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Volumn 130, Issue 43, 2008, Pages 14086-14087

An efficient methyltrioxorhenium(VII)-catalyzed transformation of hydrotrioxides (ROOOH) into dihydrogen trioxide (HOOOH)

Author keywords

[No Author keywords available]

Indexed keywords

METHYLTRIOXORHENIUM; RHENIUM; UNCLASSIFIED DRUG; WATER;

EID: 54849432401     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja806411a     Document Type: Article
Times cited : (12)

References (31)
  • 8
    • 0037127053 scopus 로고    scopus 로고
    • For 1R-matrix studies of HOOOH, see: (a) Engdahl, A.; Nelander, B. Science 2002, 295, 482.
    • For 1R-matrix studies of HOOOH, see: (a) Engdahl, A.; Nelander, B. Science 2002, 295, 482.
  • 11
    • 0000162949 scopus 로고    scopus 로고
    • For reviews on MTO-catalyzed oxygen-transfer reactions, see: (a) Romão, C. C.; Kühn, F. E.; Herrmann, W. A. Chem. Rev. 1997, 97, 3197.
    • For reviews on MTO-catalyzed oxygen-transfer reactions, see: (a) Romão, C. C.; Kühn, F. E.; Herrmann, W. A. Chem. Rev. 1997, 97, 3197.
  • 15
    • 0035823071 scopus 로고    scopus 로고
    • Wentworth, P., Jr.; Jones, L. H.; Wentworth, A. D.; Zhu, X. Y.; Larsen, N. A.; Wilson, I. A.; Xu, X.; Goddard, W. A., III; Janda, K. D.; Eschenmoser, A.; Lerner, R. A. Science 2001, 293, 1806.
    • (a) Wentworth, P., Jr.; Jones, L. H.; Wentworth, A. D.; Zhu, X. Y.; Larsen, N. A.; Wilson, I. A.; Xu, X.; Goddard, W. A., III; Janda, K. D.; Eschenmoser, A.; Lerner, R. A. Science 2001, 293, 1806.
  • 26
    • 0038626673 scopus 로고    scopus 로고
    • version 01, Gaussian, Inc, Wallingford, CT
    • Frisch, M. J.; et al. Gaussian 03, version 01, Gaussian, Inc.; Wallingford, CT, 2004.
    • (2004) Gaussian 03
    • Frisch, M.J.1
  • 27
    • 54849412481 scopus 로고    scopus 로고
    • We have investigated the possibility of an initial interaction between MTO and HOH, resulting in two hydroxide ligands, in a mechanism analogous to that outlined in ref 6d (Figure 2) for the HOOH substrate. However, the barrier to forming this complex is 19.5 kcal/mol (23.6 kcal/mol for HOOH) and is not competitive with the reaction between MTO and the silyl hydrotrioxide
    • We have investigated the possibility of an initial interaction between MTO and HOH, resulting in two hydroxide ligands, in a mechanism analogous to that outlined in ref 6d (Figure 2) for the HOOH substrate. However, the barrier to forming this complex is 19.5 kcal/mol (23.6 kcal/mol for HOOH) and is not competitive with the reaction between MTO and the silyl hydrotrioxide.
  • 28
    • 54849423650 scopus 로고    scopus 로고
    • 13C NMR spectra of some of the substrates studied (see for example, Figure S4 in Supporting Information), might be tentatively assigned to the intermediates of the type I-1.
    • 13C NMR spectra of some of the substrates studied (see for example, Figure S4 in Supporting Information), might be tentatively assigned to the intermediates of the type I-1.
  • 29
    • 54849407949 scopus 로고    scopus 로고
    • 2O was added to the reaction mixture before the reaction, does not support this presumption (see Figure S2 in SI).
    • 2O was added to the reaction mixture before the reaction, does not support this presumption (see Figure S2 in SI).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.