Soap: The polymorphic genie of hierarchically structured soft condensed-matter products

Industrial and Engineering Chemistry Research

Volumn 47, Issue 17, 2008, Pages 6347-6353

  Raut, Janhavi S ^a   Naik, Vijay M ^a   Singhal, Siddhant ^b   Juvekar, Vinay A ^b  

^a Hindustan Lever Limited   (India)

^b INDIAN INSTITUTE OF TECHNOLOGY BOMBAY   (India)

Author keywords

[No Author keywords available]

Indexed keywords

ACIDS; ASSEMBLY; COLLOIDS; CRYSTALLOGRAPHY; CRYSTALS; ELECTROMECHANICAL DEVICES; ERROR ANALYSIS; FATTY ACIDS; GELATION; LIGHT SOURCES; LIQUID CRYSTALS; METALS; OFFSHORE OIL WELL PRODUCTION; POWDERS;

AIR-WATER INTERFACE; DOMAIN SIZES; ILLUSTRATIVE EXAMPLES; METAL SALTS; MICRO-MECHANICAL STRUCTURES; MULTI SCALING; OPTICAL-; PERSONAL CARE; SELF-ASSEMBLED AGGREGATES; SOLID CRYSTALS; STRUCTURE-PROPERTY RELATIONSHIPS; TERTIARY STRUCTURES;

PHASE INTERFACES;

EID: 52049091793     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie0714753     Document Type: Conference Paper

References (38)

