메뉴 건너뛰기




Volumn 63, Issue 19, 2008, Pages 4676-4684

Modelling of alcohol and water diffusion in fuel cell membranes-Experimental validation by means of in situ Raman spectroscopy

Author keywords

Diffusion; DMFC; Fuel cell; Mass transfer; Membranes

Indexed keywords

ARCHITECTURAL ACOUSTICS; BOUNDARY CONDITIONS; BOUNDARY VALUE PROBLEMS; CYTOLOGY; DIFFERENCE EQUATIONS; DIFFERENTIAL EQUATIONS; DIFFERENTIATION (CALCULUS); DIFFUSION; DIRECT ENERGY CONVERSION; ELECTRIC BATTERIES; ELECTROCHEMISTRY; FUEL CELLS; METHANOL; PHASE EQUILIBRIA; PHOTORESISTS; POLYMERS; SEMICONDUCTOR DOPING; SOLID OXIDE FUEL CELLS (SOFC); THREE DIMENSIONAL;

EID: 52149102275     PISSN: 00092509     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ces.2008.03.014     Document Type: Article
Times cited : (42)

References (29)
  • 1
    • 0003035877 scopus 로고    scopus 로고
    • The degree and effect of methanol crossover in the direct methanol fuel cell
    • Cruickshank J., and Scott K. The degree and effect of methanol crossover in the direct methanol fuel cell. Journal of Power Sources 70 (1998) 40-47
    • (1998) Journal of Power Sources , vol.70 , pp. 40-47
    • Cruickshank, J.1    Scott, K.2
  • 2
    • 0037139225 scopus 로고    scopus 로고
    • Recent developments of the measurement of the methanol permeation in a direct methanol fuel cell
    • Dohle H., Divisek J., Mergel J., Oetjen H.F., Zingler C., and Stolten D. Recent developments of the measurement of the methanol permeation in a direct methanol fuel cell. Journal of Power Sources 105 (2002) 274-282
    • (2002) Journal of Power Sources , vol.105 , pp. 274-282
    • Dohle, H.1    Divisek, J.2    Mergel, J.3    Oetjen, H.F.4    Zingler, C.5    Stolten, D.6
  • 4
    • 0034306541 scopus 로고    scopus 로고
    • Equilibrium and diffusion of methanol and water in a Nafion 117 Membrane
    • Gates C.M., and Newman J. Equilibrium and diffusion of methanol and water in a Nafion 117 Membrane. A.I.Ch.E. Journal 46 10 (2000) 2076-2085
    • (2000) A.I.Ch.E. Journal , vol.46 , Issue.10 , pp. 2076-2085
    • Gates, C.M.1    Newman, J.2
  • 5
    • 52149116773 scopus 로고    scopus 로고
    • Gmehling, J., Onken, U., Arlt, W., 1981. Vapor-liquid equilibrium data collection, aqueous-organic systems (Supplement 1). Chemistry Data Series, vol. I, Part 1a.
    • Gmehling, J., Onken, U., Arlt, W., 1981. Vapor-liquid equilibrium data collection, aqueous-organic systems (Supplement 1). Chemistry Data Series, vol. I, Part 1a.
  • 6
    • 0033221384 scopus 로고    scopus 로고
    • A review of the state-of-the-art of the methanol crossover in direct methanol fuel cells
    • Heinzel A., and Barragán V.M. A review of the state-of-the-art of the methanol crossover in direct methanol fuel cells. Journal of Power Sources 84 (1999) 70-74
    • (1999) Journal of Power Sources , vol.84 , pp. 70-74
    • Heinzel, A.1    Barragán, V.M.2
  • 7
    • 33746988811 scopus 로고    scopus 로고
    • In situ confocal-RAMAN imagery of ion and solvent transport through an ion-exchange membrane
    • Huguet P., Sistat P., Deabate S., and Petit E. In situ confocal-RAMAN imagery of ion and solvent transport through an ion-exchange membrane. Desalination 200 (2006) 173-174
    • (2006) Desalination , vol.200 , pp. 173-174
    • Huguet, P.1    Sistat, P.2    Deabate, S.3    Petit, E.4
  • 8
    • 0842311665 scopus 로고    scopus 로고
    • Comparative studies of methanol crossover and cell performance for a DMFC
