The use of dynamic mechanical thermal analysis technique for determining an uneven distribution of precipitated silica in CPE/NR blends

Polymer Testing

Volumn 27, Issue 7, 2008, Pages 873-880

  Phewphong, Pakpum ^a   Saeoui, Pongdhorn ^b   Sirisinha, Chakrit ^a  

^a Mahidol University   (Thailand)

^b NATIONAL METAL AND MATERIALS TECHNOLOGY CENTER   (Thailand)

Author keywords

Chlorinated polyethylene; DMTA; Dynamic mechanical thermal properties; Filler distribution; Natural rubber; Silica

Indexed keywords

ABS RESINS; ARSENIC COMPOUNDS; CARBON BLACK; CHLORINE; COUPLING AGENTS; DYNAMIC MECHANICAL ANALYSIS; ELECTRIC NETWORK ANALYSIS; FILLERS; FLOW INTERACTIONS; MECHANICAL PROPERTIES; OXIDES; POLYMER BLENDS; POLYMERS; SILANES; SILICON; THERMOANALYSIS;

CHLORINATED POLYETHYLENE; DMTA; DYNAMIC MECHANICAL THERMAL PROPERTIES; FILLER DISTRIBUTION; NATURAL RUBBER;

SILICA;

EID: 51549106244     PISSN: 01429418     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.polymertesting.2008.06.010     Document Type: Article

References (23)

1. Sae-oui P., Sirisinha C., Thepsuwan U., and Hatthapanit K. Role of silane coupling agents on properties of silica-filled polychloroprene. Eur. Polym. J. 42 (2006) 479
2. Sae-oui P., Sirisinha C., Thepsuwan U., and Hatthapanit K. Dependence of mechanical and aging properties of chloroprene rubber on silica and ethylene thiourea loadings. Eur. Polym. J. 43 (2006) 185
3. Phewthongin N., Sae-oui P., and Sirisinha C. A study of rheological properties in sulphur vulcanised CPE/NR blends. Polym. Test. 24 (2005) 227
4. Phewthongin N., Sae-oui P., and Sirisinha C. Rheological behaviour of CPE/NR blends filled with precipitated silica. J. Appl. Polym. Sci. 100 (2006) 2565
5. Phewphong P., Sae-oui P., and Sirisinha C. Mechanism of silica reinforcement in CPE/NR blends by the use of rheological approaches. J. Appl. Polym. Sci. 107 (2007) 2638
6. Walters M.H., and Keyte D.N. Heterogeneous structure in blends of rubber polymers. Rubb. Chem. Technol. 38 (1965) 62
7. Andrews E.H. Resistance to ozone cracking in elastomer blends. J. Appl. Polym. Sci. 10 (1966) 47
8. Marsh P.A., Voet A., and Price L.D. Electron microscopy of heterogeneous elastomer blends. Rubb. Chem. Technol. 40 (1967) 359
9. Marsh P.A., Voet A., Price L.D., and Mullens T.J. Fundamental of electron microscopy of heterogeneous elastomer blends. II. Rubb. Chem. Technol. 41 (1968) 344
10. Marsh P.A., Mullens T.J., and Price L.D. Micrography of a triblend. Rubb. Chem. Technol. 43 (1970) 400
11. Hess W.M., and Chirico V.E. Elastomer blend properties? Influence of carbon black type and location. Rubb. Chem. Technol. 50 (1977) 301
12. Hess W.M., Herd C.R., and Vegvari P.C. Characterization of immiscible elastomer blends. Rubb. Chem. Technol. 66 (1993) 329
13. Callan J.E., Hess W.M., and Scott C.E. Elastomer blends. Compatibility and response to fillers. Rubb. Chem. Technol. 44 (1971) 814
14. Cotton R., and Murphy L.J. Mixing of carbon black with rubber. VI. Analysis of NR/SBR blends. Rubb. Chem. Technol. 61 (1988) 609
15. Maiti S., De S.K., and Bhowmick A.K. Quantitative estimation of filler distribution in immiscible rubber blends by mechanical damping studies. Rubb. Chem. Technol. 65 (1992) 293
16. Sirisinha C., and Prayoonchatphan N. Study of carbon black distribution in BR/NBR blends based on damping properties: influences of carbon black particle size, filler, and rubber polarity. J. Appl. Polym. Sci. 81 (2001) 3198
17. Wootthikanokkhan J., and Rattanathamwat N. Distribution of carbon black in natural rubber/acrylic rubber blends. J. Appl. Polym. Sci. 102 (2006) 248
18. Sirisinha C., Sae-oui P., and Pattanawanidchai S. Rheological properties, oil and thermal resistance in sulfur-cured CPE/NR blends. J. Appl. Polym. Sci. 93 (2004) 1129
19. Pattanawanidchai S., Sae-oui P., and Sirisinha C. Influence of precipitated silica on dynamic mechanical properties and resistance to oil and thermal ageing in CPE/NR blends. J. Appl. Polym. Sci. 96 (2005) 2218
20. Nair T.M., Kumaran M.G., and Unnikrishnan G. Mechanical and aging properties of cross-link ethylene propylene diene rubber/styrene butadiene rubber blends. J. Appl. Polym. Sci. 93 (2004) 2606
21. Sirisinha C., Phoowakeereewiwat S., and Saeoui P. Cure and dynamic mechanical properties in peroxide-cured isoprene rubber: effect of stearic acid and amine-based antioxidant. Eur. Polym. J. 40 (2004) 1779
22. Radhakrishnan C.K., Sujith A., Unnikrishnan G., and Thomas S. Effect of the blends ratio and crosslinking systems on the curing behavior, morphology and mechanical properties of styrene-butadiene rubber/poly(ethylene-co-vinylacetate) blends. J. Appl. Polym. Sci. 94 (2004) 827
23. Aperm A.S., Joeph K., Laxminarayanan R., and Thomas S. Physical, mechanical, and viscoelastic properties of natural rubber vulcanizates cured with new binary accelerator system. J. Appl. Polym. Sci. 87 (2003) 2193