Partitioning of Cl and F between fluid and hydrous phonolitic melt of Mt. Vesuvius at ~ 850-1000 °C and 200 MPa

Chemical Geology

Volumn 256, Issue 3-4, 2008, Pages 172-184

  Yu Chevychelov, Vitaliy ^a   Botcharnikov, Roman E ^b   Holtz, Francois ^b  

^a INSTITUTE OF EXPERIMENTAL MINERALOGY   (Russian Federation)

^b LEIBNIZ UNIVERSITY HANNOVER   (Germany)

Author keywords

Chlorine; Fluorine; Mixed fluid; Partitioning; Phonolitic melt; Vesuvius volcano

Indexed keywords

CHLORINE; EXPERIMENTAL STUDY; FLUORINE; PARTITIONING; SOLUBILITY;

CAMPANIA [ITALY]; EURASIA; EUROPE; ITALY; NAPOLI [CAMPANIA]; SOUTHERN EUROPE; VESUVIUS;

EID: 54449083343     PISSN: 00092541     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.chemgeo.2008.06.025     Document Type: Article

References (93)

1. 2O above 573 K. Geochim. Cosmochim. Acta 57 (1993) 1657-1680
2. 8 melts. Eur. J. Mineral. 7 (1995) 905-920
3. Belkin H.E., De Vivo B., Torok K., and Webster J.D. Pre-eruptive volatile content, melt-inclusion chemistry, and microthermometry of interplinian Vesuvius lavas (pre-A.D. 1631). J. Volcanol. Geotherm. Res. 82 (1998) 79-95
4. 2-membrane setup for internally heated pressure vessels: description and application for water solubility in basaltic melts. Am. Mineral. 87 (2002) 1717-1726
5. Berndt J., Koepke J., and Holtz F. An experimental investigation of the influence of water and oxygen fugacity on differentiation of MORB at 200 MPa. J. Petrol. 46 (2005) 135-167
6. Botcharnikov R.E., Behrens H., Holtz F., Koepke J., and Sato H. Sulfur and chlorine solubility in Mt. Unzen rhyodacitic melt at 850 °C and 200 MPa. Chem. Geol. 213 (2004) 207-225
7. 2O-Cl fluids in andesitic melt. Eur. J. Mineral. 19 (2007) 671-680
8. Candela P.A., and Piccoli P.M. Model ore-metal partitioning from melts into vapor and vapor/brine mixtures. In: Thompson J.F.H. (Ed). Magmas, Fluids and Ore Deposits (1995), Mineral. Assoc. Canada 107-127
9. Carroll M.R. Chlorine solubility in evolved alkaline magmas. Ann. Geophys. 48 (2005) 619-631
10. 2O in phonolitic melts. Am. Mineral. 82 (1997) 549-556
11. Carroll M.R., and Webster J.D. Solubilities of sulfur, noble gases, nitrogen, chlorine, and fluorine in magmas. In: Carroll M.R., and Holloway J.R. (Eds). Volatiles in Magmas, Rev. Mineral vol. 30 (1994), Mineral. Soc. Am., Washington 231-279
12. Chevychelov V.Yu. Chlorine dissolution in fluid-rich granitic melts: the effect of calcium addition. Geochem. Intern. 37 (1999) 456-467
13. 2O-NaCl-HCl. N. Jb. Mineral. Abh. 172 (1997) 101-115
14. Chevychelov V.Yu., and Suk N.I. Influence of the composition of magmatic melt on the solubility of metal chlorides at pressures of 0.1-3.0 kbar. Petrology 11 (2003) 62-74
15. Chevychelov V.Yu., Simakin A.G., and Bondarenko G.V. Mechanism of chlorine dissolution in water-saturated model granodiorite melt: applications of IR spectroscopic methods. Geochem. Intern. 41 (2003) 395-409
16. Chevychelov V.Yu., Zaraisky G.P., Borisovskii S.E., and Borkov D.A. Effect of melt composition and temperature on the partitioning of Ta, Nb, Mn, and F between granitic (alkaline) melt and fluorine-bearing aqueous fluid: fractionation of Ta and Nb and conditions of ore formation in rare-metal granites. Petrology 13 (2005) 305-321
