Aluminum(III)-promoted prins cyclization of 2-allylphenols: An expedient synthesis of benzoxepins

Synthesis

Volumn , Issue 17, 2008, Pages 2733-2738

  Yadav, Jhillu S ^a   Subba Reddy, Basi V ^a   Yadav, Nagendra Nath ^a   Satheesh, Gujarathi ^a  

^a INDIAN INSTITUTE OF CHEMICAL TECHNOLOGY   (India)

Author keywords

2 allylphenols; Benzoxepins; Carbonyl compounds; Prins cyclization

Indexed keywords

ALDEHYDES; ALUMINA; ALUMINUM; AROMATIC COMPOUNDS; COST EFFECTIVENESS; KETONES; ORGANIC COMPOUNDS; STEREOSELECTIVITY;

2-ALLYLPHENOLS; ALUMINUM (III); AROMATIC ALDEHYDES; BENZOXEPINS; CARBONYL COMPOUNDS; CHEMOSELECTIVITY; CROSS COUPLINGS; GOOD YIELDS; MILD CONDITIONS; PRINS CYCLIZATION;

LIGHT METALS;

2 ALLYLPHENOL DERIVATIVE; 4 CHLORO 2 (2 NAPHTHYL) 2,3,4,5 TETRAHYDRO 1 BENZOXEPIN; 4 CHLORO 2 (2,4,6 TRIMETHOXYPHENYL) 2,3,4,5 TETRAHYDRO 1 BENZOXEPIN; 4 CHLORO 2 (3 PHENOXYPHENYL) 2,3,4,5 TETRAHYDRO 1 BENZOXEPIN; 4 CHLORO 2 (4 CHLOROPHENYL) 2,3,4,5 TETRAHYDRO 1 BENZOXEPIN; 4 CHLORO 2 (4 METHOXYPHENYL) 2,3,4,5 TETRAHYDRO 1 BENZOXEPIN; 4 CHLORO 2 (4 METHYLPHENYL) 2,3,4,5 TETRAHYDRO 1 BENZOXEPIN; 4 CHLORO 2 PHENYL 2,3,4,5 TETRAHYDRO 1 BENZOXEPIN; 4 CHLORO 2,2 DIETHYL 2,3,4,5 TETRAHYDRO 1 BENZOXEPIN; 4 CHLORO 2,2 DIETHYL 7 METHYL 2,3,4,5 TETRAHYDRO 1 BENZOXEPIN; 4 CHLORO 2,2 DIMETHYL 2,3,4,5 TETRAHYDRO 1 BENZOXEPIN; 4 CHLORO 4' METHYL 4,5 DIHYDROSPIRO[1 BENZOXEPIN 2(3H),1' CYCLOHEXANE]; 4 CHLORO 4,5 DIHYDROSPIRO[1 BENZOXEPIN 2(3H),1' CYCLODODECANE]; 4 CHLORO 4,5 DIHYDROSPIRO[1 BENZOXEPIN 2(3H),1' CYCLOHEXANE]; 4 CHLORO 4,5 DIHYDROSPIRO[1 BENZOXEPIN 2(3H),1' CYCLOPENTANE]; 4 CHLORO 7 METHOXY 4,5 DIHYDROSPIRO[1 BENZOXEPIN 2(3H),1' CYCLODODECANE]; 4 CHLORO 7 METHOXY 4,5 DIHYDROSPIRO[1 BENZOXEPIN 2(3H),1' CYCLOPENTANE]; 4 CHLORO 7 METHYL 4,5 DIHYDROSPIRO[1 BENZOXEPIN 2(3H),1' CYCLODODECANE]; 4 CHLORO 7 METHYL 4,5 DIHYDROSPIRO[1 BENZOXEPIN 2(3H),1' CYCLOPENTANE]; 4' CHLORO 7' METHOXY 4',5' DIHYDROSPIRO[ADAMANTANE 2,2'(3'H) [1]BENZOXEPIN]; ALDEHYDE; ALUMINUM; BENZOXEPIN DERIVATIVE; PHENOL DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CHEMICAL REACTION; CHEMICAL STRUCTURE; CROSS COUPLING REACTION; CYCLIZATION; ISOMERISM; MASS SPECTROMETRY; PROTON NUCLEAR MAGNETIC RESONANCE; STEREOCHEMISTRY; SYNTHESIS;

EID: 51949098083     PISSN: 00397881     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2008-1067209     Document Type: Article

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