Insertion of chromium(III) ascorbate complex into layered double hydroxide through reduction of intercalated chromate by ascorbic acid

Applied Clay Science

Volumn 42, Issue 1-2, 2008, Pages 90-94

  Das, Nigamananda ^a   Das, Rita ^b  

^a Maharaja Sriram Chandra Bhanja Deo University   (India)

^b Department of Chemistry   (India)

Author keywords

Ascorbic acid; Chromate; Cr(III) complex; Hydrotalcite; Intercalation; LDH

Indexed keywords

ACIDS; CHROMATES; CHROMIUM; DYES; KETONES; METAL COMPLEXES; METALLIC COMPOUNDS; ORGANIC ACIDS; X RAY DIFFRACTION ANALYSIS;

ASCORBIC ACID; ASCORBIC ACIDS; BASAL SPACINGS; CR COMPLEXES; CR(III) COMPLEX; DIFFUSE REFLECTANCE SPECTROSCOPIES; ELEMENTAL ANALYSIS; HYDROTALCITE; IN-SITU FORMATIONS; INTERLAYER SPACES; LAYERED DOUBLE HYDROXIDES; LDH; MGAL LAYERED DOUBLE HYDROXIDES; NEUTRAL PHS; UV-VISIBLE; X-RAY DIFFRACTIONS;

CHROMIUM COMPOUNDS;

ANION; ASCORBIC ACID; CHROMATE; CHROMIUM; FTIR SPECTROSCOPY; HYDROTALCITE; HYDROXIDE; IN SITU MEASUREMENT; SPECTRAL ANALYSIS; X-RAY DIFFRACTION;

EID: 54849432061     PISSN: 01691317     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.clay.2007.11.009     Document Type: Article

References (32)

