Extreme rate acceleration by axial thiolate coordination on the isomerization of endoperoxide catalyzed by iron porphyrin

Angewandte Chemie - International Edition

Volumn 47, Issue 34, 2008, Pages 6438-6440

  Yamane, Takehiro ^a   Makino, Kohei ^a   Umezawa, Naoki ^a   Kato, Nobuki ^a   Higuchi, Tsunehiko ^a  

^a NAGOYA CITY UNIVERSITY   (Japan)

Author keywords

Cytochrome P450; Endoperoxides; Enzyme models; Heme; Ligand effects

Indexed keywords

CHEMICAL REACTIONS; ELECTRON TRANSITIONS; ISOMERIZATION; PORPHYRINS;

CYTOCHROME P450; ENDOPEROXIDES; ENZYME MODELS; HEME; LIGAND EFFECTS;

ISOMERS;

CYTOCHROME P450; DRUG DERIVATIVE; HEMIN; HEMIN DIMETHYL ESTER; PROSTAGLANDIN H2;

ARTICLE; BIOSYNTHESIS; CATALYSIS; CHEMISTRY; ISOMERISM;

CATALYSIS; CYTOCHROME P-450 ENZYME SYSTEM; HEMIN; ISOMERISM; PROSTAGLANDIN H2;

EID: 52049107680     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200800137     Document Type: Article

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