-
2
-
-
33746903669
-
-
2nd ed, Ed, R. B. King, Wiley, Chichester
-
b) R. Pöttgen, W. Hönle, H. G. von Schnering in Encyclopedia of Inorganic Chemistry, Vol. VIII, 2nd ed. (Ed.: R. B. King), Wiley, Chichester, 2005, pp. 4255-4308;
-
(2005)
Encyclopedia of Inorganic Chemistry
, vol.8
, pp. 4255-4308
-
-
Pöttgen, R.1
Hönle, W.2
von Schnering in, H.G.3
-
4
-
-
31444435025
-
-
Angew. Chem. Int. Ed. 2006, 45, 699-700;
-
(2006)
Angew. Chem. Int. Ed
, vol.45
, pp. 699-700
-
-
-
5
-
-
34250877807
-
-
d) A. J. Karttunen, M. Linnolahti, T. A. Pakkanen, Chem. Eur. J. 2007, 13, 5232-5237.
-
(2007)
Chem. Eur. J
, vol.13
, pp. 5232-5237
-
-
Karttunen, A.J.1
Linnolahti, M.2
Pakkanen, T.A.3
-
6
-
-
14844317403
-
-
H. Okudera, R. E. Dinnebier, A. Simon, Z. Kristallogr. 2005, 220, 259-264.
-
(2005)
Z. Kristallogr
, vol.220
, pp. 259-264
-
-
Okudera, H.1
Dinnebier, R.E.2
Simon, A.3
-
8
-
-
1642575790
-
-
b) H. Hartl, Angew. Chem. 1995, 107, 2857-2859;
-
(1995)
Angew. Chem
, vol.107
, pp. 2857-2859
-
-
Hartl, H.1
-
12
-
-
31444433664
-
-
M. Ruck, D. Hoppe, B. Wahl, P. Simon, Y. Wang, G. Seifert, Angew. Chem. 2005, 117, 7788-7792;
-
(2005)
Angew. Chem
, vol.117
, pp. 7788-7792
-
-
Ruck, M.1
Hoppe, D.2
Wahl, B.3
Simon, P.4
Wang, Y.5
Seifert, G.6
-
13
-
-
28244482587
-
-
Angew. Chem. Int. Ed. 2005, 44, 7616-7619.
-
(2005)
Angew. Chem. Int. Ed
, vol.44
, pp. 7616-7619
-
-
-
14
-
-
36849129963
-
-
R. Hultgren, N. S. Gingrich, B. E. J. Warren, J. Chem. Phys. 1935, 3, 351-355.
-
(1935)
J. Chem. Phys
, vol.3
, pp. 351-355
-
-
Hultgren, R.1
Gingrich, N.S.2
Warren, B.E.J.3
-
15
-
-
0021507208
-
-
a) G. Fasol, M. Cardona, W. Hönle, H. G. von Schnering, Solid State Commun. 1984, 52, 307-310;
-
(1984)
Solid State Commun
, vol.52
, pp. 307-310
-
-
Fasol, G.1
Cardona, M.2
Hönle, W.3
von Schnering, H.G.4
-
20
-
-
14744297484
-
-
a) A. Pfitzner, M. F. Bräu, J. Zweck, G. Brunklaus, H. Eckert, Angew. Chem. 2004, 116, 4324-4327;
-
(2004)
Angew. Chem
, vol.116
, pp. 4324-4327
-
-
Pfitzner, A.1
Bräu, M.F.2
Zweck, J.3
Brunklaus, G.4
Eckert, H.5
-
21
-
-
4544344822
-
-
Angew. Chem. Int. Ed. 2004, 43, 4228-4231;
-
(2004)
Angew. Chem. Int. Ed
, vol.43
, pp. 4228-4231
-
-
-
22
-
-
14844302863
-
-
b) M. Ruck, D. Hoppe, P. Simon, Z. Kristallogr. 2005, 220, 265-268.