1. Zhu, S.; Chambers, J. G.; Naik, V. M. Soap. In Kirk-Othmer Concise Encyclopedia of Chemical Technology; Wiley-Interscience: New York, 2007; Vol. 2, p 861.
2. Terech, P.; Rodriguez, V.; Barnes, J. D.; McKenna, G. B. Organogels and Aerogels of Racemic and Chiral 12-Hydroxyoctadecanoic Acid. Langmuir 1994, 10, 3406.
3. Terech, P.; Weiss, R G. Low Molecular Mass Gelators of Organic Liquids and the Properties of Their Gels. Chem. Rev. 1997, 97, 3133.
4. Witte, A. C. Grease Manufacture. In Encyclopedia of Chemical Processing and Design; McKetta, J. J., Cunningham, W. A., Eds.; Marcel Decker: New York, 1984; Vol. 25, p 88.
5. Darke, W. F.; McBain, J. W.; Salmon, C. S. The Ultramicroscopio Structure of Soaps. Proc. R. Soc. London, Ser. A 1920, 395.
6. McBain, J. W.; Sierichs, W. C. The Solubility of Sodium and Potassium Soaps and Diagrams of Aqueous Potassium Soaps. J. Am. Oil Chem. Soc. 1948, 221.
7. McBain, J. W.; Vold, R. D.; Frick, M. A Phase Rule Study of the System Sodium Stearate - Water. J. Phys. Chem. 1940, 44, 1013.
8. Madelmont, C.; Perron, R. Study of the influence of the chain length on some aspects of soap/water diagrams. Colloid Polym. Sci. 1976, 254, 581.
9. (a) Laughlin R. G. In Advances in Liquid Crystals; Brown, G. H., Ed.; Academic Press: New York, 1978; Vol. 3, p 41.
10. (b) Laughlin R. G. In Surfactants; Tadros, Th. R, Ed.; Academic Press: London, 1984; p 53.
11. (c) Laughlin, R. G. The Aqueous Phase Behavior of Surfactants; Academic Press: San Diego, CA, 1994.
12. Luzatti, V.; Mustacchi, H.; Skoulios, A. The Structure of the Liquid-Crystal Phases of Some Soap + Water Systems. Faraday Soc. Discuss. 1958, 25, 43.
13. Buerger, M. J.; Smith, L. B.; Ryer, F. V.; Spike, J. E. The Crystalline Phases of Soap. Proc. Natl. Acad. Sci. U.S.A. 1945, 31 (8), 226-233.
14. Ekwall, P.; Mandell, L.; Fontell, K. Ternary systems of potassium soap, alcohol, and water: I. Phase equilibria and phase structures; II. Structure and composition of the mesophases. J. Colloid Interface Sci. 1969, 31, 508.
15. Shinoda, K. J. The Critical Micelle Concentration of Soap Mixtures (Two-Component Mixture). J. Phys. Chem. 1954, 58, 541.
16. Fairhurst, C.; Fuller, S.; Gray, J.; Holmes, M. C.; Tiddy, G. J. T. Lyotropic surfactant liquid crystals. In Handbook of Liquid Crystals; Wiley-VCH: New York, 1998; Vol. 3, p 341.
17. Tiddy, G. J. T. Surfactant Liquid Crystal Phases. Phys. Rep. 1980, 57, 1-46.
18. De Mul, M. N. G.; Davis, T. H.; Evans, D. F.; Bhave, A. V.; Wagner, J. R. Solution Phase Behavior and Solid Phase Structure of Long-Chain Sodium Soap Mixtures. Langmuir 2000, 16, 8276.
19. Liang, J.; Ma, Y.; Zheng, Y.; Davis, T. H.; Chang, H. T.; Binder, D.; Abbas, S.; Hsu, F. L. Solvent-Induced Crystal Morphology Transformation in a Ternary Soap System: Sodium Stearate Crystalline Fibers and Platelets. Langmuir 2001, 17, 6447.
20. Trager, O.; Sowade, S.; Bottecher, C.; Fuhrjop, J.-H. Huid and Chiral Ephedrinum Myristate Micellar Fibres. J. Am. Chem. Soc. 1997, 119, 9120.
21. Hasan, S.; Rowe, W.; Tiddy, G. J. T. Surfactant Liquid Crystals. In Handbook of Applied Surface and Colloid Chemistry; Wiley: New York, 2001; p 465.
22. Zhu, S.; Pudney, P. D. A.; Heppenstall-Butler, M.; Butler, M. F.; Ferdinando, D.; Kirkland, M. Interaction of the Acid Soap of Triethanolamine Stearate and Stearic Acid with Water. J. Phys. Chem. B 2007, 111, 1016.
23. Hoffmann, H.; Ulbricht, W. Rheological Effects in Surfactant Phases. In Handbook of Applied Surface and Colloid Chemistry; Wiley: New York, 2001; p 189.
24. Jindal, V. K.; Kalus, J.; Pilsl, H.; Hoffmann, H.; Lindner, P. Dynamic Small-Angle Neutron scattering Study of Rodlike Micelles in a Surfactant Solution. J. Phys. Chem. 1990, 94 (7), 3129.
25. Naik V. M. Nano Phenomena at Work, for Colour Management in Personal Care. In Bionanotechnology: Global Prospects; Reisner, D. E., Ed.; CRC Press: Boca Raton, FL, 2008.
26. Lakes, R. Materials with Structural Hierarchy. Nature 1993, 361, 511.
27. (a) Nadakatti, S. M.; Naik, V. M.; Thomas, S. (Unilever Home & Personal Care USA). Melt Cast Solid Shaped Detergent Bar Compositions with High Water Content, U.S. Patent 6,365,567,2002.
28. (b) Nadakatti, S. M.; Naik, V. M. (Unilever Plc, Unilever N.V.). Casting of Shaped Soft Solid Articles, World Patent W09851773, 1998.
29. (c) Nadakatti, S. M.; Naik, V. M. (Unilever Plc GB). Mould and Process for Casting Shaped Soft Articles, Eur. Patent EP0983336, 1998.
30. (d) Cordell, J. M.; Irving, G. N.; Nadakatti, S. M.; Allan, P. S.; Naik, V. M.; Overton, C. A.; Tarverdi, K.; Stocker, F. E. (Unilever Plc GB). Process for the Production of a Detergent Composition, World Patent WO9853038, 1998.
31. (e) Allan, P. S.; Irving, G. N.; Nadakatti, S. M.; Naik, V. M.; Overton, C. A.; Stocker, F. E.; Tarverdi, K.; Wahlers, J. C. (Unilever Plc GB). Process and Apparatus for the Production of a Detergent Composition, Eur. Patent EP0983337, 1998.
32. (f) Allan, P. S.; Cordell, J. M.; Irving, G. N.; Nadakatti, S. M.; Naik, V. M.; Overton, C. A.; Stocker, F. E.; Tarverdi, K.; Wahlers, J. C. (Lever Brothers Company, NY). Process for Molding of a Detergent Composition, U.S. Patent 6,224,812, 1998.
33. (g) Nadakatti, S. M.; Naik, V. M.; Thomas, S. (Unilever Plc GB). Detergent Composition, World Patent WO2002053689, 2002. (h) Koduvely, H.; Nadakatti, S. M.; Naik, V. M.; Pathak, P.; Thomas, S. (Unilever N.V. NI, Unilever Plc GB, Hindustan Lever Ltd., In). Low Density Detergent Bar Composition, World Patent WO2002083832, 2002.
34. Raut, J. S.; Bhattad, P.; Kulkami, A. C.; Naik, V. M. "MicroPottery"-Marangoni Effect Driven Assembly of Amphiphilic Fibers. Langmuir 2005, 21, 516.
35. Ball, P. Pots of soap. Nature 2005, 433, 373.
36. Mahadevan, L.; Keller, J. B. Coiling of Flexible Ropes. Proc. R. Soc. London A 1996, 452, 1679.
37. Mahadevan, L.; Ryu, W. S.; Samuel, A. D. T. Fluid "Rope Trick" Investigated. Nature 1998, 392, 140.
38. van de Pas, J. C.; Margaret, C. M.; den Adel, R.; Hazekamp, J.; Nootenboom, P.; Nijsse, I.; Roijers, E.; Stuart, M. Unilever internal communication, 2005.