Agostic-type B - H⋯Pb interactions stabilize a dialkylplumbylene. Structure of and bonding in [{nPr2P(BH3)}(Me 3Si)C(CH2)]2Pb

Organometallics

Volumn 27, Issue 17, 2008, Pages 4386-4394

  Izod, Keith ^a   McFarlane, William ^a   Wills, Corinne ^a   Clegg, William ^a   Harrington, Ross W ^a  

^a NEWCASTLE UNIVERSITY   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

LEAD;

EID: 52649153030     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om800598b     Document Type: Article

References (90)

1. For recent reviews of heavier tetrylene chemistry see:(a) Barrau, J.; Rima, G. Coord. Chem. Rev. 1998, 178-180, 593.
2. (b) Tokitoh, N.; Okazaki, R. Coord. Chem. Rev. 2000, 210, 251.
3. (c) Kira, M. J. Organomet. Chem. 2004, 689, 4475.
4. (d) Weidenbruch, M. Eur. J. Inorg. Chem. 1999, 373.
5. (e) Klinkhammer, K. W. In Chemistry of Organic Germanium, Tin and Lead Compounds; Rappoport, Z., Ed.; Wiley: New York, 2002; Vol. 2, pp 283-357.
6. (f) Veith, M. Angew. Chem., Int. Ed. Engl. 1987, 26, 1.
7. For leading references to diamidogermylenes, -stannylenes, and -plumbylenes see:(a) Fjeldberg, T.; Hope, H.; Lappert, M. F.; Power. P. P.; Thome, A. J. J. Chem. Soc., Chem. Commun. 1983, 639.
8. (b) Olmstead, M. M.; Power, P. P. Inorg. Chem. 1984, 23, 413.
9. (c) Tang, Y.; Felix, A. M.; Zakharov, L. N.; Rheingold, A. L.; Kemp, R. A. Inorg. Chem. 2004, 43, 7239.
10. (d) Avent, A. G.; Drost, C.; Gehrus, B.; Hitchcock, P. B.; Lappert, M. F. Z. Anorg. Allg. Chem. 2004, 630, 2090.
11. (e) Gans-Eichler, T.; Gudat, D.; Nieger, M. Angew. Chem., Int. Ed. 2002, 41, 1888.
12. (f) Chorley, R. W.; Hitchcock, P. B.; Lappert, M. F.; Leung, W.-P.; Power, P. P.; Olmstead, M. M. Inorg. Chim. Acta 1992, 198, 203.
13. (g) Braunschweig, H.; Hitchcock, P. B.; Lappert, M. F.; Pierssens, L. J.-M. Angew. Chem., Int. Ed. Engl. 1994, 33, 1156.
14. (h) Lappert, M. F.; Slade, M. J.; Atwood, J. L.; Zaworotko, M. J. J. Chem. Soc., Chem. Commun. 1980, 621.
15. (i) Bazinet, P.; Yapf G. P. A.; Richeson, D. S. J. Am. Chem. Soc. 2001, 123, 11162.
16. For a comprehensive review of the chemistry of N-heterocyclic germylenes see:Kühl, O. Coord. Chem. Rev. 2004, 248, 411.
17. For recent reviews of N-heterocyclic silylenes see:(a) Hill, N. J.; West, R. J. Organomet. Chem. 2004, 689, 4165.
18. (b) Gehrhus, B.; Lappert, M. F. J. Organomet. Chem. 2001, 617, 209.
19. (a) Yang, X.-J.; Wang, Y.; Wei, P.; Quillan, B.; Robinson, G. H. Chem. Commun. 2006, 403.
20. (b) Phillips, A. D.; Hino, S.; Power, P. P. J. Am. Chem. Soc. 2003, 125, 7520.
21. (c) Pu, L.; Olmstead, M. M.; Power, P. P.; Schiemenz, B. Organometallics 1998, 17, 5602.
22. (d) Stürmann, M.; Weidenbruch, M.; Klinkhammer, K. W.; Lissner, F.; Marsmann, H. Organometallics 1998, 17, 4425.
23. (e) Lay, U.; Pritzkow, H.; Grützmacher, H. Chem. Commun. 1992, 260.
24. (f) Simons, R. S.; Pu, L.; Olmstead, M. M.; Power, P. P. Organometallics 1997, 16, 1920.
25. (g) Grützmacher, H.; Pritzkow, H.; Edelmann, F. T. Organometallics 1991, 10, 23.
