Ethanol oxidation on a nichrome-supported spherical platinum microparticle electrocatalyst prepared by electrodeposition

International Journal of Hydrogen Energy

Volumn 33, Issue 21, 2008, Pages 6143-6149

  Wang, Zhen Hui ^a   Li, Jing ^a   Dong, Xiaoya ^a   Wang, Dong ^a   Chen, Tiwei ^a   Qiao, Haiyan ^a   Huang, Aiping ^a  

^a HENAN NORMAL UNIVERSITY   (China)

Author keywords

Electrodeposition; Ethanol electrooxidation; Nichrome support; Spherical Pt microparticles

Indexed keywords

CATALYST ACTIVITY; CATALYTIC OXIDATION; CHRONOAMPEROMETRY; CYCLIC VOLTAMMETRY; ELECTROCATALYSIS; ELECTROCATALYSTS; ELECTROCHEMICAL ELECTRODES; ELECTRODEPOSITION; ELECTRODES; ELECTROOXIDATION; ETHANOL; PLATINUM; PRECIOUS METALS; SPHERES;

CHLOROPLATINIC ACID; ELECTRO-CATALYTIC OXIDATION; ELECTROCHEMICAL MEASUREMENTS; ETHANOL ELECTRO-OXIDATION; ETHANOL OXIDATION; MICRO-PARTICLES; NICHROME; NICHROME SUBSTRATES;

PLATINUM METALS;

EID: 55049084788     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2008.07.097     Document Type: Article

References (39)

