Synthesis of alkyl 2,5-dihydro-5-oxofuran-2-carboxylates via palladium-catalyzed carbonylative cyclization of β-bromovinyl aldehydes in alcohols

Journal of Organometallic Chemistry

Volumn 693, Issue 24, 2008, Pages 3677-3680

  Cho, Chan Sik ^a   Kim, Jun Uk ^a   Choi, Heung Jin ^a  

^a Kyungpook National University   (South Korea)

Author keywords

Bromovinyl aldehydes; Alcohols; Carbon monoxide; Carbonylative cyclization; Lactones; Palladium catalyst

Indexed keywords

ALDEHYDES; ALKYLATION; CARBON MONOXIDE; CARBOXYLATION; CATALYSIS; CATALYSTS; CYCLIZATION; PALLADIUM;

CARBONYLATIVE CYCLIZATION; CATALYTIC AMOUNTS; CATALYTIC PROCESSES; FORMYL GROUPS; GOOD YIELDS; INTRAMOLECULAR ADDITIONS; LACTONES; PALLADIUM CATALYST; PALLADIUM CATALYSTS; REACTION PATHWAYS; SYNTHESIS OF;

ORGANIC COMPOUNDS;

EID: 54049117509     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2008.09.014     Document Type: Short Survey

References (34)

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32. C-D = 22.9 Hz)] was formed in 36% yield along with 2b (36% yield).
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34. A reviewer suggested that observation of oxidation products derived from β-hydrogen elimination of alcohol should be described. However, GLC analysis attempt to detect an aldehyde from crude mixture met with failure.