Cross-metathesis of oleyl alcohol with methyl acrylate: Optimization of reaction conditions and comparison of their environmental impact

Green Chemistry

Volumn 10, Issue 10, 2008, Pages 1099-1104

  Rybak, Anastasiya ^a   Meier, Michael A R ^a  

^a UNIVERSITY OF APPLIED SCIENCES EMDEN LEER   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 52949149348     PISSN: 14639262     EISSN: 14639270     Source Type: Journal    
DOI: 10.1039/b808930b     Document Type: Article

References (24)

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13. Note: for the reaction of 1 mole of 1 with 2 moles of MA, 1 mole of 2, 1 mole of 3, and 1 mole of ethene are produced; therefore, if ethene is considered as a waste product the atom economy is 93.6%; if ethene is considered a useful product and would be recovered on an industrial scale the atom economy would be 100%.
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24. Note: 2 and 5 are considered as equally useful products for a direct polyester synthesis; in the first case methanol would be the condensation by-product; in the second case methyl acetate would be formed; both would be recycled on an industrial scale.