Tris(1,2-bis(dimethylphosphino)ethane)-rhenium(I) trifluoromethanesulfonate, [Re(DMPE)3][CF3SO3]

Inorganic Syntheses

Volumn 31, Issue , 1997, Pages 253-256

  Chang, Lihsueh ^a   Deutsch, Edward ^a   Kirchhoff, John R ^b  

^a UNIVERSITY OF CINCINNATI   (United States)

^b UNIVERSITY OF TOLEDO   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ETHANE;

TRIFLUOROMETHANESULFONATE; TRIPHENYL PHOSPHINES;

RHENIUM COMPOUNDS;

EID: 53249151841     PISSN: 00738077     EISSN: None     Source Type: Book Series    
DOI: None     Document Type: Article

References (13)

1. K. Libson, M. Woods, J. C. Sullivan, I. W. Watkins, II, R. C. Elder, and E. Deutsch, Inorg. Chem., 27, 3614 (1988).
2. E. Deutsch, K. Libson, J.-L. Vanderheyden, A. R. Ketring, and H. R. Maxon, Nucl. Med. Biol., 13, 465 (1986).
3. J.-L. Vanderheyden, M. J. Heeg, and E. Deutsch, Inorg. Chem., 24, 1666 (1985).
4. (a) N. P. Johnson, C. J. L. Lock, and G. Wilkinson, J. Chem. Soc., 1054 (1965).
5. (b) J. H. Beard, J. Casey, and R. K. Murmann, Inorg. Chem., 4, 797 (1965).
6. (c) L. S. Chang, J. Rall, F. Tisato, E. Deutsch, and M. J. Heeg, Inorg. Chim. Acta, 205, 35 (1993).
7. N.P. Johnson, C. J. L. Lock, and G. Wilkinson, Inorg. Syn., 9, 145 (1967).
8. L. S. Chang, E. Deutsch, and M. J. Heeg, Transition Met. Chem., 18, 335 (1993).
9. 1H NMR specra were obtained on an IBM/Bruker AF-250 spectrometer at 101.256 and 250.134 MHz.
10. 1H NMR shifts are relative to solvent peaks (DMSO, 2.55 ppm) as an internal reference.
11. (c) J.-L. Vanderheyden, University of Cincinnati, Ph.D. Thesis, pp. 230-231 (1983).
12. 4 at δ0.0 with shifts downfield of the reference considered positive.
13. (b) The peak becomes sharper at 223 K and even sharper at 200 K.