-
(2005)
Z. Kristallogr
, vol.220
, pp. 265-268
-
-
Ruck, M.1
Hoppe, D.2
Simon, P.3
-
23
-
-
33344457421
-
-
M. Kanatzidis, R. Pöttgen, W. Jeitschko, Angew. Chem. 2005, 117, 7156-7184;
-
(2005)
Angew. Chem
, vol.117
, pp. 7156-7184
-
-
Kanatzidis, M.1
Pöttgen, R.2
Jeitschko, W.3
-
24
-
-
27744569143
-
-
Angew. Chem. Int. Ed. 2005, 44, 6996-7023.
-
(2005)
Angew. Chem. Int. Ed
, vol.44
, pp. 6996-7023
-
-
-
26
-
-
31144444052
-
-
S. Lange, C. P. Sebastian, T. Nilges, Z. Anorg. Allg. Chem. 2006, 632, 195-203.
-
(2006)
Z. Anorg. Allg. Chem
, vol.632
, pp. 195-203
-
-
Lange, S.1
Sebastian, C.P.2
Nilges, T.3
-
27
-
-
34249659907
-
-
S. Lange, P. Schmidt, T. Nilges, Inorg. Chem. 2007, 46, 4028-4035.
-
(2007)
Inorg. Chem
, vol.46
, pp. 4028-4035
-
-
Lange, S.1
Schmidt, P.2
Nilges, T.3
-
28
-
-
52649143740
-
-
Black Phosphorus is commercially available: http://www.chem-pur.de. See also: T. Nilges, M. Kersting, T. Pfeiffer, J. Solid State Chem. 2008, DOI: 10.1016/j.jssc.2008.03.008.
-
Black Phosphorus is commercially available: http://www.chem-pur.de. See also: T. Nilges, M. Kersting, T. Pfeiffer, J. Solid State Chem. 2008, DOI: 10.1016/j.jssc.2008.03.008.
-
-
-
-
29
-
-
85055393640
-
Chemische Transportreaktionen in Monographien zu "Angewandte Chemie" und "Chemie-Ingenieur-Technik
-
Weinheim
-
H. Schäfer, Chemische Transportreaktionen in Monographien zu "Angewandte Chemie" und "Chemie-Ingenieur-Technik", Verlag Chemie, Weinheim, 1962, No. 76, p. 67.
-
(1962)
Verlag Chemie
, Issue.76
, pp. 67
-
-
Schäfer, H.1
-
30
-
-
30744444696
-
-
M.-P. Bichat, J.-L. Pascal, F. Gillot, F. Favier, Chem. Mater. 2005, 17, 6761-6771.
-
(2005)
Chem. Mater
, vol.17
, pp. 6761-6771
-
-
Bichat, M.-P.1
Pascal, J.-L.2
Gillot, F.3
Favier, F.4
-
31
-
-
10844225408
-
-
M.-P. Bichat, T. Politova, J. L. Pascal, F. Favier, L. Monconduit, J. Electrochem. Soc. 2004, 151, A2074-A2081.
-
(2004)