17. Chevychelov V.Yu., Botcharnikov R.E., and Holtz F. Experimental investigation of chlorine and fluorine contents in mica (biotite) and their partitioning between mica, phonolitic melt and fluid. Geochem. Intern. 46 (2008)
18. Chevychelov V.Yu., Botcharnikov R.E., and Holtz F. Experimental investigation of chlorine and fluorine partitioning between fluid and subalkalic basaltic melt. Doklady Earth Sciences 422 7 (2008) 1089-1092
19. 2O to 1000 °C and 1500 bars. Geochim. Cosmochim. Acta 51 (1987) 1965-1975
20. Christiansen E.H., and Lee D.E. Fluorine and chlorine in granitoids from the basin and range province, western United States. Econ. Geol. 81 (1986) 1484-1494
21. Cioni R. Volatile content and degassing processes in the AD 79 magma chamber at Vesuvius (Italy). Contrib. Mineral. Petrol. 140 (2000) 40-54
22. De Natale G., Troise C., Pingue F., Mastrolorenzo G., and Pappalardo L. The Somma-Vesuvius volcano (Southern Italy): structure, dynamics and hazard evaluation. Earth-Sci. Rev. 74 (2006) 73-111
23. 2O contents of silicic volcanic glasses. Am. Mineral. 80 (1995) 319-328
24. Dolejs D., and Baker D.R. Fluorite solubility in hydrous haplogranitic melts at 100 MPa. Chem. Geol. 225 (2006) 40-60
25. 2O to 100 MPa: I. Silicate-fluoride liquid immiscibility in anhydrous systems. J. Petrol. 48 (2007) 785-806
26. 2O to 100 MPa: II. Differentiation paths of fluorosilicic magmas in hydrous systems. J. Petrol. 48 (2007) 807-828
27. 2O, F and Cl contents of silicic magmas using melt inclusions: examples from Taupo volcanic center, New Zealand. Bull. Volcanol. 51 (1989) 177-184
28. Freise M., Holtz F., Koepke J., Scoates J., and Leyrit H. Experimental constraints on the storage conditions of phonolites from the Kerguelen Archipelago. Contrib. Mineral. Petrol. 145 (2003) 659-672
29. Gabitov R.I., Price J.D., and Watson E.B. Solubility of fluorite in haplogranitic melt of variable alkalis and alumina content at 800°-1000 °C and 100 MPa. Geochem. Geophys. Geosyst. 6 (2005) Q03007
30. 2. Geochem. Int. 17 5 (1980) 35-48
31. Gorbachev N.S., and Khodorevskaya L.I. Partitioning of chlorine between aqueous fluid and basaltic melts at high pressures: behaviour of chlorine and water in processes of magma degassing. Dokl. Acad. Nauk 340 5 (1995) 672-675 [in Russian]
32. Gramenitskiy E.N., Shchekina T.I., and Deviatova V.N. Phase Relations in the Fluorine-Bearing Granitic and Nepheline-Syenitic Systems and Partitioning of Elements Between Phases (Experimental Study) (2005), GEOS, Moscow 188 p. [in Russian]
33. Hamilton D.L., and Henderson C.M.B. The preparation of silicate compositions by a gelling method. Mineral. Mag. 36 282 (1968) 832-838
34. 2O. Contrib. Mineral. Petrol. 138 (2000) 84-98
35. Heinrich C.A. Fluid-fluid interactions in magmatic-hydrothermal ore formation. Rev. Mineral. Geochem. 65 (2007) 363-387
36. 5 on the solubility of water in haplogranite melts compared to natural silicate melts. Contrib. Mineral. Petrol. 113 (1993) 492-501
37. 2O solubility in haplogranitic melts: compositional, pressure, and temperature dependence. Am. Mineral. 80 (1995) 94-108
