Dehydrogenation of alcohol mixtures to esters and ketones

Industrial and Engineering Chemistry Research

Volumn 47, Issue 19, 2008, Pages 7496-7500

  Bolder, F H A ^a  

^a SASOL TECHNOLOGY PTY LTD   (South Africa)

Author keywords

[No Author keywords available]

Indexed keywords

ALDEHYDES; ATMOSPHERIC PRESSURE; ATMOSPHERIC TEMPERATURE; CATALYSIS; CATALYST ACTIVITY; DEHYDROGENATION; ESTERIFICATION; ESTERS; FISCHER-TROPSCH SYNTHESIS; KETONES; MIXTURES; ORGANIC POLYMERS;

BOILING RANGES; COMPLEX MIXTURES; DEHYDROGENATION OF ALCOHOLS; FEED MIXTURES; OXYGENATED COMPOUNDS; PROPYL PROPANOATE; REACTION PRODUCTS; SECONDARY ALCOHOLS; SECONDARY REACTIONS; TEMPERATURE RANGES;

ORGANIC COMPOUNDS;

EID: 54249148609     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie800667p     Document Type: Article

References (23)

1. Steynberg, A. P., Dry, M. E., Eds. Fischer-Tropsch Technology; Studies in Surface Science and Catalysis, Vol. 152; Elsevier: Amsterdam, 2004.
2. Kraus, M. In Handbook of Heterogeneous Catalysis, Vol. 4; Ertl, G., Knoezinger, H., Weitkamp, J., Eds.; Wiley-VCH: Weinheim, Germany, 1997.
3. Dolgov, B. N.; Koton, M. M.; Lelchuk, S. L. The synthesis of esters by the dehydrogenation of alcohols at ordinary pressure. J. Chem. Ind. (Moscow) 1935, 12, 1066.
4. Ivaanikov, P. Ya.; Gavrilova, E. Y. The catalytic transformation of alcohol. J. Appl. Chan. (USSR) 1936, 9, 490.
5. Sanchez, A. B.; Horns, N.; Fierro, J. L.G.; Ramirez de la Piscina, P. New supported Pd catalysts for the direct transformation of ethanol to ethyl acetate under medium pressure conditions. Catal. Today 2005, 107, 431.
6. Inui, K.; Kurabayasbi, T.; Sato, S.; Ichikawa, N. Effective formation of ethyl acetate from ethanol over Cu-Zn-Zr-Al-O catalyst J. Mol. Catal. 2004, 216, 147.
7. Fawcett, C. R.; Tuck, M. W. M.; Rathmell, C.; Colley, S. W. Davy Process Technology. Patent WO 0020375, 2000.
8. Colley, S. W.; Tuck, M. W. M. In Catalysis in Application; Jackson, S. D., Hargreaves, J. S. J., Lennon, D., Eds.; Royal Society of Chemistry: London, 2003; p 101.
9. 3. J. Catal. 1989, 119, 359.
10. Dalla Lana, I. G.; Vasudeva, K.; Robinson, D. B. Catalyzed reactions of n-propanol. J. Catal. 1996, 6, 100.
11. Keuler, I. N.; Lorenzen, L.; Miachon, S. The dehydrogenation of 2-butanol over copper-based catalysts: optimising catalyst composition and determining kinetic parameters. Appl. Catal., A 2001, 218, 171.
12. Inui, K.; Kurabayasbi, T.; Sato, S. Direct synthesis of ethyl acetate from ethanol carried out under pressure. J. Catal. 2002, 212, 207.
13. Bartholomew, C. H.; Farrato, R. J. Fundamentals of Industrial Catalytic Processes, 2nd Edition; Wiley-Interscience: Hoboken, NJ, 2006; Chapter 7.
14. 4. J. Catal. 1997, 169, 447.
15. Satta, A.; Shamiryan, D.; Baklanov, M. R.; Whelan, C. M.; Le, Q. T.; Beyer, G. P.; Vantomme, A.; Maex, K. The removal of copper oxides by ethyl alcohol monitored in situ by spectroscopic ellipsometry. J. Electrochem. Soc. 2003, 150, G300.
16. Sophie, A. J. L.; Sprey, H.; Soininen, P. J.; Elers, K.-E. ASM International NV. In situ reduction of copper oxide prior to silicon deposition, U.S. Patent 6,878,628, April 2005.
17. Pudney, P. D. A.; Francis, S. A.; Joyner, R. W.; Bowker, M. A molecular beam study of the oxidative dehydrogenation of alcohols on Cu(110). J. Catal. A 1991, 131 (1), 104.
18. Bowker, M.; Petts, R. W.; Waugh, K. C. Temperature-programmed desorption studies of alcohol decomposition on ZnO: 1-propanol, 1-butanol and 2-butanol. J. Catal. 1986, 99 (1), 53.
19. 2 catalysts in the dehydrogenation of ethanol. Ind. Eng. Chan. Res. 2001, 40, 5889.
20. Ertl, G.; Knoezinger, H.; Weitkamp, J. Handbook of Heterogeneous Catalysis, 2nd Edition, Vol. 6; Witey-VCH: Weinheim, Germany, 2008.
21. Leprince, P., Ed. Conversion Processes; Petroleum Refining, Vol. 3; Editions Technip: Paris, 2001, Chapter 14, p 467.
22. Koryabkina, N. A.; Phatak, A. A.; Ruettinger, W. F.; Farrauto, R. J.; Ribeiro, F. H. Determination of kinetic parameters for the water-gas shift reaction on copper catalysts under realistic conditions for fuel cell applications. J. Catal. 2003, 217, 233.
23. Iwasa, N.; Takezawa, N. Reforming of ethanol-Dehydrogenation to ethyl acetate and steam reforming to acetic acid over copper-based catalysts. Bull. Chem. Soc. Jpn. 1991, 64, 2619.