J. Electrochem. Soc
, vol.151
-
-
Bichat, M.-P.1
Politova, T.2
Pascal, J.L.3
Favier, F.4
Monconduit, L.5
-
33
-
-
84981776940
-
-
H. Schlenger, H. Jacobs, R. Juza, Z. Anorg. Allg. Chem. 1971, 385, 177-201.
-
(1971)
Z. Anorg. Allg. Chem
, vol.385
, pp. 177-201
-
-
Schlenger, H.1
Jacobs, H.2
Juza, R.3
-
35
-
-
53549117227
-
-
X-ray powder diffraction data were collected by using a Stoe STADIP powder diffractometer fitted with CuKα1 radiation (λ, 1.54051 Å, germanium monochromator, transmission geometry, 298 K, 7.0 < 2θ < 70.0°, linear 5° PSD (Braun, A comparison of calculated and measured powder diffractograms of the samples is given in the Supporting Information. Lattice parameters derived from the powder data were used for the single-crystal structure determinations. Semiquantitative EDX analyses were performed by using a Leica 420i scanning electron microscope (Zeiss) fitted with an energy-dispersive detector unit (EDX, Oxford, Cu, In, and GaP were used as standards for calibration. A voltage of 20 kV was applied to the samples. Data were averaged for more than five independent measurements collected from crystals separated from different reaction batches. Cu 2P20 (in atom , Cu 9(2, P 912, calcd: Cu 9.1, P 90.9; Cu5
-
16 is stable in air for several months and can stored without the need for an inert gas atmosphere.
-
-
-
-
36
-
-
53549129817
-
-
Crystallographic data for Cu2P20: M, 746.6 g mol-1; dark red, nontransparent crystals, 0.01 x 0.02 x 1.0 mm3, triclinic, space group P1, a, 7.131(4, b, 11.437(4, c, 11.750(4) Å, α, 68.53(3, β, 83.60(4, γ, 84.39(4)°, V, 884.6(7) Å3, Z, 2, ρcalcd, 2.80 g cm-3, Stoe IPDS II, Mo Kα radiation (λ, 0.71073 Å, graphite monochromator, F(000, 716, μ, 4.2 mm-1, T, 293(1) K, 2487 independent reflections between 1.87 < θ < 26.74°, 1939 reflections I > 3σI, and 199 parameters, Rint, 0.0321, numerical absorption correction, full-matrix least-squares refinement against F2 with Jana 2000,[22c] R1, 0.0585, wR2, 0.0818 for I > 3σI and R
-
[22c] R1 = 0.0585, wR2 = 0.0818 for I > 3σI and R1 = 0.0792, wR2 = 0.0837 for all data.
-
-
-
-
37
-
-
53549107019
-
-
Crystallographic data for Cu5InP16: refined composition Cu4.9(1)In1.1(1)P16; M, 933.9 g mol-1; dark red, nontransparent crystal 0.45 x 0.40 x 0.18 mm3, monoclinic, space group C2/c, a, 11.124(3, b, 9.663(3, c, 7.533(2) Å, β, 109.96(1)°, V, 761.1(3) Å3, Z, 2, ρcalcd, 4.07 g cm-3, Stoe IPDS II, MoKα-radiation (λ, 0.71073 Å, graphite monochromator, F(000, 872, μ, 10.0 mm-1, T, 293(1) K, 642 independent reflections between 2.87 < θ < 29.17°, 362 reflections I > 3σI, and 53 parameters, Rint, 0.0450, numerical absorption correction, full-matrix least-squares refinement against F2 with Jana 2000,[22c] R1, 0.0240, wR2, 0.0386 for I
-
16);
-
-
-
-
38
-
-
0003612402
-
-
Institute of Physics: Praha, Czech Republic
-
c) V. Petricek, M. Dusek, L. Palatinus, JANA2000, The Crystallographic Computing System; Institute of Physics: Praha, Czech Republic, 2000.
-
(2000)
The Crystallographic Computing System
-
-
Petricek, V.1
Dusek, M.2
Palatinus, L.3
JANA4
-
44
-
-
53549114587
-
-
Magnetic measurements were performed by using a commercially available physical property measurement system PPMS Quantum Design, The samples for magnetic measurements were mounted on a VSM sample holder and measured in the temperature range from 5 to 305 K. For details see Supporitng Information
-
Magnetic measurements were performed by using a commercially available physical property measurement system PPMS (Quantum Design). The samples for magnetic measurements were mounted on a VSM sample holder and measured in the temperature range from 5 to 305 K. For details see Supporitng Information.