    • Jiang R., and Chu D. Comparative studies of methanol crossover and cell performance for a DMFC. Journal of the Electrochemical Society 151 1 (2004) A69-A76
    • (2004) Journal of the Electrochemical Society , vol.151 , Issue.1
    • Jiang, R.1    Chu, D.2
  • 9
    • 84985531893 scopus 로고
    • A multicomponent film model incorporating a general matrix method of solution of the Maxwell-Stefan equation
    • Krishna R., and Standart G.L. A multicomponent film model incorporating a general matrix method of solution of the Maxwell-Stefan equation. A.I.Ch.E. Journal 22 (1976) 383-389
    • (1976) A.I.Ch.E. Journal , vol.22 , pp. 383-389
    • Krishna, R.1    Standart, G.L.2
  • 12
    • 0033898727 scopus 로고    scopus 로고
    • Degradation of a fuel cell membrane as revealed by micro-Raman spectroscopy
    • Mattsson B., Ericson H., Torell L.M., and Sundholm F. Degradation of a fuel cell membrane as revealed by micro-Raman spectroscopy. Electrochimica Acta 45 (2000) 1405-1408
    • (2000) Electrochimica Acta , vol.45 , pp. 1405-1408
    • Mattsson, B.1    Ericson, H.2    Torell, L.M.3    Sundholm, F.4
  • 13
    • 0036607846 scopus 로고    scopus 로고
    • Simulation of the direct methanol fuel cell-I. Thermodynamic framework for a multicomponent membrane
    • Meyers J.P., and Newman J. Simulation of the direct methanol fuel cell-I. Thermodynamic framework for a multicomponent membrane. Journal of the Electrochemical Society 149 6 (2002)
    • (2002) Journal of the Electrochemical Society , vol.149 , Issue.6
    • Meyers, J.P.1    Newman, J.2
  • 15
    • 0030214360 scopus 로고    scopus 로고
    • Effect of methanol crossover in a liquid-feed polymer-electrolyte direct methanol fuel cell
    • Ravikumar M.K., and Shukla A.K. Effect of methanol crossover in a liquid-feed polymer-electrolyte direct methanol fuel cell. Journal of the Electrochemical Society 143 8 (1996) 2601-2606
    • (1996) Journal of the Electrochemical Society , vol.143 , Issue.8 , pp. 2601-2606
    • Ravikumar, M.K.1    Shukla, A.K.2
  • 16
    • 0034140802 scopus 로고    scopus 로고
    • Methanol transport through Nafion membranes-electro-osmotic Drag effects on potential step measurements
    • Ren X., Springer T.E., Zawodzinski T.A., and Gottesfeld S. Methanol transport through Nafion membranes-electro-osmotic Drag effects on potential step measurements. Journal of the Electrochemical Society 147 2 (2000) 466-474
    • (2000) Journal of the Electrochemical Society , vol.147 , Issue.2 , pp. 466-474
    • Ren, X.1    Springer, T.E.2    Zawodzinski, T.A.3    Gottesfeld, S.4
  • 18
    • 52149097606 scopus 로고    scopus 로고
    • Saure, R., 1995. Zur Trocknung von Lösungsmittelfeuchten Polymerfilmen. Ph.D. Thesis, University of Karlsruhe (TH), Karlsruhe.
    • Saure, R., 1995. Zur Trocknung von Lösungsmittelfeuchten Polymerfilmen. Ph.D. Thesis, University of Karlsruhe (TH), Karlsruhe.
  • 19
    • 52149091211 scopus 로고    scopus 로고
    • Schabel, W., 2004. Trocknung von Polymerfilmen-Messung von Konzentrationsprofilen mit der Inversen-Mikro-Raman-Spektroskopie. Ph.D. Thesis, University of Karlsruhe (TH), Karlsruhe.
    • Schabel, W., 2004. Trocknung von Polymerfilmen-Messung von Konzentrationsprofilen mit der Inversen-Mikro-Raman-Spektroskopie. Ph.D. Thesis, University of Karlsruhe (TH), Karlsruhe.
  • 20
    • 31544440739 scopus 로고    scopus 로고
    • Inverse Mikro Raman Spektroskopie-eine neue Messmethode zur Untersuchung lokaler Stofftransportvorgänge in dünnen Filmen, Folien und Membranen