38. Iacono Marziano G., Schmidt B.C., and Dolfi D. Equilibrium and disequilibrium degassing of a phonolitic melt (Vesuvius AD 79 "white pumice") simulated by decompression experiments. J. Volcanol. Geotherm. Res. 161 (2007) 151-164
39. Keppler H. Influence of fluorine on the enrichment of high field strength trace elements in granitic rocks. Contrib. Mineral. Petrol. 114 (1993) 479-488
40. 2O-HF. Contrib. Mineral. Petrol. 109 (1991) 139-150
41. Kilinc I.A., and Burnham C.W. Partitioning of chloride between a silicate melt and coexisting aqueous phase from 2 to 8 kilobars. Econ. Geol. 67 (1972) 231-235
42. 2O to 4 kilobars pressure. J. Geol. 76 (1968) 50-70
43. 2O at one kilobar pressure, with petrological applications. J. Geol. 77 5 (1969) 581-605
44. Kotelnikova Z.A., and Kotelnikov A.R. Synthetic NaF-bearing fluid inclusions. Geochem. Int. 40 (2002) 594-600
45. Kovalenko N.I. The reactions between granite and aqueous hydrofluoric acid in relation to the origin of fluorine-bearing granites. Geochem. Int. 14 (1977) 108-118
46. Kravchuk I.F., and Keppler H. Distribution of chloride between aqueous fluids and felsic melts at 2 kbar and 800 °C. Eur. J. Mineral. 6 (1994) 913-923
47. Kravchuk I.F., and Slutsky A.B. Behaviour of fluorine in fluid-magmatic system. Geokhimiya 6 (2001) 671-676 [in Russian]
48. Larsen J.F., and Gardner J.E. Experimental study of water degassing from phonolite melts: implications for volatile oversaturation during magmatic ascent. J. Volcanol. Geotherm. Res. 134 (2004) 109-124
49. Lima A., De Vivo B., Fedele L., Sintoni F., and Milia A. Geochemical variations between the 79 AD and 1944 AD Somma-Vesuvius volcanic products: constraints on the evolution of the hydrothermal system based on fluid and melt inclusions. Chem. Geol. 237 (2007) 401-417
50. Lowenstern J.B. Chlorine, fluid immiscibility, and degassing in peralkaline magmas from Pantelleria, Italy. Am. Mineral. 79 (1994) 353-369
51. Lukkari S., and Holtz F. Phase relations of a F-enriched peraluminous granite: an experimental study of the Kymi topaz granite stock, southern Finland. Contrib. Mineral. Petrol. 153 (2007) 273-288
52. Malinin S.D., and Kravchuk I.F. Behaviour of chlorine in silicate melt-aqueous chloride fluid equilibriums. Geokhimiya 8 (1995) 1110-1130 [in Russian]
53. Malinin S.D., Kravchuk I.F., and Delbove F. Chloride distribution between phases in hydrated and dry chloride-aluminosilicate melt systems as a function of phase composition. Geochem. Int. 26 (1989) 32-38
54. Manning D.A.C. The effect of fluorine on liquidus phase relationships in the system Qz-Ab-Or with excess water at 1 kbar. Contrib. Mineral. Petrol. 76 (1981) 206-215
55. Marakushev A.A., Gramenitskii E.N., and Korotaev M.Yu. Petrological model of endogenic ore formation. Geol. Rudn. Mestorozd. 1 (1983) 3-20 [in Russian]
56. Marianelli P., Métrich N., Santacroce R., and Sbrana A. Mafic magma batches at Vesuvius: a glass inclusion approach to the modalities of feeding stratovolcanoes. Contrib. Mineral. Petrol. 120 (1995) 159-169
57. Marianelli P., Métrich N., and Sbrana A. Shallow and deep reservoirs involved in magma supply of the 1944 eruption of Vesuvius. Bull. Volcanol. 61 (1999) 48-63
