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4
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-
53849109285
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2) was applied for five days after which a dark crystalline substance was secured in an argon-filled dry box.
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2) was applied for five days after which a dark crystalline substance was secured in an argon-filled dry box.
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-
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5
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53849116924
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3 (0.3 mmol), were filled under dry-box conditions in a sealed tantalum tube which was then jacketed by an evacuated Duran® glass ampoule. The ensemble was heated to 390°C for five days and then cooled slowly to room temperature.
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3 (0.3 mmol), were filled under dry-box conditions in a sealed tantalum tube which was then jacketed by an evacuated Duran® glass ampoule. The ensemble was heated to 390°C for five days and then cooled slowly to room temperature.
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6
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0003426931
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S, F. Enke-Verlag, Stuttgart
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G. Brauer, Handbuch der Präparativen Anorganischen Chemie, Band II, S. 1152, F. Enke-Verlag, Stuttgart, 1962.
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(1962)
Handbuch der Präparativen Anorganischen Chemie, Band II
, pp. 1152
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Brauer, G.1
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7
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53849133560
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Suitable single crystals of both TaI5 and CsTaI6 were selected under a microscope in a dry box and sealed in thin-walled glass capillaries. The single crystals were transferred to a single-crystal X-ray diffractometer (Stoe Image Plate Diffraction System, IPDS I) to collect a complete intensity data set at ambient temperature. Structure solution and refinement was performed with the programs SHELXS-97 (direct methods) and SHELXL-97 [7, scattering factors were from International Tables for X-ray Crystallogaphy [8, Data corrections were carried out for Lorentz and polarization factors and absorption (numerical with the aid of the programs XRED and X-SHAPE [9, Further details of the crystal structure determinations may be obtained from the Fachinformationszentrum Karlsruhe, D-76344 Eggenstein-Leopoldshafen, Germany (fax:, 49)7247-808-666; e-mail: crysdata@fizkarlsruhe.de, on quoting the depository numbers ICSD-418486 (TaI5) and ICSD-418487 CsTaI
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all = 1.051; for atomic parameters see Table 1.
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8
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53849149451
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G.M. Sheldrick, SHELXS-97, Program for Structure Analysis, Universität Göttingen, Germany, 1998;
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G.M. Sheldrick, SHELXS-97, Program for Structure Analysis, Universität Göttingen, Germany, 1998;
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9
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53849144424
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SHELXL-97, Program for Crystal Structure Refinement, Universität Göttingen, Germany, 1997.
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SHELXL-97, Program for Crystal Structure Refinement, Universität Göttingen, Germany, 1997.
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10
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0003872738
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A. J. C. Wilson ed, Kluwer Acad. Publ, Dordrecht
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A. J. C. Wilson (ed.), International Tables for Crystallography, Vol. C, Kluwer Acad. Publ., Dordrecht, 1992.
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(1992)
International Tables for Crystallography
, vol.100
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11
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53849109702
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X-RED 1.22, Stoe Data Reduction Program (C), Stoe & Cie GmbH, Darmstadt, 2001;
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X-RED 1.22, Stoe Data Reduction Program (C), Stoe & Cie GmbH, Darmstadt, 2001;
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12
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53849084252
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X-Shape 1.06, Crystal Optimization for Numerical Absorption Correction (C), STOE & Cie GmbH, Darmstadt, 1999.
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X-Shape 1.06, Crystal Optimization for Numerical Absorption Correction (C), STOE & Cie GmbH, Darmstadt, 1999.
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16
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84983967537
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H.-Chr. Gaebell, G. Meyer, R. Hoppe, Z. Anorg. Allg. Chem. 1982, 493, 65.
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H.-Chr. Gaebell, G. Meyer, R. Hoppe, Z. Anorg. Allg. Chem. 1982, 493, 65.
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17
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24444468120
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H. Henke, E. Buschmann, H. Bärnighausen, Acta Crystallogr. 1973, B29, 2622.
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(1973)
Acta Crystallogr
, vol.B29
, pp. 2622
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Henke, H.1
Buschmann, E.2
Bärnighausen, H.3
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