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For 1R-matrix studies of HOOOH, see: (a) Engdahl, A.; Nelander, B. Science 2002, 295, 482.
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For studies of HOOOH in solution, see: b
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For reviews on MTO-catalyzed oxygen-transfer reactions, see: (a) Romão, C. C.; Kühn, F. E.; Herrmann, W. A. Chem. Rev. 1997, 97, 3197.
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We have investigated the possibility of an initial interaction between MTO and HOH, resulting in two hydroxide ligands, in a mechanism analogous to that outlined in ref 6d (Figure 2) for the HOOH substrate. However, the barrier to forming this complex is 19.5 kcal/mol (23.6 kcal/mol for HOOH) and is not competitive with the reaction between MTO and the silyl hydrotrioxide
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We have investigated the possibility of an initial interaction between MTO and HOH, resulting in two hydroxide ligands, in a mechanism analogous to that outlined in ref 6d (Figure 2) for the HOOH substrate. However, the barrier to forming this complex is 19.5 kcal/mol (23.6 kcal/mol for HOOH) and is not competitive with the reaction between MTO and the silyl hydrotrioxide.
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13C NMR spectra of some of the substrates studied (see for example, Figure S4 in Supporting Information), might be tentatively assigned to the intermediates of the type I-1.
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13C NMR spectra of some of the substrates studied (see for example, Figure S4 in Supporting Information), might be tentatively assigned to the intermediates of the type I-1.
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29
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2O was added to the reaction mixture before the reaction, does not support this presumption (see Figure S2 in SI).
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2O was added to the reaction mixture before the reaction, does not support this presumption (see Figure S2 in SI).
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(b) Saladino, R.; Neri, V.; Pellicia, A. R.; Caminiti, R.; Sadun, C. J. Org. Chem. 2002, 67, 1323.
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Sadun, C.5
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