Equilibrium concentrations in membrane contactors from non-linear distribution curves: Alkali picrates extraction with a calix[4]arene

Separation and Purification Technology

Volumn 63, Issue 3, 2008, Pages 493-499

  Albaraka, Z ^a   Asfari, Z ^a   Loureiro, J M ^b   Burgard, M ^a   Trebouet D ^a  

^a UNIVERSITÉ DE STRASBOURG   (France)

^b UNIVERSITY OF PORTO   (Portugal)

Author keywords

Distribution coefficient; Hollow fibers contactor; Macrocycle extractant; Non dispersive solvent extraction

Indexed keywords

ATMOSPHERIC TEMPERATURE; CESIUM; CESIUM COMPOUNDS; CONCENTRATION (PROCESS); EQUILIBRIUM CONSTANTS; EXTRACTION; HEAVY METAL ALLOYS; IONIC STRENGTH; LIGHT METALS; MEMBRANES; METAL RECOVERY; PHASE EQUILIBRIA; SOLVENTS; TOLUENE;

ALKALI CHLORIDES; ALKALI METAL PICRATES; AQUEOUS PHASES; CALCULATED VALUES; CALIX[4]ARENE; CALIXARENE COMPLEXES; CESIUM CHLORIDES; CLOSED SYSTEMS; DECANOL; DISTRIBUTION COEFFICIENT; DISTRIBUTION COEFFICIENTS; EQUILIBRIUM CONCENTRATIONS; EQUILIBRIUM DISTRIBUTIONS; EXTRACTION ISOTHERMS; EXTRACTION KINETICS; HOLLOW FIBERS CONTACTOR; HYDROPHILIC; INITIAL CONCENTRATIONS; LINEAR DISTRIBUTIONS; MACROCYCLE EXTRACTANT; MASS ACTION LAWS; MASS BALANCES; MEMBRANE CONTACTORS; MEMBRANE PORES; MODELING; NON-DISPERSIVE SOLVENT EXTRACTION; ORGANIC; PHASE SATURATIONS; REACTION EQUILIBRIUM CONSTANTS;

SOLVENT EXTRACTION;

EID: 54049130379     PISSN: 13835866     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.seppur.2008.06.015     Document Type: Review

References (25)

