Microstructure and mechanical characterization of ZrC-Mo cermets produced by hot isostatic pressing

Materials Science and Engineering: A

Volumn 497, Issue 1-2, 2008, Pages 79-86

  Landwehr, Sean E ^a   Hilmas, Gregory E ^a   Fahrenholtz, William G ^a   Talmy, Inna G ^b   DiPietro, Stephen G ^c  

^a University of Missouri Rolla   (United States)

^b NAVAL SURFACE WARFARE CENTER   (United States)

^c Exothermics Inc   (United States)

Author keywords

Cermet; Hot isostatic pressing; Mechanical properties; Molybdenum; Zirconium carbide

Indexed keywords

CARBIDES; CERMETS; ELASTIC MODULI; FRACTURE; FRACTURE TOUGHNESS; HARDNESS; HOT ISOSTATIC PRESSING; MICROSTRUCTURE; MOLYBDENUM COMPOUNDS; ZIRCONIUM COMPOUNDS;

DENSIFICATIONS; FLEXURE STRENGTH; FORM CLUSTERS; GRAINSIZE; HOT-ISOSTATIC PRESSINGS; MECHANICAL CHARACTERIZATIONS; MICROSTRUCTURE CHARACTERIZATION; MICROSTRUCTURES ANALYSIS; MO CONTENT; RELATIVE DENSITY;

SINTERING;

EID: 53349103178     PISSN: 09215093     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.msea.2008.07.017     Document Type: Article

References (40)