-
-
-
-
45
-
-
53549127378
-
-
The electronic structure was calculated based on the experimental structure data by applying the LCAO scheme as implemented in CRYSTAL06 [25a,b] within the framework of density functional theory (DFT, 25c] Calculations were performed with the GGA functional PBE, 25d] A shrinking factor scheme of 4 4 resulting in 36 k-points for the IBZ and 260 points for the Gilat net was used. The electronic structure input was given by all-electron basis sets according to Doll et al, 25e] for Cu and Zicovich-Wilson et al. for P.[25f] Additional information on the computational procedure can be found in reference [25g] and in the Supporting Information; a) R. Dovesi, V. R. Saunders, C. Roetti, R. Orlando, C. M. Zicovich-Wilson, F. Pascale, B. Civalleri, K. Doll, N. M. Harrison, I. J. Bush, Ph. D'Arco, M. Llunell, CRYSTAL06, Torino, Italy, 2007;
-
[25f] Additional information on the computational procedure can be found in reference [25g] and in the Supporting Information; a) R. Dovesi, V. R. Saunders, C. Roetti, R. Orlando, C. M. Zicovich-Wilson, F. Pascale, B. Civalleri, K. Doll, N. M. Harrison, I. J. Bush, Ph. D'Arco, M. Llunell, CRYSTAL06, Torino, Italy, 2007;
-
-
-
-
47
-
-
0030271016
-
-
c) M. D. Towler, M. Causa, A. Zupan, Comput. Phys. Commun. 1996, 98, 181;
-
(1996)
Comput. Phys. Commun
, vol.98
, pp. 181
-
-
Towler, M.D.1
Causa, M.2
Zupan, A.3
-
48
-
-
4243943295
-
-
d) J. P. Perdew, K. Burke, M. Ernzerhof, Phys. Rev. Lett. 1996, 77, 3865-3868;
-
(1996)
Phys. Rev. Lett
, vol.77
, pp. 3865-3868
-
-
Perdew, J.P.1
Burke, K.2
Ernzerhof, M.3
-
50
-
-
0037080915
-
-
f) C. M. Zicovich-Wilson, A. Bert, C. Roetti, R. Dovesi, V. R. Saunders, J. Chem. Phys. 2002, 116, 1120-1127;
-
(2002)
J. Chem. Phys
, vol.116
, pp. 1120-1127
-
-
Zicovich-Wilson, C.M.1
Bert, A.2
Roetti, C.3
Dovesi, R.4
Saunders, V.R.5
-
51
-
-
20444493258
-
-
g) R. Weihrich, I. Anusca, M. Zabel, Z. Anorg. Allg. Chem. 2005, 631, 1463.
-
(2005)
Z. Anorg. Allg. Chem
, vol.631
, pp. 1463
-
-
Weihrich, R.1
Anusca, I.2
Zabel, M.3
-
52
-
-
53549092843
-
-
8 unit is given in the Supporting Information.
-
8 unit is given in the Supporting Information.
-
-
-
-
53
-
-
53549096326
-
-
An overview on the topological relationship between polyphosphides and ultraphosphates can be found in: R. Glaum, Neue Untersuchungen an wasserfreien Phosphaten der Übergangsmetalle, Habilitationsschrift, Universisty Gießen, 1999, p. 86
-
An overview on the topological relationship between polyphosphides and ultraphosphates can be found in: R. Glaum, Neue Untersuchungen an wasserfreien Phosphaten der Übergangsmetalle, Habilitationsschrift, Universisty Gießen, 1999, p. 86.
-
-
-
-
54
-
-
53549088420
-
-
16 is given in the Supporting Informaiton; a) A. Olbertz, D. Stachel, I. Svoboda, H. Fuess, Acta Crystallogr. Sect. C 1995, 51, 1047-1049;
-
16 is given in the Supporting Informaiton; a) A. Olbertz, D. Stachel, I. Svoboda, H. Fuess, Acta Crystallogr. Sect. C 1995, 51, 1047-1049;
-
-
-
-
55
-
-
0002172733
-
-
b) O. V. Yakubovich, O. V. Dimitrova, A. I. Vidrevich, Kristallografiya 1993, 38, 77-85.
