Reactivity and hydrogen storage performances of magnesium-nickel-copper ternary mixtures prepared by reactive mechanical grinding

International Journal of Hydrogen Energy

Volumn 33, Issue 17, 2008, Pages 4593-4606

  Milanese, C ^a   Girella, A ^a   Bruni, G ^b   Cofrancesco, P ^b   Berbenni, V ^b   Villa, M ^a   Matteazzi, P ^c,d   Marini, A ^b  

^a UNIVERSITY OF BERGAMO   (Italy)

^b UNIVERSITY OF PAVIA   (Italy)

^c CSGI   (Italy)

^d MBN Nanomateriali SpA   (Italy)

Author keywords

Hydrogen storage; Intermetallic compounds; Mg based hydrides; Pressure composition isotherm; Reactive mechanical grinding; Sorption reaction; Thermogravimetric analysis; X ray diffraction

Indexed keywords

BALL MILLING; COPPER; GRINDING (MACHINING); HYDROGEN; LIGHT METALS; MAGNESIUM; MAGNESIUM PRINTING PLATES; NICKEL; NICKEL ALLOYS; NONMETALS;

BALL MILLING IN HYDROGEN; INTERMETALLIC COMPOUNDS; MG-BASED HYDRIDES; PRESSURE-COMPOSITION ISOTHERM; REACTIVE ATMOSPHERES; REACTIVE MECHANICAL GRINDING; SORPTION REACTION; TERNARY MIXTURES; THERMOGRAVIMETRIC ANALYSIS; X-RAY DIFFRACTION;

HYDROGEN STORAGE;

COPPER COMPOUNDS; DEHYDROGENATION; GRINDING; HYDROGEN; HYDROGENATION; LIGHT METALS; MAGNESIUM COMPOUNDS; MICROSTRUCTURE; MIXTURES; NICKEL COMPOUNDS; PRINTING PLATES; REACTIVITY; SCANNING ELECTRON MICROSCOPY; SORPTION; TRANSITION METALS; X RAY DIFFRACTION;

EID: 50849088036     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2008.05.053     Document Type: Article

References (27)

1. Stampfer J.F., Holley C.E., and Suttle J.F. Magnesium-hydrogen system. J Am Chem Soc 82 (1960) 3504-3508
2. Zaluska A., Zaluski L., and Ström-Olsen J.O. Nanocrystalline magnesium for hydrogen storage. J Alloys Compd 288 1-2 (1999) 217-225
3. Manchester F.D., and Khatamian D. Mechanisms for activation of intermetallic hydrogen absorbers. Mater Sci Forum 31 (1988) 261-296
4. Yermakov A.Y., Mushnikov N.V., Uimin M.A., Gaviko V.S., Tankeev A.P., Skripov A.V., et al. Hydrogen reaction kinetics of Mg-based alloys synthesized by mechanical milling. J Alloys Compd 425 1-2 (2006) 367-372
5. 6 prepared by reactive milling. Mater Sci Eng B 108 1-2 (2004) 28-32
6. Gennari F.C., Urretavizcaya G., and Meyer G.O. Synthesis of hydrides by mechanical alloying in the Mg-Ni-Ge system. J Alloys Compd 356-357 (2003) 588-592
7. 2 atmosphere. J Alloys Compd 404-406 (2005) 27-30
8. 2 by high-pressure reactive ball milling. J Alloys Compd 427 1-2 (2007) 204-208
9. 2. J Alloys Compd 443 1-2 (2007) 121-124
10. 3 prepared by mechanical alloying. Mater Sci Eng A 335 1-2 (2002) 43-48
11. Schulz R., Huot J., Liang G., Boily S., Lalande G., Denis M.C., et al. Recent developments in the applications of nanocrystalline materials to hydrogen technologies. Mater Sci Eng A 267 2 (1999) 240-245
12. (0.03) (Ml = Cr, Fe, Co, Mn) alloys desorbing hydrogen at low temperature. J Alloys Compd 285 1-2 (1999) 298-301
13. Gross K., Spatz P., Zuttel A., and Schlapbach L. Mechanically milled Mg composites for hydrogen storage - the transition to a steady state composition. J Alloys Compd 240 1-2 (1996) 206-213
14. 0.6 composite. J Alloys Compd 297 1-2 (2000) 240-245
15. Bououdina M., Grant D., and Walker G. Review on hydrogen absorbing materials - structure, microstructure, and thermodynamic properties. Int J Hydrogen Energy 31 2 (2006) 177-182
16. Zaluska A., Zaluski L., and Ström-Olsen J.O. Structure, catalysis and atomic reactions on the nano-scale: a systematic approach to metal hydrides for hydrogen storage. Appl Phys A 72 2 (2001) 157-165
17. 2Cu alloy. J Solid State Chem 178 7 (2005) 2211-2217
18. Milanese C, Girella A, Bruni G, Berbenni V, Cofrancesco P, Marini A, et al. Hydrogen storage in magnesium-metal mixtures: reversibility, kinetic aspects and phase analysis. J Alloys Compd, in press. doi:10.1016/j.jallcom.2007.10.091.
19. Li L., Saita I., Saito K., and Akiyama T. Hydriding combustion synthesis of hydrogen storage alloys of Mg-Ni-Cu system. Intermetallics 10 10 (2002) 927-932
20. Li L., Saita I., Saito K., and Akiyama T. Effect of synthesis temperature on the hydriding behaviors of Mg-Ni-Cu ternary hydrogen storage alloys synthesized by hydriding combustion synthesis. J Alloys Compd 372 1-2 (2004) 218-223
21. 2Ni). J Less-Common Metals 92 2 (1983) 199-205
22. x (M = Fe, Co, Cu or Zn; 0 < x < 1) alloys. Int J Hydrogen Energy 13 2 (1988) 87-94
23. 1-x synthesized by mechanical alloying. Mater Sci Forum 269-272 2 (1998) 1049-1053
24. Zaluska L., Zaluski A., and Ström-Olsen J.O. Nanocrystalline metal hydrides. J Alloys Compd 253-254 (1997) 70-79
25. 2Cu) eutectic alloy: pressure sweep method. J Appl Phys 50 11 (1979) 7200-7209
26. Reilly J.J., and Wiswall R.H. Reaction of hydrogen with alloys of magnesium and copper. Inorg Chem 6 12 (1967) 2220-2223
27. 4. Inorg Chem 7 11 (1968) 2254-2256