26. (h) Brooker, S.; Buijink, J.-K.; Edelmann, F. T. Organometallics 1991, 10, 25.
27. (i) Tajima, T.; Takeda, N.; Sasamori, T.; Tokitoh, N. Organometallics 2006, 25, 3552.
28. (j) Spikes, G. H.; Peng, Y.; Fettinger, J. C.; Power, P. P. Z. Anorg. Allg. Chem. 2006, 632, 1005.
29. (k) Wegner, G. L.; Berger, R. J. F.; Schier, A.; Schmidbaur, H. Organometallics 2001, 20, 418.
30. (l) Weidenbruch, M.; Schlaefke, J.; Schafer, A.; Peters, K.; von Schnering, H. G.; Marsmann, H. Angew. Chem., Int. Ed. Engl. 1994, 33, 1846.
31. (m) Braunschweig, H.; Drost, C.; Hitchcock, P. B.; Lappert, M. F.; Pierssens, L. J.-M. Angew. Chem., Int. Ed. Engl. 1997, 36, 261.
32. (n) Bender, J. E.; Banaszak Holl, M. K.; Kampf, J. W. Organometallics 1997, 16, 2743.
33. (o) Kano, N.; Shibita, K.; Tokitoh, N.; Okazaki, R. Organometallics 1999, 18, 2999.
34. (p) Jutzi, P.; Schmidt, H.; Neumann, B.; Stammler, H.-G. Organometallics 1996, 15, 741.
35. (q) Pu, L.; Twamley, B.; Power, P. P. Organometallics 2000, 19, 2874.
36. Kira, M.; Yauchibara, R.; Hirano, R.; Kabuto, C.; Sakurai, H. J. Am. Chem. Soc. 1991, 113, 7785.
37. Kira, M.; Ishida, S.; Iwamoto, T.; Kabuto, C. J. Am. Chem. Soc. 1999, 121, 9722.
38. Kira, M.; Ishida, S.; Iwamoto, T.; Ichinohe, M.; Kabuto, C.; Ignatovich, L.; Sakurai, H. Chem. Lett. 1999, 263.
39. Jutzi, P.; Becker, A.; Stammler, H. G.; Neumann, B. Organometallics 1991, 10, 1647.
40. Eaborn, C.; Hill, M. S.; Hitchcock, P. B.; Patel, D.; Smith, J. D.; Zhang, S. Organometallics 2000, 19, 49.
41. Eaborn, C.; Ganicz, T.; Hitchcock, P. B.; Smith, J. D.; Sozerli, S. E. Organometallics 1997, 16, 5621.
42. (a) Eichler, B. E.; Power, P. P. Inorg. Chem. 2000, 39, 5444.
43. (b) Setaka, W.; Hirai, K.; Sakamoto, K.; Kira, M. J. Am. Chem. Soc. 2004, 126, 2696.
44. (c) Hino, S.; Olmstead, M.; Phillips, A. D.; Wright, R. J.; Power, P. P. Inorg. Chem. 2004, 43, 7346.
45. For examples see:(a) Drost, C.; Hitchcock, P. B.; Lappert, M. F.; Pierssens, L. J.-M. Chem. Commun. 1997, 1141.
46. (b) Drost, C.; Hitchcock, P. B.; Lappert, M. F. Organometallics 1998, 17, 3838.
47. (c) Wingerter, S.; Gornitzka, H.; Bertermann, R.; Pandey, S. K.; Rocha, J.; Stalke, D. Organometallics 2000, 19, 3890.
48. (d) Engelhardt, L. M.; Jolly, B. S.; Lappert, M. F.; Raston, C. L.; White, A. H. J. Chem. Soc., Chem. Commun. 1988, 336.
49. (e) Jolly, B. S.; Lappert, M. F.; Engelhardt, L. M.; White, A. H.; Raston, C. L. J. Chem. Soc., Dalton Trans. 1993, 2653.
50. (f) Cardin, C. J.; Cardin, D. J.; Constantine, S. P.; Drew, M. G. B.; Rashid, H.; Convery, M. A.; Fenske, D. J. Chem. Soc., Dalton Trans. 1998, 2749.
51. (g) Benet, S.; Cardin, C. J.; Cardin, D. J.; Constantine, S. P.; Heath, P.; Rashid, H.; Teixeira, S.; Thorpe, J. H.; Todd, A. K. Organometallics 1999, 18, 389.
52. (a) Davidson, P. J.; Lappert, M. F. J. Chem. Soc., Chem. Commun. 1973, 317.
53. (b) Goldberg, D. E.; Harris, D. H.; Lappert, M. F.; Thomas, K. M. J. Chem. Soc., Chem. Commun. 1976, 261.
54. (c) ZiIm, K. W.; Lawless, G. A.; Merrill, R. M.; Millar, J. M.; Webb, G. G. J. Am. Chem. Soc. 1987, 109, 7236.