-
(1993)
Kristallografiya
, vol.38
, pp. 77-85
-
-
Yakubovich, O.V.1
Dimitrova, O.V.2
Vidrevich, A.I.3
-
56
-
-
84942498237
-
-
[29c] with X = Cl, Br. a A. V. Shevelkov, E. V. Dikarev, B. A. Popovkin, Z. Kristallogr. 1994, 209, 583-585;
-
[29c] with X = Cl, Br. a) A. V. Shevelkov, E. V. Dikarev, B. A. Popovkin, Z. Kristallogr. 1994, 209, 583-585;
-
-
-
-
57
-
-
33748887438
-
-
b) A. V. Shevelkov, M. Yu. Mustyakimov, E. V. Dikarev, B. A. Popovkin, J. Chem. Soc. Dalton Trans. 1996, 147;
-
(1996)
J. Chem. Soc. Dalton Trans
, pp. 147
-
-
Shevelkov, A.V.1
Mustyakimov, M.Y.2
Dikarev, E.V.3
Popovkin, B.A.4
-
58
-
-
0002412736
-
-
c) A. V. Shevelkov, E. V. Dikarev, B. A. Popovkin, J. Solid State Chem. 1993, 104, 177-180.
-
(1993)
J. Solid State Chem
, vol.104
, pp. 177-180
-
-
Shevelkov, A.V.1
Dikarev, E.V.2
Popovkin, B.A.3
-
59
-
-
2442686516
-
-
S. Jörgens, D. Johrendt, A. Mewis, Chem. Eur. J. 2003, 9, 2405-2410.
-
(2003)
Chem. Eur. J
, vol.9
, pp. 2405-2410
-
-
Jörgens, S.1
Johrendt, D.2
Mewis, A.3
-
60
-
-
41249088070
-
-
DOI: 10.1016/j.jssc.2008.01.003
-
F. Phillipp, P. Schmidt, E. Milke, M. Binnewies, S. Hoffmann, J. Solid State Chem. 2008, DOI: 10.1016/j.jssc.2008.01.003.
-
(2008)
J. Solid State Chem
-
-
Phillipp, F.1
Schmidt, P.2
Milke, E.3
Binnewies, M.4
Hoffmann, S.5
-
61
-
-
33745589276
-
-
[32d] (Q = Te, Se, S; X = Cl, Br); a) S. Lange, T. Nilges, Chem. Mater. 2006, 18, 2538-2544;
-
[32d] (Q = Te, Se, S; X = Cl, Br); a) S. Lange, T. Nilges, Chem. Mater. 2006, 18, 2538-2544;
-
-
-
-
62
-
-
33947713084
-
-
b) S. Lange, M. Bawohl, D. Wilmer, H.-W. Meyer, H.-D. Wiemhöfer, T. Nilges, Chem. Mater. 2007, 19, 1401-1410;
-
(2007)
Chem. Mater
, vol.19
, pp. 1401-1410
-
-
Lange, S.1
Bawohl, M.2
Wilmer, D.3
Meyer, H.-W.4
Wiemhöfer, H.-D.5
Nilges, T.6
-
63
-
-
34548636638
-
-
c) T. Nilges, M. Bawohl, S. Lange, Z. Naturforsch. B 2007, 62, 955-964;
-
(2007)
Z. Naturforsch. B
, vol.62
, pp. 955-964
-
-
Nilges, T.1
Bawohl, M.2
Lange, S.3
-
64
-
-
42549126179
-
-
d) S. Lange, M. Bawohl, T. Nilges, Inorg. Chem. 2008, 47, 2625-2633.
-
(2008)
Inorg. Chem
, vol.47
, pp. 2625-2633
-
-
Lange, S.1
Bawohl, M.2
Nilges, T.3
|