메뉴 건너뛰기




Volumn 121, Issue 11, 2004, Pages 5348-5355

The workings of a molecular thermometer: The vibrational excitation of carbon tetrachloride by a solvent

Author keywords

[No Author keywords available]

Indexed keywords

INTRAMOLECULAR VIBRATIONAL RELAXATION (IVR); SOLUTE-SOLVENT DYNAMICS; VIBRATIONAL ENERGIES; VIBRATIONAL EXCITATION;

EID: 5044239778     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.1784441     Document Type: Article
Times cited : (28)

References (68)
  • 5
    • 0004971705 scopus 로고    scopus 로고
    • H. Graener, R. Zürl, and M. Hofmann, J. Phys. Chem. B 101, 1745 (1997); M. Hofmann and H. Graener, Chem. Phys. 206, 129 (1996).
    • (1996) Chem. Phys. , vol.206 , pp. 129
    • Hofmann, M.1    Graener, H.2
  • 33
    • 0012607756 scopus 로고
    • R. M. Whitnell, K. R. Wilson, and J. T. Hynes, J. Phys. Chem. 94, 8625 (1990); J. Chem. Phys. 96, 5354 (1992).
    • (1992) J. Chem. Phys. , vol.96 , pp. 5354
  • 42
    • 0000877841 scopus 로고
    • 4 are fixed at the gas-phase experimental values. Note, however, that more care is some-times required for Landau-Teller-predicted IVR rates; solvent-induced fluctuations can cause dramatic errors if the fluctuations allow intramolecular states to become nearly degenerate. See Ref. 34 for a clear discussion of this point.
    • (1975) J. Chem. Soc., Faraday Trans. 2 , vol.71 , pp. 515
    • Clark, R.J.H.1    Mitchell, P.D.2
  • 49
    • 0031383094 scopus 로고    scopus 로고
    • D. Rostkier-Edelstein, P. Graf, and A. Nitzan, J. Chem. Phys. 107, 10470 (1997); ibid. 108, 9598(E) (1998).
    • (1998) J. Chem. Phys. , vol.108
  • 50
    • 0036152868 scopus 로고    scopus 로고
    • Because of IVR bottlenecks, the lowest frequency mode may not always be the gateway for vibrational energy leaving a molecule. See J. Assman et al. (Ref. 28) and G. Käb, C. Schröder, and D. Schwarzer, Phys. Chem. Chem. Phys. 4, 271 (2002).
    • (2002) Phys. Chem. Chem. Phys. , vol.4 , pp. 271
    • Assman, J.1    Käb, G.2    Schröder, C.3    Schwarzer, D.4
  • 51
    • 0035886132 scopus 로고    scopus 로고
    • C. M. Cheatum, M. H. Heckscher, D. Bingemann, and F. F. Crim, J. Chem. Phys. 115, 7086 (2001); M. M. Heckscher, L. Sheps, D. Bingemann, and F. F. Crim, ibid. 117, 8917 (2002); C. G. Elles, D. Bingemann, M. M. Heckscher, and F. F. Crim, ibid. 118, 5587 (2003).
    • (2001) J. Chem. Phys. , vol.115 , pp. 7086
    • Cheatum, C.M.1    Heckscher, M.H.2    Bingemann, D.3    Crim, F.F.4
  • 52
    • 0037113164 scopus 로고    scopus 로고
    • C. M. Cheatum, M. H. Heckscher, D. Bingemann, and F. F. Crim, J. Chem. Phys. 115, 7086 (2001); M. M. Heckscher, L. Sheps, D. Bingemann, and F. F. Crim, ibid. 117, 8917 (2002); C. G. Elles, D. Bingemann, M. M. Heckscher, and F. F. Crim, ibid. 118, 5587 (2003).
    • (2002) J. Chem. Phys. , vol.117 , pp. 8917
    • Heckscher, M.M.1    Sheps, L.2    Bingemann, D.3    Crim, F.F.4
  • 53
    • 0037460978 scopus 로고    scopus 로고
    • C. M. Cheatum, M. H. Heckscher, D. Bingemann, and F. F. Crim, J. Chem. Phys. 115, 7086 (2001); M. M. Heckscher, L. Sheps, D. Bingemann, and F. F. Crim, ibid. 117, 8917 (2002); C. G. Elles, D. Bingemann, M. M. Heckscher, and F. F. Crim, ibid. 118, 5587 (2003).
    • (2003) J. Chem. Phys. , vol.118 , pp. 5587
    • Elles, C.G.1    Bingemann, D.2    Heckscher, M.M.3    Crim, F.F.4
  • 55
    • 5044228000 scopus 로고    scopus 로고
    • note
    • As we have emphasized in Refs. 7, 10, and 12, while instantaneous-pair (IP) theory is not completely unrelated to the traditional independent-binary- collision (IBC) model for vibrational relaxation, it does have a number of substantial differences from it. Unlike IBC theory, IP theory does not assume that dynamics of dense liquids features discrete, well-defined, two-particle collision events. Instead, it looks upon one liquid configuration at a time, and notes that the dynamic range of solute/solvent forces is so large that the high-frequency components of each configuration's forces are almost always going to be completely dominated by those from its single most prominent solvent/solute pair. The final result is then an equilibrium average over liquid configurations.
  • 61
    • 5044231027 scopus 로고    scopus 로고
    • note
    • 2 θ) = 2.
  • 62
    • 0000595103 scopus 로고    scopus 로고
    • See, for example, S. A. Egorov and J. L. Skinner, J. Chem. Phys. 106, 1034 (1997); A. Ma and R. M. Stratt, J. Chem. Phys.
    • (1997) J. Chem. Phys. , vol.106 , pp. 1034
    • Egorov, S.A.1    Skinner, J.L.2
  • 63
    • 0000595103 scopus 로고    scopus 로고
    • See, for example, S. A. Egorov and J. L. Skinner, J. Chem. Phys. 106, 1034 (1997); A. Ma and R. M. Stratt, J. Chem. Phys.
    • J. Chem. Phys.
    • Ma, A.1    Stratt, R.M.2
  • 64
    • 5044240619 scopus 로고    scopus 로고
    • note
    • 4 modes.
  • 65
    • 5044225905 scopus 로고    scopus 로고
    • note
    • 2 modes, but not the E mode


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.