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Volumn 9, Issue 15, 2008, Pages 2168-2171

Fluoride binding in water: A new environment for a known receptor

Author keywords

Fluorides; Micelles; NMR spectroscopy; Paramagnetic relaxation enhancement (pre); Salophen UO2

Indexed keywords

FLUORINE COMPOUNDS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; URANIUM DIOXIDE;

EID: 54349109337     PISSN: 14394235     EISSN: 14397641     Source Type: Journal    
DOI: 10.1002/cphc.200800412     Document Type: Article
Times cited : (29)

References (28)
  • 1
  • 2
    • 33746869247 scopus 로고    scopus 로고
    • For recent reviews on anion recognition see
    • For recent reviews on anion recognition see: P. A. Gale, Acc. Chem. Res. 2006, 39, 465-475;
    • (2006) Acc. Chem. Res , vol.39 , pp. 465-475
    • Gale, P.A.1
  • 16
    • 54349088114 scopus 로고    scopus 로고
    • UV/Vis titrations were also performed in 10 mm CTABr. Apart from the reduced solubility of 1 under these conditions, no significant differences were observed compared to the experiments performed with 50 mM CTABr solution.
    • UV/Vis titrations were also performed in 10 mm CTABr. Apart from the reduced solubility of 1 under these conditions, no significant differences were observed compared to the experiments performed with 50 mM CTABr solution.
  • 23
    • 54349097856 scopus 로고    scopus 로고
    • In the concentration range used <0.2 mm, the CrIII salt does not interact directly with CTABr micelles, nor with 1, as proved by the absence of any changes in the chemical shift of the CTABr 1H-signals in water and of the receptor 1H-signals in a DMSO-water 1:1 mixture
    • 1H-signals in a DMSO-water 1:1 mixture.
  • 25
    • 54349089951 scopus 로고    scopus 로고
    • -1, whether CTABr is present or not.
    • -1, whether CTABr is present or not.
  • 27
    • 54349099575 scopus 로고    scopus 로고
    • The NOE peaks are all negative, as expected in large and slowly tumbling systems
    • The NOE peaks are all negative, as expected in large and slowly tumbling systems.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.