Synthesis of 2-substituted cyclohexene derivatives through cross-coupling reactions via π-allylmetal intermediate using N-heterocyclic carbenes (NHCs) as ligands

Synthesis

Volumn , Issue 17, 2008, Pages 2830-2834

  Yamazaki, Tetsuro ^a   Sato, Yoshihiro ^a  

^a HOKKAIDO UNIVERSITY   (Japan)

Author keywords

Cross coupling; Kumada Tamao Coriiu reaction; Migita Kosugi Stille reaction; N heterocyclic carbene (NHC); Nickel; Palladium

Indexed keywords

CHELATION; COMPLEXATION; NICKEL; OLEFINS; ORGANOMETALLICS; PALLADIUM; SYNTHESIS (CHEMICAL);

ALLYLMETAL; CROSS-COUPLING; CROSS-COUPLING PRODUCTS; CROSS-COUPLING REACTIONS; CYCLOHEXENE; CYCLOHEXENES; GOOD YIELDS; KUMADA-TAMAO-CORIIU REACTION; MIGITA-KOSUGI-STILLE REACTION; N-HETEROCYCLIC CARBENE (NHC); N-HETEROCYCLIC CARBENES; ORGANOTIN; STILLE COUPLINGS;

LIGANDS;

1 [(TERT BUTYLDIMETHYLSILOXY)METHYL] 6 (1 ETHOXYVINYL)CYCLOHEX 1 ENE; 1 [(TERT BUTYLDIMETHYLSILOXY)METHYL] 6 CHLOROCYCLOHEX 1 ENE; 1 [(TERT BUTYLDIMETHYLSILOXY)METHYL] 6 METHOXYCYCLOHEX 1 ENE; 1 [(TERT BUTYLDIMETHYLSILOXY)METHYL] 6 PHENYLCYCLOHEX 1 ENE; 1 [(TERT BUTYLDIMETHYLSILOXY)METHYL] 6 VINYLCYCLOHEX 1 ENE; 2,2' BIS[(TERT BUTYLDIMETHYLSILOXY)METHYL] 1,1' BI(CYCLOHEX 2 ENE; CARBENOID; CYCLOHEXENE DERIVATIVE; GRIGNARD REAGENT; HETEROCYCLIC COMPOUND; MESEMBRINE; NICKEL; ORGANOTIN COMPOUND; PALLADIUM; STRYCHNINE; TUBIFOLINE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL STRUCTURE; CROSS COUPLING REACTION; SYNTHESIS;

EID: 51949117951     PISSN: 00397881     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2008-1067222     Document Type: Article

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