R. Microwave spectroscopy of high-L, n = 10 Rydberg states of helium. Phys. Rev. A 46 (1992) 2622
62. Jacobs V.L., Davis J., and Kepple P.C. Enhancement of dielectronic recombination by plasma electric microfields. Phys. Rev. Lett. 37 (1976) 1390
63. Jacobson P.L., Labelle R.D., Sturrus W.G., Ward Jr. R.F., and Lundeen S.R. Optical spectroscopy of high-Ln = 10 Rydberg states of nitrogen. Phys. Rev. A 54 (1996) 314
64. 2. Phys. Rev. A 56 (1997) R4361 57, 4065 (E)
65. 2 ground states. Phys. Rev. A 62 (2000) 102509
66. Jennings D.E., Deming D., McCabe G., Sada P.V., and Moran T. Solar magnetic field studies using the 12 micron emission lines. IV. Observations of a Delta region solar flare. Astrophys. J. 568 (2002) 1043
67. 1/2nl states. Phys. Rev. A 38 (1988) 2846
68. 2. II. The 6h-5g and 6g-5f transitions. J. Chem. Phys. 91 (1989) 3926
69. -5 polarization potential. Phys. Rev. A 18 (1978) 15
70. Kleinman C.J., Hahn Y., and Spruch L. Dominant nonadiabatic contribution to the long-range electron-atom interaction. Phys. Rev. 165 (1968) 53
71. Komara R.A., Sturrus W.G., Pollack D.H., and Cochran W.R. Dalgarno-Lewis method for second-order energies of Rydberg states of neon. Phys. Rev. A 59 (1999) 251
72. 2+. Phys. Rev. A 67 (2003) 062502
73. 2+. J. Phys. B At. Mol. Opt. Phys. 38 (2005) S87
74. Laughlin C. An asymptotic potential method for high-L Rydberg levels of calcium. J. Phys. B. At. Mol. Opt. Phys. 28 (1995) 2787
75. Lemoine B., Petitprez D., Destombes J.L., and Chang E.S. High precision infrared diode laser spectrum of Mg I. J. Phys. B. At. Mol. Opt. Phys. 23 (1990) 2217S
76. + dipole polarizability. Phys. Rev. A 57 (1998) 2426
77. MacAdam K.B., and Wing W.H. Fine structure of Rydberg states: n = 6 and 7D and F states of 4He. Phys. Rev. A 12 (1975) 1464
78. + in a Na Rydberg target. Phys. Rev. A 42 (1990) 5269
79. Martin, W.C., Fuhr, J.R., Kelleher, D.E., Musgrove, A., Podobedova, L., Reader, J., Saloman, E.B., Sansonetti, C.J., Wiese, W.L., Mohr, P.J., Olsen, K. (1999). NIST Atomic Spectra Database (Version 2.0), (online). Available: http://physics.nist.gov/asd (January 11, 2005), National Institute of Standards and Technology, Gaithersburg, MD
80. Mayer J.E., and Goeppert Mayer M. The polarizabilities of ions from spectra. Phys. Rev. 43 (1933) 605
81. McEachran R.P., Veenstra C.J., and Cohen M. Hyperfine structure in the hydrogen molecular ion. Chem. Phys. Lett. 59 (1978) 275
82. Miller T.M. Atomic and molecular polarizabilities. CRC Handbook of Chemistry and Physics (2003), CRC Press, Boca Raton, FL 10-163
83. Miller T.M., and Bederson B. Electric dipole polarizability measurements. Adv. At. Mol. Phys. 25 (1988) 37
84. 2. Chem. Phys. Lett. 172 (1990) 458
85. Palfrey S.L., and Lundeen S.R. Measurement of high-angular-momentum fine structure in helium: An experimental test of long-range electromagnetic forces. Phys. Rev. Lett. 53 (1984) 1141
86. 4He singlet states. Phys. Rev. A 22 (1980) 1050
87. Pascale J., Olson R.E., and Reinhold C.O. State-selective capture in collisions between ions and ground and excited-state alkali-metal atoms. Phys. Rev. A 42 (1990) 5305
88. Patil S.H. Atomic potentials, polarizabilities, and nonadiabatic corrections in high-angular-momentum Rydberg states. Phys. Rev. A 33 (1986) 90
89. Pruvost L., Camus P., Lecompte J.-M., Mahon C.R., and Pillet P. High angular momentum 6pnl and 6dnl doubly excited Rydberg states of barium. J. Phys. B. At. Mol. Opt. Phys. 24 (1991) 4723
90. Risberg P. The spectrum of singly-ionized magnesium, MgII. Arkiv for Fysik 9 (1955) 483
91. Ruff G.A., Safinya K.A., and Gallagher T.F. Measurements of the n = 15 - 17 f-g intervals in Cs. Phys. Rev. A 22 (1980) 183
92. Rydberg J.R. On the structure of the line-spectra of the chemical elements. Philosoph. Mag. (London) Ser. 5 29 (1890) 331
93. Safinya K.A., Gallagher T.F., and Sandner W. Resonance measurements of f-h and f-i intervals in cesium using selective and delayed field ionization. Phys. Rev. A 22 (1980) 2672