1. Rudy E. Compendium of Phase Diagram Data (1969), Air Force Materials Laboratory Metals and Ceramics Division, Wright-Patterson AFB, OH p. 162
2. Kotlyar E.E., and Nazarchuk T.N. Chemical properties of carbides of transition metals of groups IV and V. Inorg. Mater. 2 (1966) 1532-1538
3. 2 composites. J. Mater. Sci. 23 (1998) 2865-2870
4. Lidman W.G., and Hamjian H.J. Reactions during sintering of a zirconium carbide-niobium cermet. J. Am. Ceram. Soc. 35 (1952) 236-240
5. p/W composite. J. Mater. Sci. Lett. 17 (1998) 1739-1741
6. Song G.M., Wang Y.J., and Zhou Y. Elevated temperature ablation resistance and thermophysical properties of tungsten matrix composites reinforced with ZrC particles. J. Mater. Sci. 36 (2001) 4625-4631
7. Dickerson M.B., Wurm P.J., Schorr J.R., Hoffman W.P., Wapner P.G., and Sandhage K.H. Near net-shape, ultra-high melting, recession-resistant ZrC/W-based rocket nozzle liners via the displacive compensation of porosity (DCP) method. J. Mater. Sci. 39 (2004) 6005-6015
8. Suzuki T., Matsumoto H., Nomura N., and Hanada S. Microstructures and fracture toughness of directionally solidified Mo-ZrC eutectic composites. Sci. Tech. Adv. Mater. 3 (2002) 137-143
9. Suzuki T., Matsumoto H., Nomura N., and Hanada S. Microstructures and mechanical properties of eutectic Mo-XC (X = Ti, Zr, Hf) in situ composites. Trans. Mater. Res. Soc. Jpn. 26 (2001) 307-310
10. Suzuki T., Matsumoto H., Nomura N., and Hanada S. Microstructure and creep of Mo-ZrC in situ composite. Mater. Trans. 41 (2000) 1164-1167
11. Wallace T.C., Gutierrez C.P., and Stone P.L. The molybdenum-zirconium-carbon system. J. Phys. Chem. 67 (1963) 76-801
12. Fedorov T.F., Kuz'ma Yu.B., and Gorshkova L.V. Phase equilibria in the ternary system zirconium-molybdenum-carbon. Sov. Powder Metall. Met. Ceram. 3 (1965) 229-233
13. In: Holleck H. (Ed). Binäre und ternäre Carbide und Nitride der Übergangsmetalle und ihre Phasenbezeihungen (1981), Kernforschungszentrum Karlsruhe, Karlsruhe, Germany 161-162
14. Landwehr S.E., Hilmas G.E., Fahrenholtz W.G., and Talmy I.G. Processing of ZrC-Mo cermets for high-temperature applications. Part I. Chemical interactions in the ZrC-Mo system. J. Am. Ceram. Soc. 90 7 (2007) 1998-2002
15. Landwehr S.E., Hilmas G.E., Fahrenholtz W.G., and Talmy I.G. "Processing of ZrC-Mo Cermets for High Temperature Applications, Part II: Pressureless Sintering and Mechanical Properties". J. Am. Ceram. Soc. 91 3 (2008) 873-878
16. Rahaman M.N. Ceramic Processing (2007), Taylor & Francis, Boca Raton
17. Metals and Ceramics Information Center, Hot Isostatic Processing, Battelle Columbus Laboratories, Columbus, OH, 1982.
18. Khan A.A., and Labbe J.C. Aluminum nitride-molybdenum ceramic matrix composites: influence of molybdenum addition on mechanical properties. Proceedings of the 5th International Symposium in Advanced Materials (1997) 49-56
19. Khan A.A., and Labbe J.C. Aluminium nitride-molybdenum ceramic matrix composites. Influence of molybdenum addition on electrical, mechanical and thermal properties. J. Eur. Ceram. Soc. 17 (1997) 1885-1890
20. Taylor R.E. Thermal conductivity of zirconium carbide at high temperatures. J. Am. Ceram. Soc. 45 7 (1962) 353-354
21. Briggs J.Z. Properties and Selection: Nonferrous Alloys and Special-Purpose Materials. In: Lampman S.R. (Ed). ASM Metals Handbook vol.2 (1990), ASM International 1140-1143
22. Barnier P., Brodhag C., and Thevenot F. Hot-pressing kinetics of zirconium carbide. J. Mater. Sci. 21 7 (1986) 2452-2547
23. Lanin A.G., Marchev E.V., and Pritchin S.A. Non-isothermal sintering parameters and their influence on the structure and properties of zirconium carbide. Ceram. Int. 17 5 (1991) 301-307
24. Samsonov G.V., and Petrikina R.Ya. Sintering of metals, carbides, and oxides by hot-pressing. Phys. Sint. 2 3 (1970) 1-20
25. Lee H., and Gurland J. Hardness and deformation of cemented tungsten carbide. Mater. Sci. Eng. 33 (1978) 125-133
26. Calderon H.A., Kostorz G., and Ullrich G. Microstructure and plasticity of two molybdenum-base alloys (TZM). Mater. Sci. Eng. A A160 (1993) 189-199
27. Gurland J. The measurement of grain contiguity in a two phase material. Trans. Met. Soc. AIME 212 (1958) 452-455
28. Gurland J. A structural approach to the yield strength of two-phase alloys with coarse microstructures. Mater. Sci. Eng. 40 (1979) 59-71
29. Enqvist H., Jacobson S., and Axén N. A model for the hardness of cemented carbides. Wear 252 (2002) 384-393
30. 4C. Ceram. Eng. Sci. Proc. 6 7-8 (1985) 977-994
31. Filacchioni G., Casagrande E., De Angelis U., De Santis G., and Ferrara D. Effects of strain rate on tensile properties of TZM and Mo-5%Re. J. Nucl. Mater. 307-311 (2002) 705-709
32. Battelle Metals and Ceramics Information Center, Engineering Data on Selected Ceramics, vol. II. Carbides, Battelle Columbus Laboratories, Columbus, OH, 1979.
33. Spriggs R.M. Expression for effect of porosity on elastic modulus on polycrystalline refractory materials, particularly aluminum oxide. J. Am. Ceram. Soc. 45 (1961) 94
34. Hashin Z., and Shtrikman S. A variational approach to the theory of the elastic behavior of polycrystals. J. Mech. Phys. Sol. 10 (1962) 343-352
35. Fan Z., Tsakiropoulos P., and Miodownik A.P. Prediction of Young's modulus of two phase composites. Mater. Sci. Technol. 8 (1992) 922-929
36. Bartolomea J.F., Diaz M., Requena J., Moya J.S., and Tomsia A.P. Mullite/molybdenum ceramic-metal composites. Acta Mater. 47 14 (1999) 3891-3899
37. Cockeram B.V. The mechanical properties and fracture mechanisms of wrought low carbon arc cast (LCAC), molybdenum-0.5pct titanium-0.1pct zirconium (TZM), and oxide dispersion strengthened (ODS) molybdenum flat products. Mater. Sci. Eng. A 418 (2006) 120-136
38. Sigl L.S., and Exner H.E. Experimental study of the mechanics of fracture in WC-Co alloys. Met. Trans. A 18A (1987) 1299-1308
39. Ghosh A., Jenkins M.G., White K.W., Kobayashi A.S., and Brad R.C. Elevated-temperature fracture resistance of a sintered α-silicon carbide. J. Am. Ceram. Soc. 72 2 (1989) 242-247
40. Wachtman J.B. Mechanical Properties of Ceramics (1996), John Wiley & Sons, New York