Novel mechanistic aspects on the reaction between low spin Fe(II) Schiff base amino acid complexes and hydrogen peroxide-Spectrophotometric tracer of intraperoxo intermediate catalyzed reaction

Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy

Volumn 71, Issue 3, 2008, Pages 921-928

  Awad, Aida M ^a   Shaker, Ali Mohamad ^a   Zaki, Ahmad Borhan El Din ^b   Nassr, Lobna Abdel Mohsen Ebaid ^a  

^a Sohag University   (Egypt)

^b Tanta University   (Egypt)

Author keywords

Amino acids; Fe(II); Hydrogen peroxide; Kinetic mechanism; Schiff base

Indexed keywords

AMINATION; AMINES; AMINO ACIDS; HYDROGEN; HYDROGEN PEROXIDE; ORGANIC ACIDS; OXIDATION; SOLUTIONS;

AQUEOUS SOLUTIONS; FE; FE(II); FIRST-ORDER KINETICS; INNER-SPHERE ELECTRON; KINETIC MECHANISM; KINETICS AND MECHANISMS; L-LEUCINE; L-METHIONINE; L-SERINE; MECHANISTIC ASPECTS; PSEUDO-FIRST-ORDER CONDITIONS; REVERSIBLE FORMATION; SALICYL ALDEHYDE; SCHIFF BASE; SCHIFF-BASE COMPLEXES;

REACTION KINETICS;

AMINO ACID; HYDROGEN PEROXIDE; IRON; LIGAND; SCHIFF BASE; WATER;

ARTICLE; CHEMICAL MODEL; CHEMICAL STRUCTURE; CHEMISTRY; KINETICS; PH; SOLUTION AND SOLUBILITY; SPECTROPHOTOMETRY; ULTRAVIOLET SPECTROPHOTOMETRY;

AMINO ACIDS; HYDROGEN PEROXIDE; HYDROGEN-ION CONCENTRATION; IRON; KINETICS; LIGANDS; MODELS, CHEMICAL; MOLECULAR STRUCTURE; SCHIFF BASES; SOLUTIONS; SPECTROPHOTOMETRY; SPECTROPHOTOMETRY, ULTRAVIOLET; WATER;

EID: 53849146392     PISSN: 13861425     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.saa.2008.02.012     Document Type: Article

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