Preparation of seven- and eight-membered rings by carbon-carbon bond formation induced by samarium diiodide: 7-endo- and 8-endo-trig type cyclization to bicyclo[5.3.0]decanolone, bicyclo[5.4.0]undecanolone, and bicyclo[6.4.0]dodecanolone

Tetrahedron

Volumn 64, Issue 49, 2008, Pages 11096-11104

  Sono, Masakazu ^a   Sugimoto, Yuri ^a   Tatara, Hiroyuki ^a   Ise, Natsuko ^a   Takaoka, Shigeru ^a   Tori, Motoo ^a  

^a TOKUSHIMA BUNRI UNIVERSITY   (Japan)

Author keywords

Bond formation; Cyclization; Reduction; Samarium diiodide

Indexed keywords

1 HYDROXY 11 METHYLSPIRO[5.5]UNDECAN 7 ONE; 1,2 DIMETHYL 2 HYDROXYBICYCLO[5.4.0]UNDECAN 8 ONE; 2 (5 HYDROXYHEXYL) 3 METHYL 2 CYCLOHEX 1 ENONE; 2 (5 HYDROXYHEXYL) 3 METHYLCYCLOPENTANONE; 2 (5 OXOHEXYL)CYCLOHEXANONE; 2 HYDROXY 1 METHYLBICYCLO[5.3.0]DECAN 8 ONE; 2 HYDROXY 1 METHYLBICYCLO[5.4.0]UNDECAN 8 ONE; 2 HYDROXY 1 METHYLBICYCLO[6.4.0]DODECAN 9 ONE; 2 HYDROXY 2 METHYLBICYCLO[5.4.0]UNDECAN 8 ONE; 3 METHYL 2 (5 OXOHEXYL)CYCLOHEX 2 EN 1 OL; 3 METHYL 2 (5 OXOHEXYL)CYCLOHEXANONE; 3 METHYL 2 (6 HYDROXYHEXYL)CYCLOHEX 2 ENONE; 3 METHYL 2 (6 HYDROXYHEXYL)CYCLOHEXANONE; 6 (6 HYDROXY 2 METHYLCYCLOHEX 1 ENYL)HEXANOL; 6 (6 METHYL 2 OXOCYCLOHEXYL)HEXANAL; BICYCLO COMPOUND; KETONE DERIVATIVE; SAMARIUM DIIODIDE; UNCLASSIFIED DRUG;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CHEMICAL BOND; CHEMICAL REACTION; CHEMICAL STRUCTURE; CYCLIZATION; LOW TEMPERATURE; PRIORITY JOURNAL; PROTON NUCLEAR MAGNETIC RESONANCE; RING CLOSING METATHESIS;

EID: 54549123311     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tet.2008.09.073     Document Type: Article

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