메뉴 건너뛰기




Volumn 11, Issue 9, 2008, Pages 975-977

Synthesis and characterization of bis(bipyridine)ruthenium(II) complexes with bromo or protected ethynyl β-diketonato ligands

Author keywords

diketone complex; Acetylenic compounds; Microwave irradiation synthesis; Mixed ligand; Ruthenium(II) bipyridyl complex; X Ray structure

Indexed keywords


EID: 50249118165     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2008.05.012     Document Type: Article
Times cited : (16)

References (26)
  • 8
    • 50249180509 scopus 로고    scopus 로고
    • note
    • III) = 0.68 V, ΔE = 0.074 V.
  • 9
    • 50249139290 scopus 로고    scopus 로고
    • note
    • III) = 0.75 V, ΔE = 0.073 V.
  • 10
    • 50249144861 scopus 로고    scopus 로고
    • note
    • III) = 0.74 V, ΔE = 0.071 V.
  • 11
    • 50249099449 scopus 로고    scopus 로고
    • note
    • 2Ru entity and the phosphorus atom appeared rather easily but the position of the fluorine atoms were very difficult to locate even at low temperature (150 K). The structure was then refined using shelx [16]. The refinement was performed anisotropically for all the non-hydrogen atoms of the complex except for the fluorine atoms. About the fluorine atoms, partial occupations were introduced and constraints on P-F lengths were imposed. In spite of the disorder, the hydrogen atoms could be localized by difference Fourier functions, recalculated and fixed at 0.96 Å from the corresponding carbon atoms with an isotropic thermal agitation proportional to the one of the linked carbon atoms. In spite of the poor quality of the R value due to the disorder and the poor crystallinity of the sample, the geometry of the studied compound could be described without ambiguities.
  • 13
    • 50249170088 scopus 로고    scopus 로고
    • A.J.M. Duisenberg, Reflections on Area Detectors, Utrecht, 1998.
    • A.J.M. Duisenberg, Reflections on Area Detectors, Utrecht, 1998.
  • 14
    • 50249126167 scopus 로고    scopus 로고
    • S. Mackay, C.J. Gilmore, C. Edwards, N. Stewart, K. Shankland, maxus Computer Program for the Solution and Refinement of Crystal Structures, Nonius, The Netherlands, MacScience & The University of Glasgow, The Netherlands/Japan, 1999.
    • S. Mackay, C.J. Gilmore, C. Edwards, N. Stewart, K. Shankland, maxus Computer Program for the Solution and Refinement of Crystal Structures, Nonius, The Netherlands, MacScience & The University of Glasgow, The Netherlands/Japan, 1999.
  • 15
    • 50249179387 scopus 로고    scopus 로고
    • P.T. Beurskens, G. Beurskens, R. de Gelder, S. Garcia-Granda, R.O. Gould, R. Israel, J.M.M. Smits, The DIRDIF-99 Program System, University of Nijmegen, The Netherlands, 1999.
    • P.T. Beurskens, G. Beurskens, R. de Gelder, S. Garcia-Granda, R.O. Gould, R. Israel, J.M.M. Smits, The DIRDIF-99 Program System, University of Nijmegen, The Netherlands, 1999.
  • 16
    • 50249184258 scopus 로고    scopus 로고
    • G.M. Sheldrick, University of Göttingen, Germany, 1997.
    • G.M. Sheldrick, University of Göttingen, Germany, 1997.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.