Seven-coordinate ruthenium atoms sequestered in praseodymium clusters in the chloride {RuPr3}Cl3

Inorganic Chemistry

Volumn 47, Issue 18, 2008, Pages 7954-7956

  Herzmann, Nina ^a   Mudring, Anja Verena ^b   Meyer, Gerd ^a  

^a UNIVERSITY OF COLOGNE   (Germany)

^b RUHR UNIVERSITY BOCHUM   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 52949103257     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic800907c     Document Type: Article

References (26)

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4. Corbett, J. D. J. Chem. Soc., Dalton Trans. 1996, 575.
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15. Zimmermann, S.; Meyer, G. Unpublished work, 2007.
16. 3 (synthesized by the ammonium chloride route and purified as described previously), 85.5 mg of Pr (Chempur, Karlsruhe, Germany, 99.9%), and 40.8 mg of Ru (Merck, Darmstadt, Germany, 99.9%) was filled in a tantalum ampule, which was He-arc-sealed and jacketed with a silica ampule. The temperature program used was as follows: 1000°C for 5 days and cooling at 2°C/h to 700°C and then at 10°C/h to room temperature. All manipulations were carried out under strict exclusion of air and especially moisture in a drybox (MBraun, Garching, Germany). Black crystals were selected under a microscope in a drybox and sealed in thin-walled glass capillaries.
17. Meyer, G.; Ax, P. Mater. Res. Bull. 1982, 17, 1447.
18. Meyer, G. Inorg. Synth. 1989, 25, 146.
19. Meyer, G. In Advances in the Synthesis and Reactivity of Solids; Mallouk, T. E., Eds.; JAI Press: London, England, 1994; Vol. 2, pp 1-26.
20. 0)] 0.0392/0.0974, for all data 0.0589/0.1030; GOF = 1.368.
21. Meyer, G. Z. Anorg. Allg. Chem. 2008, 634, in press.
22. Payne, M. W.; Dorhout, P. K.; Kim, S.-J.; Hughbanks, T. R.; Corbett, J. D. Inorg. Chem. 1992, 31, 1389-1394.
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24. Meyer, G.; Schleid, T.; Krämer, K. J. Less-Common Met. 1989, 149, 67-71.
25. 2, coefficient 2. For Pr: 6s, -5.69, 1.7, 0.5671, 1.0, 0.5503; 6p, -2.88, 1.34, 1.0, 0.0, 0.0; 5d, -6.4, 2.55, 0.52, 1.2, 0.64; 4f, -6.12, 8.9, 0.4172, 4.35, 0.729. For Ru: 5s, -8.43, 1.95, 0.5538, 1.05, 0.5668; 5p, -3.49, 1.42, 1.0, 0.0, 0.0; 4d, -10.1, 3.45, 0.5394, 1.5, 0.6062. For Cl: 3s, -26.67, 2.9, 0.6262, 1.75, 0.5051; 3p, -13.85, 2.45, 0.5554, 1.3, 0.5519. COOP analysis (Wijeyesekera, S.; Hoffmann, R. Organometallics 1984, 3, 949) was used to interpret the chemical bonding.
26. Emsley, J. The Elements, 2nd ed.; Oxford University Press: Oxford, U.K., 1991.