Estimation of atmospheric lifetimes of hydrofluorocarbons, hydrofluoroethers, and olefins by chlorine photolysis using gas-phase NMR spectroscopy

Analytical Chemistry

Volumn 80, Issue 16, 2008, Pages 6317-6322

  Marchione, Alexander A ^a   Fagan, Paul J ^a   Till, Eric J ^a   Waterland, Robert L ^a   LaMarca, Concetta ^a  

^a DUPONT COMPANY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ARSENIC COMPOUNDS; ATMOSPHERIC CHEMISTRY; ATMOSPHERICS; CHLORINE; CHLORINE COMPOUNDS; CORRELATION METHODS; ETHYLENE; INDUCTIVELY COUPLED PLASMA; LABORATORIES; MAGNETIC RESONANCE; NANOFLUIDICS; NUCLEAR MAGNETIC RESONANCE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OLEFINS; PHOTOLYSIS; PROPYLENE; RATE CONSTANTS; RESONANCE;

AMBIENT TEMPERATURES; ATMOSPHERIC LIFETIMES; CHEMICAL-; EMPIRICAL CORRELATIONS; GAS-PHASE; HYDROFLUOROCARBONS; HYDROFLUOROETHERS; KINETIC SYSTEMS; LINEAR CORRELATIONS; NMR SPECTROS COPY; NUCLEAR MAGNETIC RESONANCE (NMR) SPECTROSCOPY; PEARSON COEFFICIENTS; RATE OF REACTION; RELATIVE RATES; TOOLS AND TECHNIQUES;

REACTION RATES;

ALKENE; CHLORINE; ETHYLENE; FLUORINATED HYDROCARBON; HYDROFLUOROETHER; PROPYLENE; UNCLASSIFIED DRUG;

AIR TEMPERATURE; ARTICLE; CORRELATION COEFFICIENT; ENVIRONMENTAL TEMPERATURE; LIFESPAN; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PHOTOLYSIS; ULTRAVIOLET IRRADIATION;

EID: 50049103013     PISSN: 00032700     EISSN: None     Source Type: Journal    
DOI: 10.1021/ac800883t     Document Type: Article

References (21)

1. Kurylo, M. J.; Orkin, V. L. Chem. Rev. 2003, 103, 5049-5076.
2. Talukdar, R.; Mellouki, A.; Gierczak, T.; Burkholder, J. B.; McKeen, S. A.; Ravishankara, A. R. J. Phys. Chem. 1991, 95, 5815-5821.
3. Tokuhashi, K.; Chen, L.; Kutsuna, S.; Uchimaru, T.; Sugie, M.; Sekiya, A. J. Fluorine Chem. 2004, 125, 1801-1807.
4. Stutz, J.; Ezell, M. J.; Ezell, A. A.; Finlayson-Pitts, B. J. J. Phys. Chem. A 1998, 102, 8510-8519.
5. Orkin, V. L.; Huie, R. E.; Kurylo, M. J. J. Phys. Chem A 1997, 101, 9118-9124.
6. Aranda, A.; Diaz-de-Mera, Y.; Bravo, I.; Rodriguez, D.; Rodriguez, A.; Martinez, E. Environ. Sci. Technol. 2006, 40, 5971-5976.
7. Sellevag, S. R.; Nielsen, C. J.; Søvde, O. A; Myhre, G.; Sundet, J. K.; Stordal, F.; Isaksen, I. S. A. Atmos. Environ. 2004, 38, 6725-6735.
8. Andersen, M. P. Sulbaek; Nielsen, O. J.; Toft, A.; Nakayama, T.; Matsumi, Y.; Waterland, R. L.; Buck, R. C.; Hurley, M. D.; Wallington, T. J. J. Photochem. Photobiol. A 2005, 176, 124-128.
9. DeMore, W. B.; Wilson, Edmond W. Jr. J. Phys. Chem. A 1999, 103, 573-576.
10. DeMore, W. B.; Bayes, K. D. J. Phys. Chem. A 1999, 103, 2649-2654.
11. Coquet, S.; Ariya, P. A. Int. J. Chem. Kinet. 2000, 32, 478-484.
12. WilsonJr., E. W.; Sawyer, A. A.; Sawyer, H. A. J. Phys. Chem. A 2001, 105, 1445-1448.
13. Kating, P. M.; Krusic, P. J.; Roe, D. C.; Smart, B. E. J. Am. Chem. Soc. 1996, 118, 10000-10001.
14. Krusic, P. J.; Marchione, A. A.; Roe, D. C. J. Fluorine Chem. 2005, 126, 1510-1516.
15. Atkinson, R.; Carter, W. P.; Winer, A. M.; Pitts, J. N. Jr. J. Air Pollut. Control Assoc. 1981, 31, 1090-1092.
16. Marie, D.; Burrows, J. P.; Meller, R.; Moortgat, G. K. J. Photochem. Photobiol. A 1993, 70, 205-14.
17. Kochi, J. M. Free Radicals; Wiley-Interscience: New York, 1973; Vol. II.
18. IPCC, 2001: Climate Change 2001: The Scientific Basis. Contribution of Working Group I to the Third Assessment Report of the Intergovernmental Panel on Climate Change; Houghton, J. T., Ding, Y., Griggs, D. J., Noguer, M., van der Linden, P. J.; Dai, X., Maskell, K., Johnson, C. A., Eds.; Cambridge University Press: New York, 2001.
19. WMO, 2003: Scientific Assessment of Ozone Depletion: 2002. Global Ozone Research and Monitoring Project-Report No. 47; World Meteorological Organization: Geneva.
20. DeMore, W. B.; Sander, S. P.; Golden, D. M.; Hampson, R. F.; Kurylo, M. J.; Howard, C. J.; Ravishankara, A. R.; Kolb, C. E.; Molina, M. J. Chemical Kinetics and Photochemical Data for Use in Stratospheric Modeling; National Aeronautics and Space Administration, Jet Propulsion Laboratories: Pasadena, CA 1997; Evaluation 12.
21. IUPAC Subcommittee for Gas Kinetic Data Evaluation; http://www.iupac- kinetic.ch.cam.ac.uk, 2006.