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Volumn 80, Issue 9, 2007, Pages 1828-1832

Reaction behavior of secondary alcohols in supercritical water

Author keywords

[No Author keywords available]

Indexed keywords

DIPHENYL METHANES; HYDROGEN ATOMS; HYDROGEN GAS EVOLUTIONS; HYDROXY GROUPS; OXIDATION PRODUCTS; OXIDIZING AGENTS; PRESENCE OF WATERS; PRODUCT DISTRIBUTIONS; REACTION BEHAVIORS; REDUCTION PRODUCTS; SECONDARY ALCOHOLS; SUPERCRITICAL WATERS; TUBULAR REACTORS; WATER DENSITIES;

EID: 52049100680     PISSN: 00092673     EISSN: 13480634     Source Type: Journal    
DOI: 10.1246/bcsj.80.1828     Document Type: Article
Times cited : (14)

References (45)
  • 14
    • 58149311656 scopus 로고    scopus 로고
    • Preprints of Symposia-American Chemical Society, Division of Fuel Chemistry
    • b) C. R. Yonker, S. Bai, B. J. Palmer, Preprints of Symposia-American Chemical Society, Division of Fuel Chemistry, 1999, Vol. 44, p. 377.
    • (1999) , vol.44 , pp. 377
    • Yonker, C.R.1    Bai, S.2    Palmer, B.J.3
  • 32
    • 58149294197 scopus 로고    scopus 로고
    • K. Nakahara, T. Arita, K. Nagami, O. Kajimoto, the 8th Meeting on Supercritical Fluids, Bordeaux, France, April 14, 2002.
    • a) K. Nakahara, T. Arita, K. Nagami, O. Kajimoto, the 8th Meeting on Supercritical Fluids, Bordeaux, France, April 14, 2002.
  • 34
    • 58149286726 scopus 로고    scopus 로고
    • H. Kojima, K. Kobiro, T. Arita, O. Kajimoto, K. Nakahara, the 82nd Autumn Annual Meeting of the Chemical Society of Japan, Toyonaka, Osaka, September 25, 2002, Abstr., No. 3PA-113.
    • a) H. Kojima, K. Kobiro, T. Arita, O. Kajimoto, K. Nakahara, the 82nd Autumn Annual Meeting of the Chemical Society of Japan, Toyonaka, Osaka, September 25, 2002, Abstr., No. 3PA-113.
  • 36
    • 0030836135 scopus 로고    scopus 로고
    • When alcohol 1 was treated with and without additional hydrogen gas in SCW (1: 0.054 mmol, H2: 0 or 0.29 mmol, 440°C for 180 min in 0.35 g mL-1 water density in SUS 316 reactor, no difference in the product distributions was observed between the reactions with and without additional hydrogen gas (with H2, 3: 24, 4: 15, without H2, 3: 25, 4: 13, But the possibility of the reduction of 1 not by hydrogen gas generated in situ but nascent hydrogen in the reaction conditions still remains. Reduction of 1 and 3 to give 4 in 15% aqueous formic acid or 15% aqueous sodium formate in supercritical conditions (460°C, 60 min) was reported: A. R. Katritzky, E. S. Ignatchenko, S. M. Allin, R. A. Barcock, M. Siskin, C. W. Hudson, Energy Fuels 1997, 11, 160
    • 2, 3: 25%, 4: 13%). But the possibility of the reduction of 1 not by hydrogen gas generated in situ but nascent hydrogen in the reaction conditions still remains. Reduction of 1 and 3 to give 4 in 15% aqueous formic acid or 15% aqueous sodium formate in supercritical conditions (460°C, 60 min) was reported: A. R. Katritzky, E. S. Ignatchenko, S. M. Allin, R. A. Barcock, M. Siskin, C. W. Hudson, Energy Fuels 1997, 11, 160.
  • 37
    • 58149290386 scopus 로고    scopus 로고
    • 2 were not detected. These gaseous products might be derived from the partial oxidation of substrate 1 by a trace amount of oxygen dissolved in water.
    • 2 were not detected. These gaseous products might be derived from the partial oxidation of substrate 1 by a trace amount of oxygen dissolved in water.
  • 39
    • 58149296717 scopus 로고    scopus 로고
    • Disproportionation of 5 and its homologues was also reported, see:
    • Disproportionation of 5 and its homologues was also reported, see:


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