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54349088114
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UV/Vis titrations were also performed in 10 mm CTABr. Apart from the reduced solubility of 1 under these conditions, no significant differences were observed compared to the experiments performed with 50 mM CTABr solution.
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UV/Vis titrations were also performed in 10 mm CTABr. Apart from the reduced solubility of 1 under these conditions, no significant differences were observed compared to the experiments performed with 50 mM CTABr solution.
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17
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23
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54349097856
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In the concentration range used <0.2 mm, the CrIII salt does not interact directly with CTABr micelles, nor with 1, as proved by the absence of any changes in the chemical shift of the CTABr 1H-signals in water and of the receptor 1H-signals in a DMSO-water 1:1 mixture
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1H-signals in a DMSO-water 1:1 mixture.
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25
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54349089951
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-1, whether CTABr is present or not.
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-1, whether CTABr is present or not.
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27
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54349099575
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The NOE peaks are all negative, as expected in large and slowly tumbling systems
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The NOE peaks are all negative, as expected in large and slowly tumbling systems.
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28
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0001650729
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K. Stott, J. Keeler, Q. N. Van, A. J. Shaka, J. Magn. Reson. 1997, 125, 302-324.
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