Thermodynamics of aqueous solutions of polyelectrolytes: experimental results for the activity of water in aqueous solutions of some single synthetic polyelectrolytes

Journal of Chemical and Engineering Data

Volumn 53, Issue 7, 2008, Pages 1564-1570

  Lammertz, Silke ^b   Pessoa Filho, Pedro A ^b   Maurer, Gerd ^a  

^a Rheinland Pfälzische Technische Universität Kaiserslautern Landau   (Germany)

^b UNIVERSITY OF SÃO PAULO   (Brazil)

Author keywords

[No Author keywords available]

Indexed keywords

CHROMATOGRAPHIC ANALYSIS; COLLOIDS; CONCENTRATION (PROCESS); ELECTROLYTES; ETHYLENE; GELATION; MONOMERS; OFFSHORE OIL WELL PRODUCTION; OPTICAL PROPERTIES; POLYELECTROLYTES; POLYMERS; REFRACTIVE INDEX; SALTS; SODIUM; SODIUM CHLORIDE; STYRENE;

AQUEOUS SOLUTIONS; GEL-PERMEATION CHROMATOGRAPHY; ISOPIESTIC METHOD; MOLECULAR MASSES; OSMOTIC COEFFICIENTS; POLYELECTROLYTE CONCENTRATION; POLYELECTROLYTE SOLUTIONS; POLYMER CHAINS; POLYSODIUM ACRYLATES; SIMILAR PATTERN; STYRENE SULFONATE; SYNTHETIC POLYELECTROLYTES;

SOLUTIONS;

EID: 51949104447     PISSN: 00219568     EISSN: None     Source Type: Journal    
DOI: 10.1021/je800108u     Document Type: Article

References (20)

1. Dautzenberg, H.; Jaeger, W.; Kotz, J.; Philipp, B.; Seidel, C.; Stscherbina, D. Polyelectrolytes; Hanser Publishers: Munich, 1994.
2. Hartig, S. M.; Greene, R. R.; Dikov, M. M.; Prokop, A.; Davidson, J. M. Multifunctional Nanoparticulate Polyelectrolyte Complexes. Pharm. Res. 2007, 24, 2353-2369.
3. Lifson, S.; Katchalsky, A. The Electrostatic Free Energy of Polyelectrolyte Solutions. II. Fully Stretched Macromolecules. J. Polym. Sci. 1954, 13, 43-55.
4. Manning, G. S. Limiting Laws and Counterion Condensation in Polyelectrolyte Solutions. I. Colligative Properties. J. Chem. Phys. 1969, 51, 924-933.
5. Hasse, H.; Kany, H.-P.; Tintinger, R.; Maurer, G. Osmotic virial coefficients of aqueous polyethylene glycol) from laser-light scattering and isopiestic measurements. Macromolecules 1995, 28, 3540-3552.
6. Kany, H.-P.; Hasse, H.; Maurer, G. Thermodynamic properties of aqueous dextran solutions from laser-light-scattering, membrane osmometry, and isopiestic measurements. J. Chem. Eng. Data 1999, 44, 230-242.
7. Kany, H.-P.; Hasse, H.; Maurer, G. Thermodynamic properties of aqueous poly(vinylpyrrolidone) solutions from laser-light-scattering, membrane osmometry, and isopiestic measurements. J. Chem. Eng. Data 2003, 48, 689-698.
8. Ninni, L.; Meirelles, A. J. A.; Maurer, G. Thermodynamic properties of aqueous solutions of maltodextrins from laser-light scattering, calorimetry and isopiestic investigations. Carbohyd. Polym. 2005, 59, 289-303.
9. Lammertz, S. Thermodynamische Eigenschaften wässriger Polyelektrolytlösungen - PhD. Thesis, Technische Universität Kaiserslautern; Shaker Verlag: Aachen, 2005.
10. VDI-Wärmeatlas, 10th ed.; Springer-Verlag: Berlin, 2006.
11. Huglin, M. B. Light scattering from polymer solutions; Academic Press: London, 1972.
12. Großmann, C.; Tintinger, R.; Zhu, J.; Maurer, G. Aqueous two-phase systems of poly(ethylene glycol) and dextran - experimental results and modeling of thermodynamic properties. Fluid Phase Equilib. 1995, 106, 111-138.
13. Pitzer, K. S. Activity coefficients in electrolyte solutions, 2nd ed.; CRC Press: Boca Raton, 1991.
14. Prausnitz, J. M.; Lichtenthaler, R. N.; Azevedo, E. G. Molecular thermodynamics of fluid-phase equilibria, 3rd. ed.; Prentice Hall PTR: NJ, 1999.
15. Oman, S. Osmotic coefficients of aqueous polyelectrolyte solutions at low concentrations, 1. Polystyrenesulfonates with mono- and bivalent counterions. Die Makromolekulare Chemie 1974, 175, 2133-2140.
16. Takahashi, A.; Kato, N.; Nagasawa, M. The osmotic pressure of polyelectrolyte in neutral salt solutions. J. Phys. Chem. 1970, 74, 944-946.
17. Reddy, M.; Marinsky, J. A. A further investigation of the osmotic properties of hydrogen and sodium polystyrenesulfonates. J. Phys. Chem. 1970, 74, 3884-3891.
18. Bonner, O. D.; Overton, J. R. The investigation of the behavior of some polysulfonates in concentrated aqueous solutions. J. Phys. Chem. 1963, 67, 1035-1039.
19. Kakehashi, R.; Yamazoe, H.; Maeda, H. Osmotic coefficients of vinylic polyelectrolyte solutions without added salt. Colloid Polym. Sci. 1998, 276, 28-33.
20. Ise, N.; Asai, K. Mean activity coefficient of polyelectrolytes IX. measurements of poly(ethylenesulfonates) of various gegenions. J. Phys. Chem. 1968, 72, 1366-1369.