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Volumn 78, Issue 3, 2008, Pages

Toward a thermodynamically consistent picture of the phase-field model of vesicles: Curvature energy

Author keywords

[No Author keywords available]

Indexed keywords

BENDING FORCES; CONSTITUTIVE LAWS; PHASE FIELD MODELLING;

EID: 51349114290     PISSN: 15393755     EISSN: 15502376     Source Type: Journal    
DOI: 10.1103/PhysRevE.78.031902     Document Type: Article
Times cited : (23)

References (34)
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    • If one has in mind a more general form of the Gaussian contribution f (H) (with f an arbitrary nonlinear function of H), then the topological invariance does not hold anymore. We shall not, however, consider this general case. Note also that even with the linear function H, the topological invariance is not fulfilled in the strict sense within phase field, since we would have H | φ | dV, and not just HdA, where dA is the area element. However, in the asymptotic limit where the interface width tends to zero, we should recover the topological invariance.
    • If one has in mind a more general form of the Gaussian contribution f (H) (with f an arbitrary nonlinear function of H), then the topological invariance does not hold anymore. We shall not, however, consider this general case. Note also that even with the linear function H, the topological invariance is not fulfilled in the strict sense within phase field, since we would have H | φ | dV, and not just HdA, where dA is the area element. However, in the asymptotic limit where the interface width tends to zero, we should recover the topological invariance.
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    • Actually, the mean curvature is defined by s n, where s is the gradient along the contour (s refers to surface). However, since |n| =1, it is straightforward to show that s n=?n.
    • Actually, the mean curvature is defined by s n, where s is the gradient along the contour (s refers to surface). However, since |n| =1, it is straightforward to show that s n=?n.
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    • The invariants of a tensor T are Tr (T), Tr (T2), and Tr (T3) [it can be shown that these invariants are also Tr (T), Tr (T2), and det (T)]. In the particular case where T=?φ, it is straightforward to show that Tr (T) = 2 φ, Tr (T2) = (?φ:?φ), and Tr (T3) = [(?φφ): ?φ], which are thus the three invariants of the tensor ?φ. This result is coherent with that provided in Ref..
    • The invariants of a tensor T are Tr (T), Tr (T2), and Tr (T3) [it can be shown that these invariants are also Tr (T), Tr (T2), and det (T)]. In the particular case where T=?φ, it is straightforward to show that Tr (T) = 2 φ, Tr (T2) = (?φ:?φ), and Tr (T3) = [(?φφ): ?φ], which are thus the three invariants of the tensor ?φ. This result is coherent with that provided in Ref..
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    • It is worth noting that the application of thermodynamics of irreversible processes shows that, because the thermodynamic variable φ is a vector, the dynamic viscosity is in general a tensor with five independent components. This feature accounts for the anisotropic character of the viscosity within the interfacial region due to the introduction of a special direction φ. However, in the present work, we restrict the model to the purely isotropic case, which is believed to capture the essential ingredient of viscous effects.
    • It is worth noting that the application of thermodynamics of irreversible processes shows that, because the thermodynamic variable φ is a vector, the dynamic viscosity is in general a tensor with five independent components. This feature accounts for the anisotropic character of the viscosity within the interfacial region due to the introduction of a special direction φ. However, in the present work, we restrict the model to the purely isotropic case, which is believed to capture the essential ingredient of viscous effects.
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    • The choice of the relative position of the subscripts x, z is consistent with the notations in this paper. We must keep in mind that sometimes (i.e., in several literature) the reverse subscript order is chosen.
    • The choice of the relative position of the subscripts x, z is consistent with the notations in this paper. We must keep in mind that sometimes (i.e., in several literature) the reverse subscript order is chosen.
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    • Strictly speaking τzx =0 only at the surface of the plate. But since the plate is thin, it should remain small within the plate. Here we have taken the elementary width of the volume element in Fig. 1 to be that of the plate itself.
    • Strictly speaking τzx =0 only at the surface of the plate. But since the plate is thin, it should remain small within the plate. Here we have taken the elementary width of the volume element in Fig. 1 to be that of the plate itself.
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    • While a surface tension does exist for fluid interfaces, the authors in were interested in not including this phase-field surface tension in the phase-field evolution itself, but rather in the momentum balance equation.
    • While a surface tension does exist for fluid interfaces, the authors in were interested in not including this phase-field surface tension in the phase-field evolution itself, but rather in the momentum balance equation.
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    • It is straightforward to show that n (s n) =0 and (s n) n=0 so that the determinant of s n, which is the third invariant, is nil. If we set A s n, then the ith components in the products above are defined as (nA) i = nj Aji, (An) i = Aij nj.
    • It is straightforward to show that n (s n) =0 and (s n) n=0 so that the determinant of s n, which is the third invariant, is nil. If we set A s n, then the ith components in the products above are defined as (nA) i = nj Aji, (An) i = Aij nj.


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