Reductive activation of tripod metal compounds: Preparative application

European Journal of Inorganic Chemistry

Volumn , Issue 9, 2008, Pages 1423-1434

  Mautz, Jürgen ^a   Huttner, Gottfried ^a  

^a UNIVERSITY OF HEIDELBERG   (Germany)

Author keywords

Cobalt; Nickel; Oxidative addition; Reductive activation; Tripodal ligands

Indexed keywords

CHEMICAL ACTIVATION; CHLORINE COMPOUNDS; COBALT; COBALT COMPOUNDS; ELECTRONS; LIGANDS; MOLECULES; OXIDATION; PARAMAGNETISM; QUANTUM CHEMISTRY; REDUCTION; SELENIUM COMPOUNDS; SULFUR COMPOUNDS;

% REDUCTIONS; COORDINATION COMPOUNDS; DISELENIDES; ISOELECTRONICS; OXIDATIVE ADDITIONS; REDUCTIVE ACTIVATION; SOLVENT MOLECULES; TRIPODAL LIGANDS; UNPAIRED ELECTRONS; VALENCE ELECTRON;

NICKEL;

EID: 53349164724     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.200700874     Document Type: Article

References (51)

1. U. Winterhalter, L. Zsolnai, P. Kircher, K. Heinze, G. Huttner, Eur. J. Inorg. Chem. 2001, 89.
2. a) J. Mautz, K. Heinze, H. Wadepohl, G. Huttner, Eur. J. Inorg. Chem. 2008, 1413-1422;
3. b) J. Mautz, Ph. D. Thesis, Ruprecht-Karls-Universität, Heidelberg, 2007: Reduktive Aktivierung von TriphosMetall-Komplexen (Triphos = CH3C(CH2PPh2)3). Aufklärung von Zwischenstufen und präparative Anwendung am Beispiel von Cobalt und Nickel; http://archiv.ub.uni- heidelberg. de/volltextserver/volltexte/2007/7473/pdf/ Dissertation_Juergen_Mautz_2007.pdf.
4. S. Beyreuther, J. Hunger, G. Huttner, S. Mann, L. Zsolnai, Chem. Ber. 1996, 129, 745.
5. a) C. Bianchini, D. Masi, C. Mealli, A. Meli, Acta Crystallogr., Cryst. Struct. Commun. 1982, 11, 1475;
6. b) C. Bianchini, C. Mealli, A. Meli, G. Scapacci, Organometallics 1983, 2, 141.
7. D. F. Evans, J. Chem. Soc. 1959, 2003.
8. a) M. D. Vaira, S. Midollini, L. Sacconi, Inorg. Chem. 1977, 16, 1518;
9. b) M. D. Vaira, S. Midollini, L. Sacconi, Inorg. Chem. 1979, 18, 3466.
10. G. Reinhard, R. Soltek, G. Huttner, A. Barth, O. Walter, L. Zsolnai, Chem. Ber. 1996, 129, 97.
11. C. A. Ghilardi, C. Mealli, S. Midollini, V. I. Nefedov, A. Orlandini, L. Sacconi, Inorg. Chem. 1980, 19, 2454.
12. N. M. Kostić, R.F. Fenske, J. Organomet. Chem. 1982, 233, 337.
13. A. Dedieu, T. A. Albright, R. Hoffmann, J. Am. Chem. Soc. 1979, 101, 3141.
14. C. Mealli, S. Midollini, L. Sacconi, Inorg. Chem. 1978, 17, 632.
15. T. J. Greenhough, B. W. S. Kolthammer, P. Legzdins, J. Trotter, Inorg. Chem. 1979, 18, 3543.
16. J. Schiemann, P. Hüberner, E. Weiss, Angew. Chem. 1983, 12, 1021;
17. Angew. Chem. Int. Ed. Engl. 1983, 22, 980.
18. a) N. R. Bunn, S. Aldridge, D. L. Coombs, A. Rossin, D. J. Willock, C. Jones, L.-l. Ooi, Chem. Commun. 2004, 1732;
19. b) N. R. Bunn, S. Aldridge, D. L. Kays, N. D. Coombs, A. Rossin, D. J. Willock, J. K. Day, C. Jones, L.-l. Ooi, Organometallics 2005, 24, 5891;
20. c) B. Schiemenz, G. Huttner, Angew. Chem. 1993, 105, 1840;
21. Angew. Chem. Int. Ed. Engl. 1993, 32, 1772.
22. a) J. D. Korp, I. Bernal, R. Hörlein, R. Serrano, W. A. Herrmann, Chem. Ber. 1985, 118, 340;
