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note
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The distance between the Ag ions in the array was larger than their diameter and the dipole is considered in the far field regime. Thus, we attribute the 355 nm plasmon peak to the dipole-like oscillation and the significant blue shift to quantum size effect rather than higher multipoles. The relationship of α(ω) ∼ λ also predicts a blue shift of plasmon oscillation when the particle size is smaller than 6 nm according to ref. 20.
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