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Volumn 634, Issue 5, 2008, Pages 829-831

Well-ordered crystals of TaI5. The formation of the ternary iodide CsTaI6

Author keywords

Crystal structure; Iodide; Tantalum

Indexed keywords


EID: 53849121260     PISSN: 00442313     EISSN: 15213749     Source Type: Journal    
DOI: 10.1002/zaac.200700530     Document Type: Article
Times cited : (2)

References (18)
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    • 2) was applied for five days after which a dark crystalline substance was secured in an argon-filled dry box.
    • 2) was applied for five days after which a dark crystalline substance was secured in an argon-filled dry box.
  • 5
    • 53849116924 scopus 로고    scopus 로고
    • 3 (0.3 mmol), were filled under dry-box conditions in a sealed tantalum tube which was then jacketed by an evacuated Duran® glass ampoule. The ensemble was heated to 390°C for five days and then cooled slowly to room temperature.
    • 3 (0.3 mmol), were filled under dry-box conditions in a sealed tantalum tube which was then jacketed by an evacuated Duran® glass ampoule. The ensemble was heated to 390°C for five days and then cooled slowly to room temperature.
  • 7
    • 53849133560 scopus 로고    scopus 로고
    • Suitable single crystals of both TaI5 and CsTaI6 were selected under a microscope in a dry box and sealed in thin-walled glass capillaries. The single crystals were transferred to a single-crystal X-ray diffractometer (Stoe Image Plate Diffraction System, IPDS I) to collect a complete intensity data set at ambient temperature. Structure solution and refinement was performed with the programs SHELXS-97 (direct methods) and SHELXL-97 [7, scattering factors were from International Tables for X-ray Crystallogaphy [8, Data corrections were carried out for Lorentz and polarization factors and absorption (numerical with the aid of the programs XRED and X-SHAPE [9, Further details of the crystal structure determinations may be obtained from the Fachinformationszentrum Karlsruhe, D-76344 Eggenstein-Leopoldshafen, Germany (fax:, 49)7247-808-666; e-mail: crysdata@fizkarlsruhe.de, on quoting the depository numbers ICSD-418486 (TaI5) and ICSD-418487 CsTaI
    • all = 1.051; for atomic parameters see Table 1.
  • 8
    • 53849149451 scopus 로고    scopus 로고
    • G.M. Sheldrick, SHELXS-97, Program for Structure Analysis, Universität Göttingen, Germany, 1998;
    • G.M. Sheldrick, SHELXS-97, Program for Structure Analysis, Universität Göttingen, Germany, 1998;
  • 9
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    • SHELXL-97, Program for Crystal Structure Refinement, Universität Göttingen, Germany, 1997.
    • SHELXL-97, Program for Crystal Structure Refinement, Universität Göttingen, Germany, 1997.
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    • A. J. C. Wilson ed, Kluwer Acad. Publ, Dordrecht
    • A. J. C. Wilson (ed.), International Tables for Crystallography, Vol. C, Kluwer Acad. Publ., Dordrecht, 1992.
    • (1992) International Tables for Crystallography , vol.100
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    • X-RED 1.22, Stoe Data Reduction Program (C), Stoe & Cie GmbH, Darmstadt, 2001;
    • X-RED 1.22, Stoe Data Reduction Program (C), Stoe & Cie GmbH, Darmstadt, 2001;
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    • X-Shape 1.06, Crystal Optimization for Numerical Absorption Correction (C), STOE & Cie GmbH, Darmstadt, 1999.
    • X-Shape 1.06, Crystal Optimization for Numerical Absorption Correction (C), STOE & Cie GmbH, Darmstadt, 1999.
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    • H.-Chr. Gaebell, G. Meyer, R. Hoppe, Z. Anorg. Allg. Chem. 1982, 493, 65.
    • H.-Chr. Gaebell, G. Meyer, R. Hoppe, Z. Anorg. Allg. Chem. 1982, 493, 65.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.