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Volumn 12, Issue 11, 1996, Pages 2617-2621

Fluorocarbons: Surface free energies and van der Waals interaction

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EID: 5244328235     PISSN: 07437463     EISSN: None     Source Type: Journal    
DOI: 10.1021/la951020v     Document Type: Article
Times cited : (90)

References (54)
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    • 0 for LD PTFE can be calculated as 0.165 ± 0.005 nm.
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    • -1) was also placed on the Teflon AF surfaces, but reliable contact angles could not be obtained because the liquid rapidly penetrated the surface.
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    • The use of the AFM (Nanoscope III; Digital Instruments, CA) to quantitatively measure the force of interaction between a sphere and a flat plate has been reported in several recent works. For experimental details see, for example: Ducker, W. A.; Senden, T. J.; Pashley, R. M. Langmuir 1992, 8, 1831. Larson, I.; Drummond, C. J.; Chan, D. Y. C.; Grieser, F. J. Am. Chem. Soc. 1993, 115, 11885. Drummond, C. J.; Senden, T. J. Colloids Surf., A 1994, 87, 217. The measured force of interaction is considered to have an accuracy of ± 20%, with the major uncertainty (±15%) arising from the experimental determination of the v-shaped cantilever spring constant (k). The surfaces generally used in AFM force measurements are too rough and inelastic to get a quantitative value for the reversible work of adhesion.
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    • The use of the AFM (Nanoscope III; Digital Instruments, CA) to quantitatively measure the force of interaction between a sphere and a flat plate has been reported in several recent works. For experimental details see, for example: Ducker, W. A.; Senden, T. J.; Pashley, R. M. Langmuir 1992, 8, 1831. Larson, I.; Drummond, C. J.; Chan, D. Y. C.; Grieser, F. J. Am. Chem. Soc. 1993, 115, 11885. Drummond, C. J.; Senden, T. J. Colloids Surf., A 1994, 87, 217. The measured force of interaction is considered to have an accuracy of ± 20%, with the major uncertainty (±15%) arising from the experimental determination of the v-shaped cantilever spring constant (k). The surfaces generally used in AFM force measurements are too rough and inelastic to get a quantitative value for the reversible work of adhesion.
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    • The use of the AFM (Nanoscope III; Digital Instruments, CA) to quantitatively measure the force of interaction between a sphere and a flat plate has been reported in several recent works. For experimental details see, for example: Ducker, W. A.; Senden, T. J.; Pashley, R. M. Langmuir 1992, 8, 1831. Larson, I.; Drummond, C. J.; Chan, D. Y. C.; Grieser, F. J. Am. Chem. Soc. 1993, 115, 11885. Drummond, C. J.; Senden, T. J. Colloids Surf., A 1994, 87, 217. The measured force of interaction is considered to have an accuracy of ± 20%, with the major uncertainty (±15%) arising from the experimental determination of the v-shaped cantilever spring constant (k). The surfaces generally used in AFM force measurements are too rough and inelastic to get a quantitative value for the reversible work of adhesion.
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    • 2 area) was less rough than the native oxidized wafer (rms roughness of 0.8 nm with a few features up to 10 nm).


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