Realization of SOMO-HOMO level conversion for a TEMPO-dithiolate ligand by coordination to platinum(II)

Journal of the American Chemical Society

Volumn 130, Issue 42, 2008, Pages 13844-13845

  Kusamoto, Tetsuro ^a   Kume, Shoko ^a   Nishihara, Hiroshi ^a  

^a UNIVERSITY OF TOKYO   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

2 THIOXO 1,3 DITHIOLE 4,5 DITHIOLATE; 2,2,6,6, TETRAMETHYLPIPERIDINE 1 OXY RADICAL; COORDINATION COMPOUND; PIPERIDINE DERIVATIVE; PLATINUM DERIVATIVE; THIOL DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL STRUCTURE; COMPLEX FORMATION; CYCLIC POTENTIOMETRY; DIMERIZATION; ELECTRIC CONDUCTIVITY; ELECTROCHEMISTRY; ELECTROMAGNETIC FIELD; LIGAND BINDING; METALLATION; OXIDATION KINETICS; POLARIZATION; STRUCTURE ANALYSIS;

CRYSTALLOGRAPHY, X-RAY; CYCLIC N-OXIDES; ELECTRON SPIN RESONANCE SPECTROSCOPY; FREE RADICALS; LIGANDS; MODELS, MOLECULAR; MOLECULAR STRUCTURE; ORGANOPLATINUM COMPOUNDS; OXIDATION-REDUCTION; PLATINUM; SPECTROPHOTOMETRY, ULTRAVIOLET; STEREOISOMERISM; SULFHYDRYL COMPOUNDS;

EID: 54249087581     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja805751h     Document Type: Article

References (14)

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13. Details are described in the Supporting Information.
14. The existence of an N-O radical is also confirmed by the IR spectrum (Figure S10).