1. Aisawa S., Sasaki S., Takahashi S., Hirahara H., Nakayama H., and Narita E. Intercalation of amino acids and oligopeptides into Zn-Al layered double hydroxide by coprecipitation reaction. J. Phys. Chem. Solids 67 (2006) 920-925
2. Ambrogi V., Fardella G., Grandolini G., and Perioli L. Intercalation compounds of hydrotalcite-like anionic clays with antiinflammatory agents - I. Intercalation and in vitro release ofibuprofen. Int. J. Pharm. 220 (2001) 23-32
3. Cavani F., Trifirò F., and Vaccari A. Hydrotalcite-type anionic clays: preparation, properties and applications. Catal. Today 11 (1991) 173-301
4. Choy J.H., Jung J.S., Oh J.M., Park M., Jeong J., Kang Y.K., and Han O.J. Layered double hydroxide as an efficient drug reservoir for folate derivatives. Biomaterials 25 (2004) 3059-3064
5. Choy J.H., Choi S.-J., Oh J.-M., and Park T. Clay minerals and layered double hydroxides for novel biological applications. Appl. Clay Sci. 36 (2007) 122-132 and reference therein
6. Coronnado E., Mascaros J.R., Gastallo C.M., and Ribera A. Insertion of magnetic bimetallic oxalate complexes into layer double hydroxide. Chem. Mater. 18 (2006) 6112-6114 and references therein
7. Corma A., Fornes V., and Roy F. Hydrotalcites as base catalysts: influence of the chemical composition and synthesis conditions on the dehydrogenation of isopropanol. J. Catal. 148 (1994) 205-213
8. Costantino U., Ambrogi V., Nocchetti M., and Perioli L. Hydrotalcite-like compounds: versatile layered hosts of molecular anions with biological activity. Micropor. Mesopor. Mater. 107 (2008) 149-213
9. 4+substitution in the layer. J. Colloid Interface Sci. 270 (2004) 1-8
10. 3- complex in Mg,Al layered double hydroxide. Inorg. Chem. 42 (2003) 4232-4240
11. del Arco M., Carriazo D., Martin C., Ferez-Grueso A.M., and Rives V. Acid and redox properties of mixed oxides prepared by calcination of chromate containing layered double hydroxides. J. Solid State Chem. 128 (2005) 3571-3580 and references therein
12. Dixon D.A., Sadler N.P., and Dasgupta T.P. Oxidation of biological substrate by chromium(VI). Part-1. Mechanism of the oxidation of L-ascorbic acid in aqueous solution. J. Chem. Soc. Dalton Trans. (1993) 3489-3495
13. Fudala Á., Pálinkó I., and Kiricsi I. Preparation and characterization of hybrid organic-inorganic composite materials using the amphoteric property of amino acids: amino acid intercalated layered double hydroxide and montmorillonite. Inorg. Chem. 38 (1999) 4653-4658
14. 2. Spectrochim. Acta, Part A 55 (1999) 421-429
15. Gutmann N.H., Spiccia L., and Turney T.W. Complexation of Cu(II) and Ni(II) by nitrilotriacetate intercalated in Zn-Cr layered double hydroxides. J. Mater. Chem. 10 (2000) 1219-1224
16. Karan B.Z., Ay A.N., Unaleroglu C., Firat T., Ristau T., and Jabs W. Structural and magnetic studies on mono and polynuclear chromium ascorbate complexes. Transit. Met. Chem. 30 (2005) 451-459 and references therein
17. Khan A.I., and O'Hare D. Intercalation chemistry of layered double hydroxides: recent developments and applications. J. Mater. Chem. 12 (2002) 3191-3198
18. Mignani A., Scavetta E., and Tonelli D. Electrodeposited glucose oxidase/anionic clay for glucose biosensors design. Anal. Chim. Acta 577 (2006) 98-106
19. 2-. Clays Clay Miner. 25 (1977) 14-18
20. Mousty C., Vieille L., and Cosnier S. Laccase immobilization in redox active layered double hydroxides: a reagentless amperometric biosensor. Biosensors Bioelectronics 22 (2007) 1733-1738
21. Morris G.S., Guidry K.A., Hegsted M., and Hasten D.L. Effects of dietary chromium supplementation on cardiac mass, metabolic enzymes, and contractile proteins. Nutt. Res. 15 (1995) 1045-1052
22. Nakamaoto K. Infrared and Raman Spectra of Inorganic and Coordination Compounds (1986), Wiley, New York
23. Prasanna S.V., Kamath P.V., and Shivakumara C. Synthesis and characterization of layered double hydroxides (LDHs) with intercalated chromate ions. Mater. Res. Bull. 42 (2006) 1028-1039
24. Prevot V., Forano C., and Besse J.P. Reactivity of oxalate with ZnAl layered double hydroxides through new, materials. J. Solid State Chem. 153 (2000) 301-309
25. Rives V. In: Tronto J., Leroux F., Dubois M., Taviot-Gueho C., Naal Z., and Klein S.I. (Eds). Layered Double Hydroxides: Present and Future (2001), Nova Science Publishers, New York
26. Rives V., and Ulibarri M.A. Layered double hydroxides (LDH) intercalated with metal coordination compounds and oxometalates. Coord. Chem. Rev. 181 (1999) 61-120
27. Sels B.F., De Vos D.E., and Jacobs P.A. Hydrotalcite-like anionic clays in catalytic organic reactions. Catal. Rev. 43 (2001) 443-488
28. Tammaro L., Costantino U., Bolognese A., Sammartino G., Marenzi G., Calignano A., Tete S., Mastrangelo F., Califano L., and Vittoria V. Nanohybrids for controlled antibiotic release in topical applications. Int. J. Antimicrob. Agents 29 (2007) 417-423
29. Tichit D., Das N., Coq B., and Durand R. Preparation of Zr-containing layered double hydroxides and characterization of the acido-basic properties of their mixed oxides. Chem. Mater. 14 (2002) 1530-1538 and references therein
30. Vaccari A. Preparation and catalytic properties of cationic and anionic clays. Catal. Today 41 (1998) 53-71
31. Weitkamp J., Hunger M., and Rymsa U. Base catalysis on microporous and mesoporous materials: recent progress and perspectives. Microporous Mesoporous Mater. 48 (2001) 255-270
32. Wypych F., and Satyanaryana K.G. In: Leroux F., and Besse J.P. (Eds). Clay Surfaces: Fundamentals and Application (2004), Elsevier, London 459-495