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Using the equation MDC, Conc, Ssignal, S blank, x noise (rms)/5 and data collected at [Cone, 2.16 × 10-6 M, which gave values of Ssignal, 1-73 × 106 cps, Sblank ≅ 1000 cps. noiserms, 200 cps and hence an MDC of 4.99 × 10-11 M
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