Dechlorination comparison of mono-substituted PCBs with Mg/Pd in different solvent systems

Chemosphere

Volumn 73, Issue 6, 2008, Pages 896-900

  DeVor, Robert ^a   Carvalho Knighton, Kathy ^b   Aitken, Brian ^a   Maloney, Phil ^a   Holland, Erin ^a   Talalaj, Lukasz ^b   Fidler, Rebecca ^a   Elsheimer, Seth ^a   Clausen, Christian A ^a   Geiger, Cherie L ^a  

^a UNIVERSITY OF CENTRAL FLORIDA   (United States)

^b UNIVERSITY OF SOUTH FLORIDA   (United States)

Author keywords

Bimetallic; Degradation; Environmental; Polychlorinated biphenyl; Solvent specificity; Zero valent metal

Indexed keywords

ARSENIC COMPOUNDS; COMPUTER NETWORKS; CONTAMINATION; DECHLORINATION; IMPURITIES; INDUSTRIAL APPLICATIONS; METHANOL; ORGANIC SOLVENTS; PALLADIUM; PRINTED CIRCUIT BOARDS; PRINTED CIRCUITS; RATE CONSTANTS; REACTION RATES; SOLVENTS; WATER POLLUTION; WATER TREATMENT;

BIMETALLIC; DEGRADATION; ENVIRONMENTAL; POLYCHLORINATED BIPHENYL; SOLVENT SPECIFICITY; ZERO-VALENT METAL;

POLLUTION;

MAGNESIUM; METHANOL; PALLADIUM; POLYCHLORINATED BIPHENYL; SOLVENT; WATER;

BIODEGRADATION; BIOREMEDIATION; DECHLORINATION; ENVIRONMENTAL ISSUE; MAGNESIUM; METHANOL; ORGANIC POLLUTANT; PALLADIUM; PCB; REACTION KINETICS; SOLVENT;

ARTICLE; CHEMICAL REACTION; DECHLORINATION; DEGRADATION KINETICS; SOLVENT EFFECT;

ENVIRONMENTAL MONITORING; ENVIRONMENTAL POLLUTANTS; MAGNESIUM; MOLECULAR STRUCTURE; PALLADIUM; POLYCHLORINATED BIPHENYLS; SOLVENTS;

EID: 51449122051     PISSN: 00456535     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.chemosphere.2008.07.006     Document Type: Article

References (17)

1. Bedard D.L., Wagner R.E., Brennan M.J., Haberl M.L., and Brown Jr. J.F. Extensive degradation of Aroclors and environmentally transformed polychlorinated biphenyls by Alcaligenes eutrophus H850. App. Environ. Microbiol. 53 (1987) 1094
2. Blanksby S.J., and Ellison G.B. Bond dissociation energies of organic molecules. Acc. Chem. Res. 36 (2003) 255-263
3. Cheng I.F., Fernando Q., and Korte N. Electrochemical dechlorination of 4-chlorophenol to phenol. Environ. Sci. Technol. 31 (1997) 1074-1078
4. Chuang F., Larson R.A., and Wessman M.S. Zero-valent iron-promoted dechlorination of polychlorinated biphenyls. Environ. Sci. Technol. 29 (1995) 2460-2463
5. Eisenreich S.J., Looney B.B., and Hollod G.J. In: Mackay D., Paterson S., Eisenreich S.J., and Simmons M. (Eds). Physical Behavior of PCBs in the Great Lakes (1983), Ann Arbor Science, Ann Arbor, Michigan 115-125
6. Erickson M.D. Analytical Chemistry of PCBs (1992), Lewis, Boca Raton pp. 5-45
7. Grittini C., Malcomson M., Fernando Q., and Korte N. Rapid dechlorination of polychlorinated biphenyls on the surface of a Pd/Fe bimetallic system. Environ. Sci. Technol. 29 (1995) 2898-2900
8. Kim Y.-H., Shin W.S., and Ko S.-O. Reductive dechlorination of chlorinated biphenyls by palladized zero-valent metals. Environ. Sci. Health A39 5 (2004) 1177-1188
9. Kovenklioglu S., Cao Z., Shah D., Farrauto R.J., and Balko E.N. Direct catalytic hydrodechlorination of toxic organics in wastewater. AIChE J. 38 (1992) 1003-1012
10. Li T., and Farrell J. Reductive dechlorination of trichloroethene and carbon tetrachloride using and palladized-iron cathodes. Environ. Sci. Technol. 34 (2000) 173-179
11. Lowry G.V., and Reinhard M. Hydrodehalogenation of 1- to 3-carbon halogenated organic compounds in water using a palladium catalyst and hydrogen gas. Environ. Sci. Technol. 33 (1999) 1905-1910
12. Mousa M.A., Quensen III J.F., Chou K., and Boyd S.A. Microbial dechlorination alleviates inhibitory effects of PCBs on mouse gametes in vitro. Environ. Sci. Technol. 30 (1996) 2087
13. Muftkian R., Fernando Q., and Korte N. A method for the rapid dechlorination of low molecular weight chlorinated hydrocarbons in water. Water Res. 29 (1995) 2434-2439
14. Quensen III J.F., Mousa M.A., Boyd S.A., Sanderson J.T., Fruese K.L., and Giesy J.P. Reduction of aryl hydrocarbon receptor-mediated activity of polychlorinated biphenyl mixtures due to anaerobic microbial degradation. Environ. Toxicol. Chem. 17 (1998) 806
15. Toxic Information Series, 1983. Polychlorinated biphenyls. US EPA Toxics Information Series, United States Environmental Protection Agency, Office of Toxics Substances, TSCA Assistance Office (TS-799) Washington, District of Columbia.
16. Wang C.-B., and Zhang W.-X. Synthesizing nanoscale iron particles for rapid and complete dechlorination of TCE and PCBs. Environ. Sci. Technol. 31 (1997) 2154-2156
17. Wu W., Xu J., Zhao H., Zhang Q., and Liao S. A practical approach to the degradation of polychlorinated biphenyls in transformer oil. Chemosphere 60 7 (2005) 944-950