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The attraction between two or more nominally monovalent gold ions in compounds has been known in structural chemistry for a long time, and Is called aurophilic attraction, or more generally, metallophilic attraction. See for example: P. Pyykko, Angew. Chem. Int. Ed. 2004, 43, 4412-4456
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The attraction between two or more nominally monovalent gold ions in compounds has been known in structural chemistry for a long time, and Is called aurophilic attraction, or more generally, metallophilic attraction. See for example: P. Pyykko, Angew. Chem. Int. Ed. 2004, 43, 4412-4456.
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7
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For a deeper understanding of these metal(I) thiolate structures see: F. Bensebaa, T. H. Ellis, E. Kruus, R. Voicu, Y. Zhou, Con. J. Chem. 1998, 76, 1654-1659;
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54949156962
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54949131098
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In a way, these polymers can be envisaged as non-conventional polypeptides, for they are constituted of glutathione repeating units. The difference from conventional polypeptides is that here the short peptides are not linked by peptide-bonds, but they are linked by the side chain
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In a way, these polymers can be envisaged as non-conventional polypeptides, for they are constituted of glutathione repeating units. The difference from conventional polypeptides is that here the short peptides are not linked by peptide-bonds, but they are linked by the side chain.
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