58. Mathez E.A., and Webster J.D. Partitioning behavior of chlorine and fluorine in the system apatite-silicate melt-fluid. Geochim. Cosmochim. Acta 69 (2005) 1275-1286
59. Métrich N., and Rutherford M.J. Experimental study of chlorine behavior in hydrous silicic melts. Geochim. Cosmochim. Acta 56 (1992) 607-616
60. Paone A., Ayuso R.A., and De Vivo B. A metallogenic survey of alkalic rocks of Mt. Somma-Vesuvius volcano. Mineral. Petrol. 73 (2001) 201-233
61. Price J.D., Hogan J.P., Gilbert M.C., London D., and Morgan G.B. Experimental study of titanite-fluorite equilibria in the A-type Mount Scott Granite: implications for assessing F contents of felsic magma. Geol. 27 10 (1999) 951-954
62. Raia F., Webster J.D., and De Vivo B. Pre-eruptive volatile contents of Vesuvius magmas: constraints on eruptive history and behavior. I - The medieval and modern interplinian activities. Eur. J. Mineral. 12 (2000) 179-193
63. Ravich M.I. Water-Salt Systems at Elevated Temperatures and Pressures (1974), Nauka, Moscow 151 p. [in Russian]
64. Ravich M.I., and Valyashko V.M. Solubility of sodium fluoride at elevated temperatures. Russ. J. Inorgan. Chem. 10 (1965) 107-109
65. Roy R. Aids in hydrothermal experimentation. J. Am. Ceram. Soc. 39 (1956) 145-146
66. Santacroce R., Bertagnini A., Civetta L., Landi P., and Sbrana A. Eruptive dynamics and petrogenetic processes in a very shallow magma reservoir: the 1906 eruption of Vesuvius. J. Petrol. 34 (1993) 383-425
67. Scaillet B., and Macdonald R. Experimental constraints on the relationships between peralkaline rhyolites of the Kenya rift valley. J. Petrol. 44 (2003) 1867-1894
68. Scaillet B., and Macdonald R. Fluorite stability in silicic magmas. Contrib. Mineral. Petrol. 147 (2004) 319-329
69. Schmidt B.C., and Behrens H. Water solubility in phonolite melts, influence of melt composition and temperature. Chem. Geol. 256 (2008) 258-267 10.1016/j.chemgeo.2008.06.043 (this issue)
70. Shinohara H. Exsolution of immiscible vapor and liquid phases from a crystallizing silicate melt: implications for chlorine and metal transport. Geochim. Cosmochim. Acta 58 (1994) 5215-5221
71. Shinohara H., Iiyama J.T., and Matsuo S. Partition of chlorine compounds between silicate melt and hydrothermal solutions. Geochim. Cosmochim. Acta 53 (1989) 2617-2630
72. Signorelli S., and Capaccioni B. Behaviour of chlorine prior and during the 79 A.D. Plinian eruption of Vesuvius (southern Italy) as inferred from the present distribution in glassy mesostases and whole-pumices. Lithos 46 (1999) 715-730
73. Signorelli S., and Carroll M.R. Solubility and fluid-melt partitioning of Cl in hydrous phonolitic melts. Geochim. Cosmochim. Acta 64 (2000) 2851-2862
74. Signorelli S., and Carroll M.R. Experimental study of Cl solubility in hydrous alkaline melts: constraints on the theoretical maximum amount of Cl in trachytic and phonolitic melts. Contrib. Mineral. Petrol. 143 (2002) 209-218
75. 2O, F, Cl and S) contents of phonolitic magmas feeding the 3550-year old Avellino eruption from Vesuvius, southern Italy. J. Volcanol. Geotherm. Res. 93 (1999) 237-256