    • Schabel W. Inverse Mikro Raman Spektroskopie-eine neue Messmethode zur Untersuchung lokaler Stofftransportvorgänge in dünnen Filmen, Folien und Membranen. Chemie Ingenieur Technik 77 12 (2005) 1915-1926
    • (2005) Chemie Ingenieur Technik , vol.77 , Issue.12 , pp. 1915-1926
    • Schabel, W.1
  • 21
    • 52149117663 scopus 로고    scopus 로고
    • Schabel, W., Scharfer, P., Ludwig, I., Müller, M., Kind, M., 2005. Concentration profile measurements in polymeric coatings during drying by means of Inverse-Micro-Raman-Spectroscopy (IMRS). Raman Update Autumn 2005, Horiba Jobin Yvon.
    • Schabel, W., Scharfer, P., Ludwig, I., Müller, M., Kind, M., 2005. Concentration profile measurements in polymeric coatings during drying by means of Inverse-Micro-Raman-Spectroscopy (IMRS). Raman Update Autumn 2005, Horiba Jobin Yvon.
  • 22
    • 34548309392 scopus 로고    scopus 로고
    • Mass transport measurements in membranes by means of in situ Raman spectroscopy-first results of methanol and water profiles in fuel cell membranes
    • Scharfer P., Schabel W., and Kind M. Mass transport measurements in membranes by means of in situ Raman spectroscopy-first results of methanol and water profiles in fuel cell membranes. Journal of Membrane Science 303 1-2 (2007) 37-42
    • (2007) Journal of Membrane Science , vol.303 , Issue.1-2 , pp. 37-42
    • Scharfer, P.1    Schabel, W.2    Kind, M.3
  • 24
    • 0002193932 scopus 로고
    • Ueber Erstarrungs- und Quellungseigenschaften von Gelatine
    • Schroeder P. Ueber Erstarrungs- und Quellungseigenschaften von Gelatine. Zeitschrift fuer Physikalische Chemie 45 (1903) 57
    • (1903) Zeitschrift fuer Physikalische Chemie , vol.45 , pp. 57
    • Schroeder, P.1
  • 25
    • 0001725160 scopus 로고    scopus 로고
    • The impact of mass transport and methanol crossover on the direct methanol fuel cell
    • Scott K., Taama W.M., Argyropoulos P., and Sundmacher K. The impact of mass transport and methanol crossover on the direct methanol fuel cell. Journal of Power Sources 83 (1999) 204-216
    • (1999) Journal of Power Sources , vol.83 , pp. 204-216
    • Scott, K.1    Taama, W.M.2    Argyropoulos, P.3    Sundmacher, K.4
  • 26
    • 1842559793 scopus 로고    scopus 로고
    • Investigation of the limiting processes of a DMFC by mathematical modeling
    • Siebke A., Schnurnberger W., Meier F., and Eigenberger G. Investigation of the limiting processes of a DMFC by mathematical modeling. Fuel Cells 3 1-2 (2003) 37-47
    • (2003) Fuel Cells , vol.3 , Issue.1-2 , pp. 37-47
    • Siebke, A.1    Schnurnberger, W.2    Meier, F.3    Eigenberger, G.4
  • 28
    • 52149120370 scopus 로고    scopus 로고
    • VDI-Waermeatlas, 1997. VDI-Gesellschaft Verfahrenstechnik und Chemieingenieurwesen, eight ed. Chapter GD1.
    • VDI-Waermeatlas, 1997. VDI-Gesellschaft Verfahrenstechnik und Chemieingenieurwesen, eight ed. Chapter GD1.
  • 29
    • 0030126879 scopus 로고    scopus 로고
    • Real-time mass spectrometric study of the methanol crossover in a direct methanol fuel cell
    • Wang J.T., Wasmus S., and Savinell R.F. Real-time mass spectrometric study of the methanol crossover in a direct methanol fuel cell. Journal of the Electrochemical Society 143 4 (1996) 1233-1239
    • (1996) Journal of the Electrochemical Society , vol.143 , Issue.4 , pp. 1233-1239
    • Wang, J.T.1    Wasmus, S.2    Savinell, R.F.3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.