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The first paper that originated the CM model: (a) Shaik, S. J. Am. Chem. Soc. 1981, 105, 3692. About the most updated review of the CM model, one can see:
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We have evaluated an alternative reaction mechanism in which insertion of a bound isocyanide and coordination of an additional one to the metal occur in this sequence, opposite that considered currently, via the intermediacy of three-coordinate MII metallacyclobutane and -pentane structures. However, after about several weeks' search, it always failed. We thus think the mechanism proposed in the present work should be trustful
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II metallacyclobutane and -pentane structures. However, after about several weeks' search, it always failed. We thus think the mechanism proposed in the present work should be trustful.
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