55. Izod, K.; McFarlane, W.; Tyson, B. V.; Carr, I.; Clegg, W.; Harrington, R. W. Organometallics 2006, 25, 1135.
56. Bridgewater, B. M.; Parkin, G. Inorg. Chem. Commun. 2000, 3, 534.
57. Eichler, B. E.; Phillips, B. L.; Power, P. P.; Augustine, M. P. Inorg. Chem. 2000, 39, 5450.
58. Abragam, A. The Principles of Nuclear Magnetism; Oxford University Press: Oxford, UK, 1961; p 316.
59. (a) Becke, A. D. J. Chem. Phys. 1993, 98, 5648.
60. (b) Stephens, P. J.; Devlin, F. J.; Chablowski, C. F.; Frisch, M. J. J. Phys. Chem. 1994, 98, 11623.
61. (c) Hertwig, R. H.; Koch, W. Chem. Phys. Lett. 1997, 268, 345.
62. (a) Hay, P. J.; Wadt, W. R. J. Chem. Phys. 1985, 82, 270.
63. (b) Wadt, W. R.; Hay, P. J. J. Chem. Phys. 1985, 82, 284.
64. (c) Hay, P. J.; Wadt, W. R. J. Chem. Phys. 1985, 82, 299.
65. (a) Hariharan, P. C.; Pople, J. A. Theor. Chim. Acta 1973, 28, 213.
66. (b) Francl, M. M.; Petro, W. J.; Hehre, W. J.; Binkley, J. S.: Gordon, M. S.; DeFrees, D. J.; Pople, J. A. J. Chem. Phys. 1982, 77, 3654.
67. (a) Carpenter, J. E.; Weinhold, F. J. Mol. Struct. (Theochem) 1988, 169, 41.
68. (b) Carpenter, J. E. Ph.D. Thesis, University of Wisconsin, Madison, WI, 1987.
69. (c) Foster, J. P.; Weinhold, F. J. Am. Chem. Soc. 1980, 102, 7211.
70. (d) Reed, A. E.; Weinhold, F. J. Chem. Phys. 1983, 78, 4066.
71. (e) Reed, A. E.; Weinhold, F. J. Chem. Phys. 1983, 1736.
72. (f) Reed, A. E.; Weinstock, R. B.; Weinhold, F. J. Chem. Phys. 1985, 83, 735.
73. (g) Reed, A. E.; Curtiss, L. A.; Weinhold, F. Chem. Rev. 1988, 88, 899.
74. Wong, M. W. Chem. Phys. Lett. 1996, 256, 391.
75. NIST Computational Chemistry Comparison and Benchmark Database, NIST Standard Reference Database Number 101, Release 14, Sept 2006, Editor: Russell D. Johnson III, http://srdata.nist.gov/cccbdb.
76. (a) Canees, M. T.; Mennucci, B.; Tomasi, J. J. Chem. Phys. 1997, 107, 3032.
77. (b) Mennucci, B.; Tomasi, J. J. Chem. Phys. 1997, 106, 5151.
78. (c) Mennucci, B.; Canees, E.; Tomasi, J. J. Phys. Chem. B 1997, 101, 10506.
79. (d) Tomasi, J.; Mennucci, B.; Canees, E. J. Mol. Struct. (THEOCHEM) 1999, 464, 211.
80. Nikol, H.; Becht, A.; Vogler, A. Inorg. Chem. 1992, 31, 3277.
81. (a) McWeeny, R. Phys. Rev. 1962, 126, 1028.
82. (b) Ditchfield, R. Mol. Phys. 1974, 27, 789.
83. (c) Dodds, J. L.; McWeeny, R.; Sadlej, A. J. Mol. Phys. 1980, 41, 1419.
84. (d) Wolinski, K.; Hilton, J. F.; Pulay, P. J. Am. Chem. Soc. 1990, 112, 8251.
85. Izod, K.; McFarlane, W.; Tyson, B. V.; Clegg, W.; Harrington, R. W. Chem. Commun. 2004, 570.
86. (a) Fischer, E. O.; Gruben, H. Z. Anorg. Allg. Chem. 1956, 286, 237.
87. (b) Armstrong, D. R.; Davidson, M. G.; Moncrieff, D.; Russell, C. A.; Stourton, C.; Steiner, A.; Stalke, D.; Wright, D. S. Organometallics 1997, 16, 3340.
88. (a) APEX2, SMART, and SAINT software for CCD diffractometers; Bruker AXS Inc.: Madison, WI, 2004 and 1997.
89. (b) Sheldrick, G. M. Acta Crystallogr., Sect. A 2008, 64, 112.
90. Frisch, M. J.; et al. Gaussian 03, Revision C.02; Gaussian, Inc.: Wallingford, CT, 2004.