Separation and optical resolution of a pair of atrop diastereomers of the octahedral rhodium(III) complex with a nine-membered S,S-chelate ring

Inorganic Chemistry

Volumn 47, Issue 17, 2008, Pages 7450-7452

  Yoshinari, Nobuto ^a   Konno, Takumi ^a  

^a OSAKA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 51849155444     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic800910e     Document Type: Article

References (25)

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16. See the Supporting Information.
17. We found only one paper that presents a metal complex with a nine-membered S,S-chelate ring, but the structure of this complex has not been determined by X-ray analysis. (a) Gahan, L. R.; O'Connor, M. J. Aust. J. Chem. 1978, 31, 511.
18. 7
19. 2 contains three and a half independent, yet nearly identical complex cations.
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25. 1H NMR study.