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Volumn , Issue 10, 2008, Pages 1645-1653

Hydrogen bonding and Lewis acid-base interactions in the system bis(pentafluorophenyl)borinic acid/methanol

Author keywords

Fluoroarylboranes; Hydrogen bonds; Lewis acids; NMR spectroscopy; X ray diffraction

Indexed keywords

CHLORINE COMPOUNDS; COMPLEXATION; DIMERS; ESTERS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PROTON TRANSFER; SINGLE CRYSTALS; STABILIZATION; TEMPERATURE; THERMODYNAMIC STABILITY; X RAY ANALYSIS; X RAY DIFFRACTION;

EID: 53249106887     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.200701210     Document Type: Article
Times cited : (21)

References (63)
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    • [17] is very close to that of water (0.367 vs. 0.353).
    • [17] is very close to that of water (0.367 vs. 0.353).
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    • It is interesting to observe that in a series of pyrazolato-based dizinc(II) complexes the -(Me)OHO(H)- bridging ligand can assume either one of the two limiting structures, that is -(Me)OH⋯O(H)- or -(Me)O⋯HO(H)-, when the pyrazolato moiety is varied: a) B. Bauer-Siebenlist, F. Meyer, E. Farkas, D. Vidovic, J. A. Cuesta-Seijo, R. Herbst-Irmer, H. Pritzkow, Inorg. Chem. 2004, 43, 4189-4202;
    • It is interesting to observe that in a series of pyrazolato-based dizinc(II) complexes the -(Me)OHO(H)- bridging ligand can assume either one of the two limiting structures, that is -(Me)OH⋯O(H)- or -(Me)O⋯HO(H)-, when the pyrazolato moiety is varied: a) B. Bauer-Siebenlist, F. Meyer, E. Farkas, D. Vidovic, J. A. Cuesta-Seijo, R. Herbst-Irmer, H. Pritzkow, Inorg. Chem. 2004, 43, 4189-4202;
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    • Some methyl borinate was formed also by the direct reaction of MeOH with the anhydride present in the initial solution: Ar2BOBAr2, MeOH ⇄ Ar2BOMe, Ar2BOH
    • 2BOH.
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    • [9] spectroscopic data, respectively.
    • [9] spectroscopic data, respectively.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.