23. b) W. Gäde, E. Weiss, J. Organomet. Chem. 1981, 213, 451;
24. c) F. Ettel, G. Huttner, L. Zsolnai, W. Imhof, J. Organomet. Chem. 1990, 397, 299;
25. d) W. A. Herrmann, H.-J. Kneuper, E. Herdtweck, Angew. Chem. 1985, 97, 1060;
26. Angew. Chem. Int. Ed. Engl. 1985, 24, 1062;
27. e) F. Ettel, G. Huttner, L. Zsolnai, Angew. Chem. 1989, 101, 1525;
28. Angew. Chem. Int. Ed. Engl. 1989, 28, 1496.
29. a) A. Strube, J. Heuser, G. Huttner, H. Lang, J. Organomet. Chem. 1988, 356, C9;
30. b) A. Strube, G. Huttner, H. Lang, J. Organomet. Chem. 1990, 399, 267;
31. c) A. Strube, G. Huttner, L. Zsolnai, Angew. Chem. 1988, 100, 1586;
32. Angew. Chem. Int. Ed. Engl. 1988, 27, 1529;
33. d) A. Strube, G. Huttner, L. Zsolnai, Z. Anorg. Allg. Chem. 1989, 577, 263;
34. e) F. Bringewski, G. Huttner, W. Imhof, J. Organomet. Chem. 1993, 448, C3.
35. C. Mealli, L. Sacconi, Inorg. Chem. 1982, 21, 2870.
36. K. Fried, Diploma Thesis, Ruprecht-Karls-Universität, Heidelberg, 2005.
37. K. Heinze, G. Huttner, L. Zsolnai, A. Jacobi, P. Schober, Chem. Eur. J. 1997, 3, 732.
38. F. H. Allen, Acta Crystallogr., Sect. B 2002, 58, 380.
39. N. Braun, G. Huttner, Acta Crystallogr., Sect. B 2004, 61, 174.
40. The same type of packing is observed for the structure of 4a·3THF. The solvent molecules in this structure show disorder such that the distances referring to packing are not as accurate as for 4a·3DME. The distance between the centres of the coordination compounds are around 1878 pm, indicating that the THF solvate molecules call for more space than do the DME molecules.
41. J. H. Gross, N. Nieth, H. B. Linden, U. Blumbach, F. J. Richter, M. E. Tauchert, R. Tompers, P. Hofmann, Anal. Bioanal. Chem. 2006, 386, 52.
42. a) W. Hewertson, H. R. Watson, J. Chem. Soc. 1962, 1490;
43. b) A. Muth, O. Walter, G. Huttner, A. Asam, L. Zsolnai, C. Emmerich, Z. Naturforsch. Teil B 1994, 48, 149.
44. K. Heinze, G. Huttner, L. Zsolnai, P. Schober, Inorg. Chem. 1997, 36, 5457.
45. With the techniques used, problems arise with the highly airand moisture-sensitive compound during the preparation of the test sample. The customary degree of accuracy was therefore not attainable with this compound.
46. DENZO-SMN, Data processing software, Nonius 1998; http://www.nonius.com.
47. a) G. M. Sheldrick, SHELXS-97, Program for Crystal Structure Solution, University of Göttingen, 1997; http://shelx.uni-ac. gwdg.de/SHELX/index.html;
48. b) G. M. Sheldrick, SHELXL-97, Program for Crystal Structure Refinement, University of Göttingen, 1997; http://shelx.uni-ac. gwdg.de/SHELX/index.html.
49. International Tables for X-ray Crystallography, Vol. 4, Kynoch Press, Birmingham, U. K., 1974.
50. L. Zsolnai, G. Huttner, XPMA, University of Heidelberg, 1994; http://www.uni-heidelberg.de/institute/fak12/AC/huttner/software/ software.html.
51. R. Soltek, Winray 32, University of Heidelberg, 2000; http://www.uni-heidelberg.de/institute/fak12/AC/huttner/software/software.html.