1. Dumazet-Bonnamour I., Halouani H., Oueslati F., and Lamartine R. Calixarenes for metal cations extraction. Comptes Rendus Chimie 8 (2005) 881-891
2. Deligoz H., and Erdem E. Comparative studies on the solvent extraction of transition metal cations by calixarene, phenol and ester derivatives. J. Hazard. Mater. 154 1-3 (2008) 29-32
3. Kumar A., Mohapatra P.K., Pathak P.N., and Manchanda V.K. Dicyclohexano 18 crown 6 in butanol-octanol mixture: a promising extractant of Sr(II) from nitric acid medium. Talanta 45 (1997) 387-395
4. Asfari Z., Bressot C., Vicens J., Hill C., Dozol J.F., Rouquette H., Eymard S., Lamare V., and Tournois B. Doubly crowned calix[4]arenes in the 1,3-alternate conformation as cesium-selective carriers in supported liquid membranes. Anal. Chem. 67 (1995) 3133
5. Mohapatra P.K., Ansari S.A., Sarkar A., Bhattacharyya A., and Manchanda V.K.V.K. Evaluation of calix-crown ionophores for selective separation of radio-cesium from acidic nuclear waste solution. Anal. Chim. Acta 571 (2006) 308-314
6. Mariani M., Macerata E., Galletta M., Buttafava A., Casnati A., Ungaro R., Faucitano A., and Giola M. Partitioning of minor actinides: effects of gamma irradiation on the extracting capabilities of a selected calixarene-based picolinamide ligand. Radiat. Phys. Chem. 76 (2007) 1285-1289
7. Yaftian M.R., Burgard M., C B. Dieleman, D. Matt, rare-earth metal ion separation using a supported liquid membrane mediated by a narrow rim phosphorylated calix[4]arene. J. Membr. Sci. 144 (1998) 57
8. Kim J.K., Kim J.S., Shul Y.G., Lee K.W., and Oh W.Z. Selective extraction of cesium ion with cali[4]arene crown ether through thin sheet supported liquid membrane. J. Membr. Sci. 187 (2001) 3-11
9. Duhart A., Dozol J.F., Rouquette H., and Deratani A. Selective removal of cesium from model nuclear waste solutions using a solid membrane composed of an unsymmetrical calix[4]arene-bis-crown-6 bonded to an immobilized polysiloxane backbone. J. Membr. Sci. 185 (2001) 145-155
10. Pabby A.K., and Sastre A.-M. Developments in dispersion-free membrane-based extraction-separation processes. Ion Exchange Solvent Extract. 15 (2002) 331-469
11. Rydberg J., Cox M., Musikas C., and Choppin G.R. Solvent Extraction Principles and Practices. 2nd ed. (2004), Marcel Dekker, Inc., New York
12. Kathios D.J., Jarvinen G.D., Yarbro S.L., and Smith B.F. A preliminary evaluation of microporous hollow fiber membrane modules for the liquid-liquid extraction of actinides. J. Membr. Sci. 97 (1994) 251-261
13. Geist A. Small-scale actinide(III) partitioning processes in miniature hollow fibre modules. Radiochim. Acta 93 (2005) 197
14. Kubota F., Kakoi T., Goto M., Furusaki S., Nakashio F., and Hano T. Permeation behavior of rare earth metals with a calix[4]arene carboxyl derivative in a hollow-fiber membrane. J. Membr. Sci. 165 (2000) 149-158
15. Haddaoui J., Trebouet D., Loureiro J.M., and Burgard M. Non-dispersive solvent extraction of alkali metals with the dicyclohexano 18 crown 6: evaluation of mass transfer coefficients. Sep. Sci. Technol. 39 (2004) 3839-3858
16. Kao H.C., and Juang R.S. Kinetic analysis of non-dispersive solvent extraction of concentrated Co(II) from chloride solutions with Aliquat 336: significance of the knowledge of reaction equilibrium. J. Membr. Sci. 264 (2005) 104-112
17. Trebouet D., Burgard M., and Loureiro J.M. Guidelines for the application of a stationary model in the prediction of the overall mass transfer coefficient in a hollow fiber membrane contactor. Sep. Purif. Technol. 50 (2006) 97-106
18. Hill C., Dozol J.F., Rouquette H., Eymard S., and Tournois B. Study of the stability of some supported liquid membranes. J. Membr. Sci. 114 (1996) 73-80
19. Kikuchi Y., and Sakamoto Y. Complex formation of alkali metal ions with 18-crown-6 and its derivatives in 1,2-dichloroethane. Anal. Chim. Acta 403 (2000) 325-332
20. Talanova G.G., Elkarim N.S., Talanov V.S., Hanes R.E., Hwang H.S., Bartsch R.A., and Rogers R.D. The "picrate effect" on extraction selectivities of aromatic group-containing crown ethers for alkali metal cations. J. Am. Chem. Soc. 121 (1999) 11281-11290
21. Asfari Z., Weiss J., Pappalardo S., and Vicens J. Synthesis and properties of double-calix[4]arenes, doubly-crowned calix[4]arenes, and double-calix-crowns. Pure Appl. Chem. 65 (1993) 585-590
22. Albaraka Z., Trebouet D., Tuna M., Loureiro J.M., and Burgard M. An analysis of the mass transfer in non-dispersive solvent extraction closed system. Int. J. Chem. Reactor Eng. 6 (2008)
23. Casnati A., Pochini A., Ungaro R., Ugozzoli F., Arnaud F., Fanni S., Schwing M.-J., Egberink R.J.M., De Jong F., and Reinhoudt D.N. Synthesis, complexation, and membrane transport studies of 1, 3-alternate calix[4]arene-crown-6 conformers: a new class of cesium selective ionophores. J. Am. Chem. Soc. 117 (1995) 2767-2777
24. 2) in water by different types of activated carbon-equilibrium, dynamics, and mathematical modelling. J. Environ. Eng. 133 3 (2007) 294-302
25. Dozol J.F., Casas J., and Sastre A.M. Influence of the extractant on strontium transport from reprocessing concentrate solutions through flat-sheet supported liquid membranes. Sep. Sci. Technol. 29 (1994) 1999-2018