Neighboring metal-induced oxidative addition in conjunction with a hydride trap: Formation of [(η5-MeC5H4)Fe(CO)(μ-η 1:-PPh2CH2PPh2)(μ-H)M(CO) 4] (M = W, Mo)

Organometallics

Volumn 16, Issue 2, 1997, Pages 155-157

  Liu, C W ^a   Wen, Yuh Sheng ^a   Liu, Ling Kang ^a  

^a INSTITUTE OF CHEMISTRY   (Taiwan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 5044245914     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om9608061     Document Type: Article

References (51)

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18. 2 used previously for the synthesis of hydridobridged metal clusters was either an oxidative addition to preformed cluster compounds or a metal hydride attachment to the second metal centers.
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42. c
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45. w = 0.056, and GOF = 2.52 with 81 atoms and 427 parameters for 3913 out of 4763 measured reflections. The hydride position was found from the final difference Fourier map. The oxygen atom of the diethyl ether solvate was located on the crystallographic inversion center, the diethyl ether being disordered. Currently a neutron diffraction study is being in progress in order to locate the exact position of hydride.
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51. 4(dppm) were isolated with a sizable amount of 1 recovered.