1. Rousseau S, Coutanceau C, Lamy C, Léger JM. Direct ethanol fuel cell (DEFC): electrical performances and reaction products distribution under operating conditions with different platinum-based anodes. J Power Sources 2006; 158(1):18-24.
2. Song SQ, Tsiakaras P. Recent progress in direct ethanol proton exchange membrane fuel cells (DE-PEMFCs). Appl Catal B: Environ 2006;63(3-4):187-93.
3. Jha N, Reddy ALM, Shaijumon MM, Rajalakshmi N, Ramaprabhu S. Pt-Ru/multi-walled carbon nanotubes as electrocatalysts for direct methanol fuel cell. Int J Hydrogen Energy 2008;33(1):427-33.
4. Lai CM, Lin JC, Hsueh KL, Hwang CP, Tsay KC, Tsai LD, et al. On the electrochemical impedance spectroscopy of direct methanol fuel cell. Int J Hydrogen Energy 2007;32(17): 4381-8.
5. Huang YJ, Zhou XC, Liao JH, Liu CP, Lu TH, Xing W. Preparation of Pd/C catalyst for formic acid oxidation using a novel colloid methods. Electrochem Commun 2008;10(4): 621-1.
6. Jung EH, Jung UH, Yang TH, Peak DH, Jung DH, Kim SH. Methanol crossover through PtRu/Nafion composite membrane for a direct methanol fuel cell. Int J Hydrogen Energy 2007;32(7):903-7.
7. Batista EA, Malpass GRP, Motheo AJ, Iwasita T. New mechanistic aspects of methanol oxidation. J Electroanal Chem 2004;571(2):273-82.
8. Wang ZB, Yin GP, Shao YY, Yang BQ, Shi PF, Feng PX. Electrochemical impedance studies on carbon supported PtRuNi and PtRu anode catalysts in acid medium for direct methanol fuel cell. J Power Sources 2007;165(1):9-15.
9. Frackowiak E, Lota G, Cacciaguerra T, Béguin F. Carbon nanotubes with Pt-Ru catalyst for methanol fuel cell. Electrochem Commun 2006;8(1):129-32.
10. Ureta-Zañartu MS, Alarcón A, Muñoz G, Gutiérrez C. Electrooxidation of methanol and ethylene glycol on gold and on gold modified with an electrodeposited polyNiTSPc film. Electrochim Acta 2007;(28)::7857-64.
11. Ganesan R, Ham DJ, Lee JS. Platinized mesoporous tungsten carbide for electrochemical methanol oxidation. Electrochem Commun 2007;9(10):2576-9.
12. Camara GA, Lima RBD, Iwasita T. Catalysis of ethanol electrooxidation by PtRu: the influence of catalyst composition. Electrochem Commun 2004;6(8):812-5.
13. Shao MH, Adzic RR. Electrooxidation of ethanol on a Pt electrode in acid solutions: in situ ATR-SEIRAS study. Electrochim Acta 2005;50(12):2415-22.
14. Vigier F, Coutanceau C, Hahn F, Belgsir EM, Lamy C. On the mechanism of ethanol electro-oxidation on Pt and PtSn catalysts: electrochemical and in situ IR reflectance spectroscopy studies. J Electroanal Chem 2004;563(1):81-9.
15. Song SQ, Zhou WJ, Zhou ZH, Jiang LH, Sun GQ, Xin Q, et al. Direct ethanol PEM fuel cells: the case of platinum based anodes. Int J Hydrogen Energy 2005;30(9):995-1001.
16. Wang H, Jusys Z, Behm RJ. Ethanol electrooxidation on a carbon-supported Pt catalyst: reaction kinetics and product yields. J Phys Chem B 2004;108(50):19413-24.
17. Bommersbach P, Mohamedi M, Guay D. Electrooxidation of ethanol at sputter-deposited platinum-tin catalysts. J Electrochem Soc 2007;154(8):B876-82.
18. Chetty R, Scott K. Direct ethanol fuel cells with catalysed metal mesh anodes. Electrochim Acta 2007;52(12):4073-81.
19. Xue XX, Ge JJ, Tian T, Liu CP, Xing W, Lu TH. Enhancement of the electrooxidation of ethanol on Pt-Sn-P/C catalysts prepared by chemical deposition process. J Power Sources 2007;172(2):560-9.
20. 3 alcohols with Pt and Pt-Ru sputter deposited interdigitated array electrodes. Electrochim Acta 2008;53(7):3029-35.
21. Camara GA, Lima RBD, Iwasita T. The influence of PtRu atomic composition on the yields of ethanol oxidation: a study by in situ FTIR spectroscopy. J Electroanal Chem 2005;585(1):128-31.
22. Santos VP, Colle VD, Lima RBD, Tremiliosi-Filho G. In situ FTIR studies of the catalytic oxidation of ethanol on Pt(III) modified by bi-dimensional osmium nanoislands. Electrochim Acta 2007;52(7):2376-85.
23. Fujiwaa N, Friedrich KA, Stimming U. Ethanol oxidation on PtRu electrodes studied by differential electrochemical mass spectrometry. J Electroanal Chem 1999;472(2):120-5.
24. Freitas RG, Santos MC, Oliveira RTS, Bulhoes LOS, Pereira EC. Methanol and ethanol electroxidation using Pt electrodes prepared by the polymeric precursor method. J Power Sources 2006;158(1):164-8.
25. Wang MY, Chen JH, Fan Z, Tang H, Deng GH, He DL, et al. Ethanol electro-oxidation with Pt and Pt-Ru catalysts supported on carbon nanotubes. Carbon 2004;42(15):3257-72.
26. Bagchi J, Bhattacharya SK. The effect of composition of Ni-supported Pt-Ru binary anode catalysts on ethanol oxidation for fuel cells. J Power Sources 2007;163(2):661-70.
27. Jiang LH, Sun GQ, Sun SG, Liu JG, Tang SH, Li HQ, et al. Structure and chemical composition of supported Pt-Sn electrocatalysts for ethanol oxidation. Electrochim Acta 2005;50(27):5384-9.
28. Simões FC, Anjos DMD, Vigier F, Léger JM, Hahn F, Coutanceau C, et al. Electroactivity of tin modified platinum electrodes for ethanol electrooxidation. J Power Sources 2007;167(1):1-10.
29. Gupta SS, Datta J. A comparative study on ethanol oxidation behavior at Pt and PtRh electrodeposits. J Electroanal Chem 2006;594(1):65-72.
30. Tanaka S, Umeda M, Ojima H, Usui Y, Kimura O, Uchida I. Preparation and evaluation of a multi-component catalyst by using a co-sputtering system for anodic oxidation of ethanol. J Power Sources 2005;152:34-9.
31. Xu CW, Shen PK, Ji XH, Zeng R, Liu YL. Enhanced activity for ethanol electrooxidation on Pt-MgO/C catalysts. Electrochem Commun 2005;7(12):1305-8.
32. Liu ZL, Hong L. Electrochemical characterization of the electrooxidation of methanol, ethanol and formic acid on Pt/C and PtRu/C electrodes. J Appl Electrochem 2007;37(4): 505-10.
33. Wang ZB, Yin GP, Zhang J, Sun YC, Shi PF. Investigation of ethanol electrooxidation on a Pt-Ru-Ni/C catalyst for a direct ethanol fuel cell. J Power Sources 2006;160(1): 37-43.
34. 2 nanocatalysts for ethanol electrooxidation. J Colloid Interface Sci 2007;307(1):139-44.
35. Spǎtaru N, Zhang X, Spǎtaru T, Tryk DA, Fujishima A. Platinum electrodeposition on conductive diamond powder and its application to methanol oxidation in acidic media. J Electrochem Soc 2008;155(3):B264-9.
36. Wu G, Li L, Li JH, Xu BQ. Polyaniline-carbon composite films as supports of Pt and PtRu particles for methanol electrooxidation. Carbon 2005;43(12):2579-87.
37. Hu ZA, Shang XL, Yang YY, Kong C, Wu HY. The electrochemical synthesis of polyaniline/polysulfone composite films and electrocatalytic activity for ascorbic acid oxidation. Electrochim Acta 2006;51(16):3351-5.
38. Wang H, Xu CW, Cheng FL, Jiang SP. Pd nanowire arrays as electrocatalysts for ethanol electrooxidation. Electrochem Commun 2007;9(5):1212-6.
39. Budevski E, Staikov G, Lorenz WJ. Electrocrystallization nucleation and growth phenomena. Electrochim Acta 2000; 45(15-16):2559-74.