76. 2O- and Chlorine-bearing fluids in basaltic melt of Mount Etna at T = 1050-1250 °C and P = 200 MPa. Chem. Geol. 256 (2008) 101-109 10.1016/j.chemgeo.2008.06.043 (this issue)
77. Straub S.M., and Layne G.D. The systematics of chlorine, fluorine, and water in Izu arc front volcanic rocks: implications for volatile recycling in subduction zones. Geochim. Cosmochim. Acta 67 (2003) 4179-4203
78. Thomas R., Foerster H.-J., Rickers K., and Webster J.D. Formation of extremely F-rich hydrous melt fractions and hydrothermal fluids during differentiation of highly evolved tin-granite magmas: a melt/fluid-inclusion study. Contrib. Mineral. Petrol. 148 (2005) 582-601
79. Thompson A.B., Aerts M., and Hack A.C. Liquid immiscibility in silicate melts and related systems. Rev. Mineral. Geochem. 65 (2007) 99-127
80. Urusova M.A., and Ravich M.I. Phase equilibria in the potassium fluoride-water system at elevated temperatures. Russ. J. Inorgan. Chem. 11 (1966) 353-357
81. Veksler I.V. Liquid immiscibility and its role at the magmatic-hydrothermal transition: a summary of experimental studies. Chem. Geol. 210 (2004) 7-31
82. 2 fluids and topaz rhyolite melt. Implications for mineralizing magmatic-hydrothermal fluids in F-rich granitic systems. Contrib. Mineral. Petrol. 104 (1990) 424-438
83. Webster J.D. Fluid-melt interactions involving Cl-rich granites: experimental study from 2 to 8 kbar. Geochim. Cosmochim. Acta 56 (1992) 659-678
84. Webster J.D. Water solubility and chlorine partitioning in Cl-rich granitic systems: effects of melt composition at 2 kbar and 800 °C. Geochim. Cosmochim. Acta 56 (1992) 679-687
85. Webster J.D. Exsolution of magmatic volatile phases from Cl-enriched mineralizing granitic magmas and implications for ore metal transport. Geochim. Cosmochim. Acta 61 (1997) 1017-1029
86. Webster J.D. Chloride solubility in felsic melts and the role of chloride in magmatic degassing. J. Petrol. 38 (1997) 1793-1807
87. Webster J.D. The exsolution of magmatic hydrosaline chloride liquids. Chem. Geol. 210 (2004) 33-48
88. Webster J.D., and De Vivo B. Experimental and modeled solubilities of chlorine in aluminosilicate melts, consequences of magma evolution, and implications for exsolution of hydrous chloride melt at Mt. Somma-Vesuvius. Am. Mineral. 87 (2002) 1046-1061
89. Webster J.D., and Holloway J.R. Partitioning of F and Cl between magmatic hydrothermal fluids and highly evolved granitic magmas. In: Stein H.J., and Hannah J.L. (Eds). Ore-bearing Granite Systems; Petrogenesis and Mineralizing Processes, Special Paper vol. 246 (1990), Geol. Soc. Am. 21-34
90. Webster J.D., and Mandeville C.W. Fluid immiscibility in volcanic environments. Rev. Mineral. Geochem. 65 (2007) 313-362
91. 2O and Cl solubilities in F-enriched silicate liquids; implications for volatile saturation of topaz rhyolite magmas. Contrib. Mineral. Petrol. 132 (1998) 198-207
92. Webster J.D., Kinzler R.J., and Mathez E.A. Chloride and water solubility in basalt and andesite melts and implications for magmatic degassing. Geochim. Cosmochim. Acta 63 (1999) 729-738
93. Webster J.D., Raia F., De Vivo B., and Rolandi G. The behavior of chlorine and sulfur during differentiation of the Mt. Somma-Vesuvius magmatic system. Mineral. Petrol. 73 (2001) 177-200