A total synthesis of (+)-isolaurepan

Tetrahedron Letters

Volumn 49, Issue 49, 2008, Pages 7012-7014

  Tripathi, Divya ^a   Kumar, Pradeep ^a  

^a NATIONAL CHEMICAL LABORATORY   (India)

Author keywords

Cis selective cyclization; Cyclic ethers; Isolaurepan; Oxepanes; Oxidative resolution of secondary alcohols

Indexed keywords

ISOLAUREPAN; OXEPANE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL STRUCTURE; CYCLIZATION; ENANTIOSELECTIVITY; SYNTHESIS;

EID: 54049090307     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2008.09.134     Document Type: Article

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26. 3 (322.48): C, 74.49; H, 10.63. Found: C, 74.26; H, 10.85.
27. The ee was measured by HPLC using a Chiralcel OD column (isopropyl alcohol/petroleum ether = 1:99); flow, 1.0 ml/min.
28. 2Si (356.66): C, 70.72; H, 12.43. Found: C, 70.58; H, 12.61.
29. 3): δ 14.0, 19.4, 22.6, 25.3, 26.2, 29.3, 31.8, 36.8, 36.9, 37.4, 39.6, 80.0, 80.3.