A discrete supramolecular conglomerate composed of two saddle-distorted zinc(II)-phthalocyanine complexes and a doubly protonated porphyrin with saddle distortion undergoing efficient photoinduced electron transfer

Angewandte Chemie - International Edition

Volumn 47, Issue 35, 2008, Pages 6712-6716

  Kojima, Takahiko ^a   Honda, Tatsuhiko ^a   Ohkubo, Kei ^a   Shiro, Motoo ^d   Kusukawa, Takahiro ^c   Fukuda, Takamitsu ^b   Kobayashi, Nagao ^b   Fukuzumi, Shunichi ^a  

^a JAPAN SCIENCE AND TECHNOLOGY AGENCY   (Japan)

^b TOHOKU UNIVERSITY   (Japan)

^c KYOTO INSTITUTE OF TECHNOLOGY   (Japan)

^d RIGAKU CORPORATION   (Japan)

Author keywords

Electron transfer; Photochemistry; Phthalocyanines; Porphyrins; Supramolecular chemistry

Indexed keywords

ELECTRON TRANSITIONS; HYDROGEN; HYDROGEN BONDS; PORPHYRINS; SUPRAMOLECULAR CHEMISTRY; ZINC;

ELECTRON TRANSFER; INTERMOLECULAR HYDROGEN BONDINGS; PHOTO-INDUCED ELECTRON TRANSFER; PHOTOCHEMISTRY; PHTHALOCYANINE COMPLEXES; PHTHALOCYANINES; PROTONATED;

ZINC COMPOUNDS;

INDOLE DERIVATIVE; ORGANOMETALLIC COMPOUND; PHTHALOCYANINE; PORPHYRIN; PROTON; ZINC;

ARTICLE; CHEMISTRY; ELECTRON TRANSPORT; LIGHT; PHOTOCHEMISTRY; X RAY CRYSTALLOGRAPHY;

CRYSTALLOGRAPHY, X-RAY; ELECTRON TRANSPORT; INDOLES; LIGHT; ORGANOMETALLIC COMPOUNDS; PHOTOCHEMISTRY; PORPHYRINS; PROTONS; ZINC;

EID: 52449097415     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200802601     Document Type: Article

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44. 2+ ion could be resolved with the two moieties, which were heavily superimposed, so that the porphine and phenyl groups were treated as rigid groups. To improve the ratio of n(ref)/n(para), all the phenyl groups of [Zn(OPPc)] and toluene molecules were refined as rigid groups. CCDC 688606 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
45. The fluorescence lifetime of 2 was determined to be 1.5 ns.
46. The fluorescence lifetime of 3 was determined to be 1.2 ns.
47. The absorption maxima of singlet excited state of 2 were seen at 590 and 960 nm and those of singlet excited state of 3 were observed at 510 and 900 nm upon photoexcitation at 410 nm in PhCN (Figure S7 in the Supporting Information).
48. 3+ (bpy = 2,2′-bipyridine) in PhCN (see Figure S8 in the Supporting Information).