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When alcohol 1 was treated with and without additional hydrogen gas in SCW (1: 0.054 mmol, H2: 0 or 0.29 mmol, 440°C for 180 min in 0.35 g mL-1 water density in SUS 316 reactor, no difference in the product distributions was observed between the reactions with and without additional hydrogen gas (with H2, 3: 24, 4: 15, without H2, 3: 25, 4: 13, But the possibility of the reduction of 1 not by hydrogen gas generated in situ but nascent hydrogen in the reaction conditions still remains. Reduction of 1 and 3 to give 4 in 15% aqueous formic acid or 15% aqueous sodium formate in supercritical conditions (460°C, 60 min) was reported: A. R. Katritzky, E. S. Ignatchenko, S. M. Allin, R. A. Barcock, M. Siskin, C. W. Hudson, Energy Fuels 1997, 11, 160
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2, 3: 25%, 4: 13%). But the possibility of the reduction of 1 not by hydrogen gas generated in situ but nascent hydrogen in the reaction conditions still remains. Reduction of 1 and 3 to give 4 in 15% aqueous formic acid or 15% aqueous sodium formate in supercritical conditions (460°C, 60 min) was reported: A. R. Katritzky, E. S. Ignatchenko, S. M. Allin, R. A. Barcock, M. Siskin, C. W. Hudson, Energy Fuels 1997, 11, 160.
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37
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2 were not detected. These gaseous products might be derived from the partial oxidation of substrate 1 by a trace amount of oxygen dissolved in water.
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2 were not detected. These gaseous products might be derived from the partial oxidation of substrate 1 by a trace amount of oxygen dissolved in water.
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58149296717
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Disproportionation of 5 and its homologues was also reported, see:
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Disproportionation of 5 and its homologues was also reported, see:
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