94. Sansonetti C.J., Andrew K.L., and Verges J. Polarization, penetration, and exchange effects in the hydrogen-like nf and ng terms of cesium. J. Opt. Soc. Am. 71 (1981) 423
95. Schoenfeld, W.G. (1994). Analysis of high-L Rydberg levels of silicon from the solar spectrum: A test of the extended polarization model. PhD Thesis, University of Massachusetts, Amherst, MA
96. Schussler T., Schramm U., Ruter T., Broude C., Grieser M., Habs D., Schwalm D.E., and Wolf A. Laser-stimulated recombination spectroscopy for the study of long-range interactions in highly charged Rydberg ions. Phys. Rev. Lett. 75 (1995) 802
97. Sigut T.A.A., and Lester J.B. Infrared emission lines in early type stars. I. MgII. Astrophys. J. 461 (1996) 972
98. 1/2 cores. Phys. Rev. A 68 (2003) 022510
99. + by measurement of the fine structure of high-Ln = 9 and 10 Rydberg states of barium. Phys. Rev. A (submitted for publication)
100. Spruch L., and Kelsey E.J. Vacuum fluctuation and retardation effects on long-range potentials. Phys. Rev. A 18 (1978) 845
101. Stebbings R.F., and Dunning F.B. Rydberg States of Atoms and Molecules (1983), Cambridge Univ. Press, Cambridge
102. Stevens G.D., and Lundeen S.R. Measurements of G-H, H-I fine structure intervals in n = 7, 9, and 10 helium Rydberg states. Phys. Rev. A 60 (1999) 4379
103. Stevens G.D., and Lundeen S.R. Experimental studies of helium Rydberg fine structure. Comments on Atomic and Molecular Physics, Comments on Modern Physics vol. 1 (2000) Part D, pp. 207-219
104. Stickland R.J., and Cotterell B.J. Infrared inter-Rydberg emission spectra as a possible probe of molecular hydrogen in astrophysical environments. Chem. Phys. Lett. 251 (1996) 287
105. Storry C.H., Rothery N.E., and Hessels E.A. Measurement of the n = 9 F-to-G intervals in atomic lithium. Phys. Rev. A 55 (1997) 128
106. 4 interval in helium: A 200 part per billion measurement. Phys. Rev. A 55 (1997) 967
107. 2 in a fast beam. Phys. Rev. Lett. 54 (1985) 792
108. 2. Phys. Rev. Lett. 57 (1986) 1863
109. 2: A test of the polarization model. Phys. Rev. A 38 (1988) 135
110. 2 Rydberg states (ν = 0, R = 1) n = 10 G, H, I, and K. Phys. Rev. A 44 (1991) 3032
111. Sun X., and MacAdam K.B. Microwave measurements of d-f-g-h intervals and d and f fine structure of sodium Rydberg states. Phys. Rev. A 49 (1994) 2453
112. 2P). Phys. Rev. A 49 (1994) 3453
113. Theodosiou C.E. Evaluation of penetration effects in high-L Rydberg states. Phys. Rev. A 28 (1983) 3098
114. Tran N.H., van Linden van den Heuvell H.B., Kachru R., and Gallagher T.F. Radiofrequency resonance measurements of Na d-f intervals. Phys. Rev. A 30 (1984) 2097
115. Vaidyanathan A.G., and Shorer P. Dynamical contributions to the quantum defects of calcium. Phys. Rev. A 25 (1982) 3108
116. Vaidyanathan A.G., Spencer W.P., Rubbmark J.R., Kuiper H., Fabre C., Kleppner D., and Ducas T.W. Experimental study of nonadiabatic core interactions in Rydberg states of calcium. Phys. Rev. A 26 (1982) 3346
117. Van Deurzen C.H.H. Analysis of 4-ionized vanadium (VV). J. Opt. Soc. Am. 67 (1977) 476
118. Wahlgren G.M., and Hubrig S. Emission lines in the optical spectrum of 3 Cen A. Astronomy Astrophys. 418 (2004) 1073
119. Ward Jr., R.F. (1994). Spectroscopy of high-Ln = 10 Rydberg states of carbon, oxygen, and neon. PhD Thesis, Univ. of Notre Dame
120. Ward Jr. R.F., Sturrus W.G., and Lundeen S.R. Microwave spectroscopy of high-L Rydberg states of neon. Phys. Rev. A 53 (1996) 113
121. White H.E. Introduction to Atomic Spectra (1934), McGraw-Hill, New York p. 8
122. Wolf A., Uhlenberg G., Schramm U., Schussler T., Livingston A.E., Gwinner G., Saathoff G., and Schwalm D. Spectroscopy using stimulated electron-ion recombination. Hyp. Interact. 127 (2000) 203
123. Zygelman B. Non-Abelian geometric phase and long-range atomic forces. Phys. Rev. Lett. 64 (1990) 256